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Preparation method of nano-reinforcing metal matrix composite material with high strength and toughness

A nano-reinforcement and composite material technology, which is applied in the field of preparation of high-strength nano-reinforced metal matrix composite materials, can solve the problems of reinforcement structure damage, large structural damage, and reduction of nano-reinforcement space, so as to relieve stress and strain Effects of concentrating, improving work hardening ability, and improving isotropic hardening ability

Inactive Publication Date: 2020-08-07
上海鑫烯复合材料工程技术中心有限公司
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  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although the above-mentioned method can prepare nano-reinforced composite materials with non-uniform distribution of matrix grains, it has the following disadvantages: 1) Although high-energy ball milling or low-temperature ball milling can disperse nano-reinforcements, the damage to its structure is also great, especially For nanocarbons (such as carbon nanotubes, graphene, etc.), the intrinsic properties of the reinforcement are significantly reduced; 2) blending the ball-milled powder with the non-ball-milled powder can only obtain a matrix with a bimodal distribution of the grain structure 3) Since the nano-reinforcement is only added into the co-ball milling at the beginning of high-energy ball milling or low-temperature ball milling, it only exists in the fine-grained region, and there is no nano-reinforcement in the coarse-grained region. The space for nano-reinforcement dispersion is reduced, which brings greater challenges to dispersion; 4) The matrix composition is limited. Since the reinforcement and matrix powder need to be subjected to high-energy ball milling or low-temperature ball milling, the strength of the matrix powder cannot be too high. If If the strength of the matrix powder is too high and lacks deformation ability, the structure of the reinforcement will be severely damaged during the deformation process, especially the nano-carbon reinforcement that is sensitive to the structure
Due to the above shortcomings, the mechanical properties of the prepared nano-reinforced metal matrix composites have a strong-plastic inversion relationship in which the strength increases and the plasticity decreases, which restricts the development of engineering applications of such materials.

Method used

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  • Preparation method of nano-reinforcing metal matrix composite material with high strength and toughness

Examples

Experimental program
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Effect test

Embodiment 1

[0032] A CNT / Al-Cu-Mg composite material was prepared, wherein the mass fraction of carbon nanotubes was 1.5%, the mass fraction of Cu was 4%, the mass fraction of Mg was 1.5%, and the mass fraction of Al was 93%.

[0033] Mix 66.25wt% pure Al powder with a median particle size of 30 μm and 25wt% 2024Al powder with 5wt% Cu powder, 1.875wt% Mg powder and 1.875wt% CNT in a mixer for 5 hours, then put it into a ball mill, and use stainless steel The ball is used as the ball milling medium, and 3wt% stearic acid is additionally added as a process control agent, the ball-to-material ratio is 20:1, ball milled at a speed of 135 rpm for 12 hours, and then ball milled at a speed of 270 rpm for 2 hours, and then CNTs are obtained Well-dispersed grade I composite powder. Mix 80 wt% of the above grade I composite powder with 20 wt% of pure Al powder without ball milling in a mixer for 5 hours to obtain grade II composite powder.

[0034] The above-mentioned grade II composite powder was f...

Embodiment 2

[0036] Prepare graphene / Al-Zn-Cu-Mg composite material, wherein, the mass fraction of graphene is 0.5%, the mass fraction of Zn is 5%, the mass fraction of Cu is 2%, the mass fraction of Mg is 2%, Al The quality score is 93%.

[0037] Mix 63.125wt% pure Al powder and 25wt% 7075Al powder with 6.25wt% Zn powder, 2.5wt% Mg powder, 2.5wt% Cu powder and 0.625wt% CNT in a mixer for 5 hours, and then Put it into a ball mill, use stainless steel balls as the ball milling medium, add 3wt% stearic acid as a process control agent in addition, the ball to material ratio is 10:1, ball mill with a speed of 150 rpm for 14 hours, and then use 300 rpm Rotate the ball mill for 2.5 hours, and then obtain a grade I composite powder with well-dispersed graphene. After uniformly mixing 75wt% of the above-mentioned grade I composite powder and 25wt% of 7075Al powder, press it into a green body with a diameter of 40 mm under a pressure of 600 MPa, and then put the green body in a vacuum sintering fu...

Embodiment 3

[0039] The nano-SiC / Al-Cu-Mg composite material was prepared, wherein the mass fraction of nano-silicon carbide was 5%, the mass fraction of Cu was 4%, the mass fraction of Mg was 1.5%, and the mass fraction of Al was 89.5%.

[0040] Mix 61.875wt% pure Al powder with a medium particle size of 30 μm and 25wt% 2024Al powder with 5wt% Cu powder, 1.875wt% Mg powder and 6.25wt% nano-SiC in a mixer for 5 hours, and then put them into a ball mill to Stainless steel balls are used as the ball milling medium, and an additional 5wt% stearic acid is added as a process control agent, the ball-to-material ratio is 15:1, ball milled at a speed of 200 rpm for 10 hours, and then ball milled at a speed of 400 rpm for 1 hour, and then obtained Grade I composite powder with well dispersed graphene. Mix 80wt% of the above grade I composite powder with 20wt% of pure Al powder without ball milling in a mixer for 5h to obtain grade II composite powder.

[0041] The above-mentioned grade II composit...

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Abstract

The invention discloses a preparation method of a nano-reinforcing metal matrix composite material with high strength and toughness. The preparation method of the nano-reinforcing metal matrix composite material with high strength and toughness is characterized by comprising the steps of jointly ball-milling pure metal powder, alloy powder thereof, elementary-substance element powder for alloyingand a nano-reinforcing body by adopting variable-speed ball milling so as to obtain I-grade composite powder; then mixing with non-ball-milled pure metal or alloy powder so as to obtain II-grade composite powder; and densifying the obtained II-grade composite powder so as to obtain the nano-reinforcing metal matrix composite material. In the composite material, a non-homogeneous grain structure ofa matrix can promote stress stiffening and work hardening, stress-strain concentration is effectively relieved, and strength and plasticity are synchronously improved. The method is capable of regulating and controlling alloy components of the matrix as needed, wide in application range, and capable of realizing macro-quantitative preparation of bulk composite materials, so that the engineering application of the metal matrix composite material is promoted.

Description

technical field [0001] The invention relates to a preparation method of a high-strength and toughness nano-reinforced metal-matrix composite material, belonging to the technical field of metal-matrix composite materials. Background technique [0002] Metal matrix composites have been commercially applied in many fields such as transportation, aerospace, and electronic communication due to their lightweight structure and excellent heat and wear resistance, electrical and thermal conductivity, and damping and vibration reduction properties. However, SiC, Al 2 o 3 The interface stress concentration generated by the mismatch of modulus and thermal expansion coefficient between the traditional micron reinforcement and the metal matrix will lead to low stress fracture failure, which greatly reduces the plasticity, toughness and damage tolerance of metal matrix composites. In contrast, nano-reinforcements can effectively alleviate thermal mismatch and interfacial stress concentra...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C21/16C22C21/10C22C32/00C22C21/00C22C1/05C22C1/10B22F9/04B22F3/02B22F3/10B22F3/20
CPCB22F3/02B22F3/1007B22F3/20B22F9/04B22F2003/208B22F2009/042B22F2009/043B22F2998/10B22F2999/00C22C1/051C22C21/00C22C21/10C22C21/16C22C26/00C22C32/0063C22C2026/002B22F2201/20
Inventor 申世军杨继彪
Owner 上海鑫烯复合材料工程技术中心有限公司
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