Method for recovering sulfur in industrial by-product sulfur-calcium slag by fixed bed
An industrial by-product, fixed bed technology, applied in chemical instruments and methods, sulfur preparation/purification, sulfur compounds, etc., can solve problems such as environmental pollution, land occupation by titanium gypsum, loss of titanium gypsum, etc.
Active Publication Date: 2020-07-28
SOUTHWEAT UNIV OF SCI & TECH
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Problems solved by technology
The discharge of titanium gypsum not only occupies a large amount of land, but also pollutes the environment
Due to the washing of rainwater, the titanium gypsum on the stacking yard will be lost. At the same time, after the titanium gypsum is washed and soaked by rainwater, soluble harmful substances will dissolve in water, and the flow and circulation of water in the environment will seriously pollute surface water and Groundwater; on the other hand, after the accumulation of titanium gypsum is exposed to the sun and blown by the wind, a small part will be scattered in the atmosphere in powder form and settle on the surface of foreign objects that may come into contact, polluting the environment and threatening health [Li Guozhong, Zhao Shuai, Yu Yang. Application research of titanium gypsum in the field of building materials [J]. Brick and tile, 2008, (3): 58-60]
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[0023] The present invention will be described in further detail below in conjunction with specific examples.
[0024] A method for recovering sulfur in industrial by-product sulfur-calcium slag in a fixed bed, characterized in that it comprises the following steps in sequence: the industrial by-product sulfur-calcium slag is mixed evenly with a sulfur increasing agent, and then added to a fast decomposer for countercurrent heat exchange reaction to obtain oxidation Calcium and sulfur dioxide flue gas; the sulfur dioxide flue gas is passed into the activated reduction bed for reaction to obtain sulfur vapor flue gas, and the flue gas is cooled to recover sulfur.
[0025] Table 1
[0026]
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Abstract
The invention discloses a method for recovering sulfur in an industrial by-product sulfur-calcium slag by a fixed bed, comprising the following steps of: uniformly mixing the industrial by-product sulfur-calcium slag with a sulfur increasing agent, and adding into a rapid decomposer to carry out countercurrent heat exchange reaction to obtain calcium oxide and sulfur dioxide flue gas; introducingthe sulfur dioxide flue gas into an activation reduction bed for reaction to obtain sulfur steam flue gas, and cooling the flue gas to recover sulfur. Compared with the prior art, the method has the characteristics of low production cost, high production efficiency and good product quality.
Description
technical field [0001] The invention relates to the field of resource utilization of industrial waste residues, in particular to the utilization of industrial by-product sulfur-calcium residues. Background technique [0002] The industrial by-product sulfur-calcium slag is mainly one of industrial by-product gypsum, dry desulfurization ash or sulfur-fixing slag; the industrial by-product gypsum needs to be dried at 200-500°C to obtain anhydrous gypsum. [0003] Gypsum is a sulfate mineral with the chemical formula CaSO4 xH2O. Gypsum is divided into natural gypsum and industrial by-product gypsum. At present, the raw materials of industrial by-product gypsum are mainly phosphogypsum, desulfurization gypsum, titanium gypsum, and a small amount of fluorine gypsum, citrate gypsum, salt gypsum, etc. Dry desulfurization ash mainly contains calcium sulfite, and the ash obtained by desulfurization of slaked lime and sulfur dioxide in flue gas in a high-humidity absorption tower is...
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IPC IPC(8): C01B17/02C01B17/06
CPCC01B17/0264C01B17/06
Inventor 马小玲谭宏斌董发勤杨飞华张吉秀李玉香邓秋林王进明王进王军霞贺小春李芳
Owner SOUTHWEAT UNIV OF SCI & TECH