Ternary peroxide fluororubber and preparation method thereof, and intelligent wearable material and preparation method thereof

A ternary peroxyfluororubber and peroxyfluororubber technology, which is applied in applications, clothing, jewelry, etc., can solve the problems that wristbands and watchbands cannot meet the requirements of safety, environmental protection, durability, and physical comfort.

Inactive Publication Date: 2020-07-03
四川道弘科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0010] The object of the present invention is to provide a kind of ternary peroxide fluororubber and its preparation method and smart wearable material and its preparation method, to solve the problem that the traditional wristband and watchband materials in the prior art cannot meet the require...

Method used

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  • Ternary peroxide fluororubber and preparation method thereof, and intelligent wearable material and preparation method thereof
  • Ternary peroxide fluororubber and preparation method thereof, and intelligent wearable material and preparation method thereof
  • Ternary peroxide fluororubber and preparation method thereof, and intelligent wearable material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0081] Carry out in the high pressure polymerization reactor of 10L, the total weight of vinylidene fluoride, tetrafluoroethylene and hexafluoropropylene added in the present embodiment is 2.3Kg, and the concrete steps are:

[0082] A1. Add 5L of deionized water, 4g of dipotassium hydrogen phosphate, 4g of diiodomethane and 10g of perfluoropolyether carboxylate ammonium salt (10wt%) into the high-pressure polymerization reaction kettle, evacuating nitrogen for replacement, and the oxygen in the high-pressure polymerization reaction kettle The content is reduced to less than 25ppm, and the temperature of the reactor is raised to 85°C;

[0083] A2, add initial monomers (vinylidene fluoride, tetrafluoroethylene and hexafluoropropylene) into the high-pressure polymerization reaction kettle with a compressor until the pressure in the high-pressure polymerization reaction kettle is 2.0Mpa, start stirring, and adjust the rotational speed to be 98rpm;

[0084] A3. When the mixture in ...

Embodiment 2

[0088] The present embodiment is carried out in a 10L high-pressure polymerization reactor, and the total weight of vinylidene fluoride, tetrafluoroethylene and hexafluoropropylene added in the present embodiment is 2.3Kg, and the specific steps are:

[0089] A1, add 5L deionized water, 5g dipotassium hydrogen phosphate, 6g diiodomethane and 9g perfluoropolyether carboxylate ammonium salt (10wt%) in the high pressure polymerization reaction kettle, evacuate nitrogen replacement, and replace the oxygen in the high pressure polymerization reaction kettle with oxygen The content is reduced to less than 25ppm, and the temperature of the reactor is raised to 83°C;

[0090] A2, adding initial monomers (vinylidene fluoride, tetrafluoroethylene and hexafluoropropylene) to the high-pressure polymerization reactor with a compressor to the pressure in the high-pressure polymerization reactor is 2.2Mpa, start stirring, and adjust the rotating speed to be 100rpm;

[0091] A3. When the mixt...

Embodiment 3

[0095] The present embodiment is carried out in a 10L high-pressure polymerization reactor, and the total weight of vinylidene fluoride, tetrafluoroethylene and hexafluoropropylene added in the present embodiment is 2.3Kg, and the specific steps are:

[0096] A1. Add 5L of deionized water, 5g of dipotassium hydrogen phosphate, 6g of diiodomethane and 11g of perfluoropolyether carboxylate ammonium salt (10wt%) into the high-pressure polymerization reaction kettle, and evacuated nitrogen replacement to reduce the oxygen content in the reaction kettle to less than 25ppm, and the temperature of the reactor was raised to 70°C;

[0097] A2, adding initial monomers (vinylidene fluoride, tetrafluoroethylene and hexafluoropropylene) to the high-pressure polymerization reactor with a compressor to the pressure in the high-pressure polymerization reactor is 2.7Mpa, start stirring, and adjust the rotating speed to be 105rpm;

[0098] A3. When the mixture in the high-pressure polymerizatio...

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Abstract

The invention provides ternary peroxide fluororubber and a preparation method thereof, and an intelligent wearable material and a preparation method thereof. The invention aims to solve the technicalproblem that wrist strap and watchband materials in the prior art cannot well meet requirements for swimming pool water resistance, sweat resistance, artificial sebum resistance, oleic acid resistanceand dirt resistance required by intelligent wearable wrist straps and watchbands at the same time. According to the preparation of fluororubber in the invention, iodine is used as a crosslinking active point, iodine used as the crosslinking active point is bonded to the tail end of a fluororubber polymer molecular chain or the tail end of a side chain of a vulcanization point monomer, and vulcanization crosslinking can be easily carried out with peroxide. A polymer prepared in the invention is used for preparing the intelligent wearable material. The prepared intelligent wearable wrist strapmaterial or watchband material can meet the requirements for swimming pool water resistance, sweat resistance, artificial sebum resistance, oleic acid resistance and dirt resistance, and a intelligentwearable wrist strap or watchband prepared from the material is safe, environmentally-friendly and durable to use, soft in hand feeling, good in texture and comfortable in somatosensory feeling and can better meet the high technical requirement for continuous changing of the material for the intelligent wearable wrist strap or watchband.

Description

technical field [0001] The invention relates to the field of fluorine-containing polymer materials, in particular to a ternary peroxyfluororubber and a preparation method thereof, and an intelligent wearable material and a preparation method thereof. Background technique [0002] In recent years, with the advancement of science and technology and the continuous improvement of people's quality of life, artificial intelligence and sports health have rapidly entered the lives of the public, and smart wearable devices have also emerged. Smart watches and smart bracelets have both: traditional watch functions, health monitoring, and intelligent interaction with smart devices such as smartphones. The huge market demand has driven the explosive growth of smart wearable wristbands and strap materials. [0003] Smart wearable wristbands and strap materials need to be safe, environmentally friendly, durable, comfortable, and meet specific functional requirements. Among them, specific...

Claims

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Application Information

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IPC IPC(8): C08F214/28C08F214/26C08F214/22C08F2/38C08L27/20C08K13/02C08K3/22C08K3/34C08K3/30C08K5/14A44C5/00
CPCA44C5/0053C08F214/22C08F214/26C08F214/28C08K3/22C08K3/30C08K3/34C08K5/14C08K13/02C08K2003/2296C08K2003/3045C08L2201/08C08F2/38C08L27/20
Inventor 周武刚苟文珊巫文强郑贤君
Owner 四川道弘科技有限公司
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