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Ceramic and metal co-support flat tube, battery/electrolytic cell, battery stack structure

A technology of electrolytic cells and flat tubes, applied in the energy field, can solve the problem of high sealing weight

Active Publication Date: 2021-05-18
XI AN JIAOTONG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] The invention provides a ceramic and metal co-supported flat tube, battery / electrolytic cell, and battery stack structure, which mainly solves the problems of sealing and excessive weight in metal-supported solid oxide fuel cells

Method used

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  • Ceramic and metal co-support flat tube, battery/electrolytic cell, battery stack structure
  • Ceramic and metal co-support flat tube, battery/electrolytic cell, battery stack structure
  • Ceramic and metal co-support flat tube, battery/electrolytic cell, battery stack structure

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0076] see figure 1 As shown, the sintered flat tube porous ceramic support body, the thickness of the flat tube is 0.8cm, the length and width of the upper and lower plane areas are: 15cm×5cm, the metal foil is fixed on the side and top surface of the ceramic support body, and the two ends of the metal foil are 1cm It is a non-porous area, and the middle 13cm is a porous area. The Ni / GDC anode was prepared by atmospheric plasma spraying on the porous area of ​​the metal foil, covering the porous area, the ScSZ electrolyte was prepared by atmospheric plasma spraying, the anode was completely wrapped, and the LSCF cathode was prepared on the electrolyte by atmospheric plasma spraying to complete the single cell preparation.

[0077] Explanation: The side and top surfaces in this embodiment refer to the side with the fuel gas inlet and outlet as the bottom surface, and the other surfaces as the side and top surfaces. The reason for this name is that when the solid oxide fuel ce...

Embodiment 2

[0079] Sintered flat tube porous ceramic support body, the thickness of the flat tube is 1.2cm, the length and width of the upper and lower plane areas are: 25cm×6cm, the metal foil is fixed on the side and top surface of the ceramic support body, and the 1cm at both ends of the metal foil is non-porous area, the middle 23cm is a porous area. Atmospheric plasma spraying Ni / GDC hydrogen electrode wraps the porous region in the middle, atmospheric plasma spraying and densification process prepares BZCY electrolyte-wrapped hydrogen electrode and all exposed porous metal supports, and prepares spinel Mn1 on the uncovered metal foil on the electrolyte side. 5Co1.5O3 protection, cast LSM / LSCF oxygen electrodes on the two planes of the flat tube respectively, and prepare an electrolytic cell after sintering, and the prepared electrolytic cell shows a high hydrogen production rate.

Embodiment 3

[0081] Sintered flat tube porous ceramic support body, the thickness of the flat tube is 2cm, the length and width of the upper and lower plane areas are: 50cm×8cm, the metal foil is bonded to the side and top surface of the ceramic support body, and the 1cm at both ends is a dense area, and the middle 48cm is the porous area. The Ni / GDC anode was prepared by atmospheric plasma spraying method on the porous area of ​​the metal support, covering the porous area, the ScSZ electrolyte was prepared by vacuum plasma spraying, and the anode was completely wrapped, and the LSCF cathode was prepared on the electrolyte by atmospheric plasma spraying, and two porous metal sheets were Contact the cathodes on both sides of the flat tube through the elastic force to derive the current on the cathode side to complete the preparation of the single cell. Single cell expresses good voltage and power output.

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Abstract

The invention provides a ceramic and metal co-supported flat tube, a battery / electrolytic cell and a battery stack structure. Wherein, the structure includes a porous ceramic flat tube support body and a flat tubular metal foil; the flat tubular metal foil wraps the porous ceramic flat tube support body; the closed end, the open end and the porous area of ​​the metal foil of the flat tubular metal foil; wherein, the flat tubular metal foil Both the closed end of the metal foil and the open end of the flat tubular metal foil are non-porous areas, and the porous areas are used for fuel gas circulation. Through the structure provided by the present invention, the closed end and the open end of the flat tube are jointly supported by ceramics and metal, and are respectively in contact with the electrolyte layer to achieve the purpose of self-sealing, effectively solving the sealing problem existing in metal-supported solid oxide fuel cells .

Description

technical field [0001] The invention relates to the field of energy technology, in particular to ceramic and metal co-supported flat tubes, batteries / electrolytic cells, and cell stack structures. Background technique [0002] Solid oxide fuel cell (Solid oxide fuel cell abbreviated as SOFC) is a solid-state power generation device with high power generation efficiency, no noise and no pollution when working, and directly converts the chemical energy of the fuel into electrical energy without burning. The functional layer of a solid oxide fuel cell mainly includes three functional layers: an anode, an electrolyte, and a cathode. [0003] Currently, there are two basic structures of the SOFC structure, the tube type and the planar type. The biggest difference between the two lies in whether the direction of current collection and conduction is perpendicular to the direction of the electrolyte film or parallel to the direction of the electrolyte film. The advantages of flat-...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M8/00H01M8/0271H01M8/0276H01M8/04007H01M8/12H01M8/243H01M8/2457C25B1/04C25B9/63C25B9/17
CPCH01M8/004H01M8/0271H01M8/04067H01M8/0276H01M8/12H01M8/243H01M8/2457H01M2008/1293C25B9/63C25B1/04C25B11/00C25B9/17Y02E60/36Y02E60/50
Inventor 李成新康思远李甲鸿李长久张山林
Owner XI AN JIAOTONG UNIV