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Anti-adhesion low-smoke halogen-free and flame-retardant polyolefin cable material

A polyolefin cable material, anti-adhesion technology, applied in the direction of circuits, electrical components, plastic/resin/wax insulators, etc., can solve problems such as not easy to separate, casualties, toxic smoke, etc.

Inactive Publication Date: 2020-09-08
上海方之德新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Cable material refers to the plastic used for wire and cable insulation and sheathing. As people become more and more aware of fire prevention, people pay more and more attention to the flame retardant performance of cable materials. However, adding halogen-containing plastics to cable materials Flame retardants, when there is a fire, will produce toxic smoke, causing greater casualties, so now low-smoke halogen-free flame-retardant cable materials are more and more widely used
[0003] There is still room for improvement in the smoke suppression, flame retardant and mechanical properties of the existing cable materials, and when the cables are coiled, if the anti-adhesion performance of the cable materials is poor, the cables will directly stick to each other, which will not Easy to separate, easy to damage the cable

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0053] An anti-adhesion, low-smoke, halogen-free and flame-retardant polyolefin cable material is prepared by the following method: 85g of ethylene-vinyl acetate copolymer, 65g of high-density polyethylene, 30g of magnesium hydroxide, 70g of aluminum hydroxide, 0.15g of melamine acid salt, 22g red phosphorus, 8.8g acrylic acid, 11g allyl alcohol, 23g silica with a diameter of 30nm, 7g zinc hydroxystannate with a diameter of 50nm, 21g nano-BaSO with a diameter of 30nm 4 , 1g of polylactic acid, and 1.5g of sodium hyaluronate are mixed uniformly, and mixed at a temperature of 130 ° C for 10 minutes, and then extruded and granulated at a temperature of 115 ° C using a twin-screw extruder to obtain anti-adhesion and low smoke. Halogen-free flame retardant polyolefin cable compound.

Embodiment 2

[0055] An anti-adhesion, low-smoke, halogen-free and flame-retardant polyolefin cable material is prepared in the following manner: 95 g of ethylene-vinyl acetate copolymer, 55 g of high-density polyethylene, 38 g of magnesium hydroxide, 50 g of aluminum hydroxide, 0.35 g of melamine urea acid salt, 10g red phosphorus, 17.6g acrylic acid, 22g allyl alcohol, 17g silica with 30nm diameter, 13g zinc hydroxystannate with 50nm diameter, 15g nano BaSO with 38nm diameter 4 , 2g of polylactic acid, and 0.5g of sodium hyaluronate are mixed evenly, and mixed at a temperature of 130 ° C for 10 minutes, and then extruded and pelletized at a temperature of 115 ° C using a twin-screw extruder to obtain anti-adhesion and low smoke. Halogen-free flame retardant polyolefin cable compound.

Embodiment 3

[0057] An anti-adhesion, low-smoke, halogen-free and flame-retardant polyolefin cable material is prepared in the following manner: 90 g of ethylene-vinyl acetate copolymer, 60 g of high-density polyethylene, 34 g of magnesium hydroxide, 60 g of aluminum hydroxide, 0.25 g of melamine urine acid salt, 16g red phosphorus, 13.5g acrylic acid, 16.5g allyl alcohol, 20g silica with 32.5nm diameter, 10g zinc hydroxystannate with 50nm diameter, 18g nano BaSO with 36nm diameter 4 , 1.5g of polylactic acid, and 1g of sodium hyaluronate were mixed evenly, and mixed at a temperature of 135 ° C for 12.5 minutes, and then at a temperature of 127.5 ° C, extruded and pelletized using a twin-screw extruder to obtain low anti-adhesion Smoke free halogen flame retardant polyolefin cable compound.

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Abstract

The invention discloses an anti-adhesion low-smoke halogen-free and flame-retardant polyolefin cable material. The invention belongs to the technical field of cable materials, and solves the problem of possible adhesion between cables. The cable material is prepared by adopting the following method of: by weight part, weighing 85-95 parts of an ethylene-vinyl acetate copolymer, 55-65 parts of highdensity polyethylene, 30-38 parts of magnesium hydroxide, 50-70 parts of aluminum hydroxide, 0.15-0.35 part of melamine urate, 10-22 parts of red phosphorus, 20-40 parts of a hyperdispersant, 17-23 parts of silicon dioxide, 7-13 parts of zinc hydroxystannate, 15-21 parts of nano BaSO4, 1-2 parts of polylactic acid and 0.5-1.5 parts of sodium hyaluronate evenly, conducting internal mixing for 10-15min at 130-140DEG C for 10-15min, and then performing extruding and granulating at 115-140DEG C, thereby achieving the effects of enabling the cable material to have good smoke-suppressing and flame-retardant properties and high anti-adhesive properties.

Description

technical field [0001] The invention relates to the field of cable materials, in particular to an anti-blocking low-smoke halogen-free flame-retardant polyolefin cable material. Background technique [0002] Cable material refers to the plastic used for wire and cable insulation and sheathing. As people become more and more aware of fire prevention, people pay more and more attention to the flame retardant performance of cable materials. However, adding halogen-containing plastics to cable materials Flame retardants, when a fire occurs, will produce toxic fumes, causing greater casualties, so now low-smoke, halogen-free, flame-retardant cable materials are more and more widely used. [0003] There is still room for improvement in the smoke suppression, flame retardant and mechanical properties of the existing cable materials, and when the cables are coiled, if the anti-adhesion performance of the cable materials is poor, the cables will directly stick to each other, which wi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/08C08L23/06C08L67/04C08L5/08C08K13/06C08K9/04C08K3/22C08K5/3492C08K3/02C08K3/36C08K3/30C08K5/20C08K13/02H01B3/44
CPCC08L23/0853H01B3/441C08L2203/202C08L2201/02C08L2201/22C08L2207/062C08L2205/035C08K2201/011C08K2003/3045C08K2003/026C08K2003/2224C08K2003/2227C08K2201/003C08K2003/2231C08K2201/014C08L23/06C08L67/04C08L5/08C08K13/02C08K3/22C08K5/34928C08K3/02C08K3/36C08K3/30C08K13/06C08K9/04C08K5/20
Inventor 董建东何亚丽
Owner 上海方之德新材料有限公司
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