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High-entropy-alloy-based self-lubricating composite and preparation method thereof

A high-entropy alloy and composite material technology, applied in the field of self-lubricating composite material preparation, can solve the problems of many solidification structure defects, high energy consumption, low performance, etc., and achieve the effect of avoiding solidification structure defects, excellent mechanical properties, and dense structure.

Active Publication Date: 2020-08-25
XI'AN UNIVERSITY OF ARCHITECTURE AND TECHNOLOGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The preparation of high-entropy alloy-based self-lubricating composites and their additive manufacturing are hotspots for future industrial needs. However, due to the high melting point of high-entropy alloys and the high melting point of most solid lubricants, traditional additive manufacturing Technology (selective laser cladding, selective laser sintering, and electron beam fuse forming, etc.) to prepare high-entropy alloy-based self-lubricating composite materials consumes a lot of energy on the one hand, and on the other hand, there are many defects in the solidification structure and low performance.

Method used

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  • High-entropy-alloy-based self-lubricating composite and preparation method thereof
  • High-entropy-alloy-based self-lubricating composite and preparation method thereof
  • High-entropy-alloy-based self-lubricating composite and preparation method thereof

Examples

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preparation example Construction

[0027] The present invention proposes a high-entropy alloy-based self-lubricating composite material and a preparation method thereof comprising: taking the quaternary high-entropy alloy CoCrFeNi as the matrix, and the solid lubricant as the lubricating phase, mixing CoCrFeNi and the solid lubricant by ball milling, and then using cold spraying Deposit on the metal substrate to form a deposit body, and then use a stirring head to perform friction stir processing on the deposit body to obtain a high-entropy alloy-based self-lubricating composite material. The mass ratio of the CoCrFeNi to the solid lubricant is (2.3-4 ):1.

[0028] The method specifically includes: weighing the CoCrFeNi powder and the solid lubricant powder, placing the weighed CoCrFeNi powder and the solid lubricant powder in a ball mill for full ball milling to make them evenly mixed. The ball-milled mixed powder is placed in the powder storage bin of the cold spray equipment to prepare the high-entropy alloy...

Embodiment 1

[0033] This example is to prepare 70% CoCrFeNi-30% MoS 2 Self-lubricating compound. 70%CoCrFeNi-30%MoS 2 It means that the mass percentage of CoCrFeNi in the composite material is 70%, MoS 2 The mass percentage is 30%, and concrete steps are as follows:

[0034] (1) According to CoCrFeNi and MoS 2 The mass ratio is 7:3, respectively weigh CoCrFeNi powder and MoS 2 powder, wherein the particle size distribution range of CoCrFeNi powder is 25-50 μm, and the purity is 99.6%; MoS 2 The particle size distribution range of the powder is 30-60 μm, and the purity is 99.5%.

[0035] (2) The weighed CoCrFeNi powder and MoS 2 The powder is placed in a ball mill for ball milling, the ball milling time is 3 hours, and the ball-to-material ratio is 3:1.

[0036](3) Place the ball-milled mixed powder in the powder storage bin of the cold spraying equipment for deposit preparation. The gas used for cold spraying is air, the spraying pressure is 3.5MPa, the gas preheating temperature is...

Embodiment 2

[0042] This example is to prepare 80% CoCrFeNi-20% MoS 2 Self-lubricating composite additive body. 80%CoCrFeNi-20%MoS 2 It means that the mass percentage of CoCrFeNi in the composite material is 80%, MoS 2 The mass percentage is 20%. In this embodiment, a thicker high-entropy alloy-based self-lubricating composite material additive body is prepared, and the steps of cold spraying and friction stir processing are repeated twice.

[0043] Specific steps are as follows:

[0044] (1) According to CoCrFeNi and MoS 2 The mass ratio is 4:1, respectively weigh CoCrFeNi powder and MoS 2 powder, wherein the particle size distribution range of CoCrFeNi powder is 25-50 μm, and the purity is 99.6%; MoS 2 The particle size distribution range of the powder is 30-60 μm, and the purity is 99.5%.

[0045] (2) The weighed CoCrFeNi powder and MoS 2 The powder is placed in a ball mill for ball milling, the ball milling time is 4 hours, and the ball-to-material ratio is 4:1.

[0046] (3) Pl...

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Abstract

The invention discloses a high-entropy-alloy-based self-lubricating composite and a preparation method thereof. The preparation method of the high-entropy-alloy-based self-lubricating composite includes the steps that a four-element high-entropy alloy CoCrFeNi is used as a matrix, a solid lubricant is used as a lubricating phase, the CoCrFeNi and the solid lubricant are ball-milled and mixed and then deposited on a metal substrate through cold spraying to form a sedimentary body, the sedimentary body is subjected to friction stir machining through a stirring head, and the high-entropy-alloy-based self-lubricating composite is obtained, wherein the mass ratio of the CoCrFeNi to the solid lubricant is (2.3-4):1. According to the self-lubricating composite, the high-entropy alloy CoCrFeNi isused as the matrix, excellent mechanical performance of the high-entropy alloy overcomes losses of strength and toughness caused by adding of the solid lubricant, and therefore the prepared high-entropy-alloy-based self-lubricating composite keeps good self-lubricating capacity and has excellent mechanical performance.

Description

technical field [0001] The invention belongs to the technical field of self-lubricating composite material preparation, and in particular relates to a high-entropy alloy-based self-lubricating composite material and a preparation method thereof. Background technique [0002] Generally, metal-based self-lubricating composite materials are widely used in mechanical parts that are difficult to lubricate with conventional grease or in mechanical equipment that serve in harsh working conditions such as high speed, heavy load, high temperature, vacuum, and cryogenic. In order to obtain a lower coefficient of friction, metal-based self-lubricating composites generally need to add more solid lubricants, however, too much solid lubricants will reduce the mechanical properties of the composites. At present, most researchers prepare metal-based self-lubricating composites by sacrificing the strength of composites to improve their self-lubricating ability, which severely limits the appl...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23C24/04B22F9/04B22F1/00B33Y10/00B33Y40/20B33Y70/10
CPCC23C24/045B22F9/04B33Y10/00B33Y40/00B33Y70/00B22F2009/043B22F1/052B22F1/105Y02P10/25
Inventor 王文韩鹏彭湃刘强王快社张婷乔柯吴冰方园刘志浩
Owner XI'AN UNIVERSITY OF ARCHITECTURE AND TECHNOLOGY
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