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White-light OLED device and manufacturing method thereof

A manufacturing method and white light technology, applied in the field of OLED devices, can solve the problems of increased manufacturing difficulty and increased manufacturing cost, and achieve the effects of low cost, cost saving and simple process

Active Publication Date: 2020-08-07
SUZHOU INST OF NANO TECH & NANO BIONICS CHINESE ACEDEMY OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, whether it is in vacuum evaporation or in solution method, this complex device structure will cause the increase of manufacturing cost and the increase of manufacturing difficulty.

Method used

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  • White-light OLED device and manufacturing method thereof
  • White-light OLED device and manufacturing method thereof
  • White-light OLED device and manufacturing method thereof

Examples

Experimental program
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Embodiment 1

[0068] This embodiment provides a white light OLED device, which includes an anode, a hole injection layer, a light emitting layer, an electron transport layer and a cathode which are sequentially stacked. Wherein, the light-emitting layer has a single-layer structure, and its material is 10-(3-(1-phenyl-1H-benzo[d]imidazol-2-yl)phenyl)-10H- Phenoxazine, the material of the anode is ITO, the material of the hole injection layer is TAPC, the material of the electron transport layer is TPBI, and the material of the cathode is Al.

[0069] The maximum luminance of the white OLED device of this embodiment is 1000cd / m 2 ~1100cd / m 2 ; The CIE coordinates when the lighting voltage is 3.5V and 8V are (0.29, 0.36), and the change of the CIE coordinates in the process from 5V to 10V is only (±0.01, ±0.01); the luminous uniformity is greater than 95%. The white light OLED device provided in this embodiment exhibits excellent luminous performance.

[0070] The manufacturing method of t...

Embodiment 2

[0081] In the description of Embodiment 2, the similarities with Embodiment 1 will not be repeated here, and only the differences with Embodiment 1 will be described. The difference between embodiment 2 and embodiment 1 is that the material of the cathode in the white light OLED device in this embodiment is Al; and the light-emitting layer is obtained by spin-coating.

[0082] Specifically, in step 3 in Example 1, first, use a 1mL syringe to extract 0.3mL-0.5mL PEDOT:PSS and evenly drop it on the Plassma-treated substrate, and then use a homogenizer at 3000r / min-4000r / min The speed of 30s to 40s for 30s to 40s, and then move the uniform spin-coated hole injection layer film to a hot table and bake it at 160°C for 8min to 10min to obtain a stable and uniform hole injection layer with a thickness of 20nm to 30nm; Then, weigh 30 mg of 10-(3-(1-phenyl-1H-benzo[d]imidazol-2-yl)phenyl)-10H-phenoxazine shown in the above formula 2-2 and place it in a 4mL Then measure 2mL of chlorobe...

Embodiment 3

[0085] In the description of Embodiment 3, the similarities with Embodiment 1 will not be repeated here, and only the differences with Embodiment 1 will be described. The difference between embodiment 3 and embodiment 1 is that the material of the cathode in the white light OLED device in this embodiment is Al; and the light-emitting layer is made by inkjet printing.

[0086] Specifically, in step 3 in the same embodiment 1, at first, put the Plassma-treated substrate on the inkjet printer, select a 4mL reagent bottle, measure 1mL PEDOT:PSS and add it to the reagent bottle, and then Measure 3mL of ethylene glycol into the reagent bottle, place the reagent bottle at a frequency of 99kHz and sonicate for 10min~15min to obtain the hole injection layer solution; then, use a 1mL syringe to draw 0.3mL~0.5mL of the hole injection layer solution Inject into the card holder, and then print a uniform hole injection layer along the strip-shaped ITO on the substrate, and then move the hol...

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Abstract

The invention provides a white-light OLED device, which comprises an anode, a hole injection layer, a light emitting layer, an electron transport layer and a cathode which are stacked in sequence, wherein the light emitting layer has a single-layer structure, the material of the light emitting layer directly emits white light, the material of the light emitting layer has a D-pi-A structure, an A group is benzimidazole as an electron donor, a D group is a group which is used as an electron acceptor and has a structure represented by a formula 1, and a pi group is a five-membered ring or a six-membered ring. According to the white-light OLED device, a fluorescent material with a specific structure is selected as a light emitting layer material, and the effect of emitting white light can be achieved through a single layer, so that the defects that large thickness, complex production process and the like caused by multi-color light mixing can be avoided. The invention further provides a manufacturing method of the white-light OLED device. Based on material selection of the light-emitting layer, the white light OLED device can be realized through a vacuum evaporation method and can alsobe realized through solution methods such as ink-jet printing or spin coating, so that the manufacturing cost is low, and the manufacturing process is simple.

Description

technical field [0001] The invention belongs to the technical field of OLED devices, and specifically relates to a white light OLED device and a manufacturing method thereof. Background technique [0002] Entering the 21st century, with the rapid development of information technology, people put forward higher requirements in terms of solid-state lighting and flat panel display. Organic light emitting diodes (Organic Light Emitting Diodes, OLEDs) have attracted extensive attention from researchers because of their advantages such as high brightness, low energy consumption, wide spectrum, wide viewing angle, all-solid-state, self-illumination, fast response, low drive, and bendability. . [0003] OLED is a vertically stacked electroluminescent device similar to a "sandwich" structure. Its structure is generally divided into five parts, namely anode, hole injection layer, organic light emitting layer, electron transport layer and cathode. White organic light emitting diodes ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01L51/50H01L51/54H01L51/56
CPCH10K85/656H10K50/125H10K71/00Y02B20/00
Inventor 张东煜刘亚坤胡永旭孙玉玲
Owner SUZHOU INST OF NANO TECH & NANO BIONICS CHINESE ACEDEMY OF SCI