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Organic electroluminescent device containing pyrene or azapyrene

An electroluminescence device and luminescence technology, applied in the field of semiconductors, can solve the problems of mismatching electron injection and transmission rates, weak injection and transmission characteristics, unfavorable device stability, etc., to improve hole injection and transmission performance, improve Effect of photoelectric performance and distribution balance

Active Publication Date: 2020-09-15
JIANGSU SUNERA TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

It is known that the injection and transport characteristics of the hole injection layer and the hole transport layer used in the existing organic electroluminescent devices are relatively weak, and the hole injection and transport rates do not match the electron injection and transport rates, resulting in partial recombination regions. large shift, which is not conducive to the stability of the device

Method used

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  • Organic electroluminescent device containing pyrene or azapyrene
  • Organic electroluminescent device containing pyrene or azapyrene
  • Organic electroluminescent device containing pyrene or azapyrene

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0091] Device Preparation Example 1: Carry out according to the following process:

[0092] a) use transparent glass as the substrate, on which coating thickness is 150nm ITO, as the anode layer, then respectively with deionized water, acetone, ethanol ultrasonic cleaning each 15 minutes, then process 2 minutes in the plasma cleaner;

[0093] b) On the washed first electrode layer, the hole injection layer HI1 obtained in the preparation of the above hole injection layer is evaporated by vacuum evaporation method, with a thickness of 10nm;

[0094] c) On the hole injection layer, a hole transport layer is evaporated by vacuum evaporation, the material of the hole transport layer is compound 1, and the thickness is 60nm;

[0095] d) Evaporating an electron blocking layer EB1 on the hole transport layer by vacuum evaporation with a thickness of 40nm;

[0096] e) On the electron blocking layer, evaporate the light-emitting layer material by vacuum evaporation, the host material ...

Embodiment 2-15

[0100] Device Example 2-15: proceed according to the process of Device Preparation Example 1, except that in step b), the hole injection layer 1 is replaced with any one of the hole injection layers 2-5; in step c), Replace the hole transport material with any one of compound 1, compound 2, compound 23, compound 37, and compound 66; in step d), replace the electron blocking layer material with any one of EB1 and compound 62, the specific device structure As in Table 2.

Embodiment 16

[0101] Device Example 16: according to the process of Device Preparation Example 1, the difference is that in step d), the film thickness of the electron blocking layer is 40nm; in step e), the host material is EMH-13, and the guest material is EMD-8 , and the mass ratio of EMH-13 and EMD-8 is 96:4, and the thickness is 40nm.

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Abstract

The invention relates to an organic electroluminescent device, which is provided with a substrate, a first electrode, an organic functional material layer and a second electrode from bottom to top insequence, and is characterized in that the organic functional material layer comprises: a hole transport region located on the first electrode, a light emitting layer over the hole transport region and including a host material and a guest material, and an electron transmission region located on the light emitting layer, wherein the hole transport region sequentially comprises a hole injection layer, a hole transport layer and an electron blocking layer from bottom to top, and at least one of the hole injection layer, the hole transport layer and the electron blocking layer is made of a compound with a structure represented by a general formula (1). By optimizing the device structure, high hole injection transmission characteristics can be maintained, the photoelectric property of the OLEDdevice can be effectively improved, and the service life of the OLED device can be effectively prolonged.

Description

technical field [0001] The invention relates to the technical field of semiconductors, in particular to an organic electroluminescence device in which an organic compound containing pyrene or azapyrene is used as a hole injection layer, a hole transport layer or an electron blocking layer. Background technique [0002] Organic electroluminescent (OLED: Organic Light Emitting Diodes) device technology can be used to manufacture new display products and new lighting products, and it is expected to replace the existing liquid crystal display and fluorescent lamp lighting, with a very broad application prospect. Typically, an OLED is composed of several layers including a positive electrode, a negative electrode, a hole injection layer, a hole transport layer, an organic light emitting layer, an electron transport layer, and an electron injection layer. OLED light-emitting device is a current device. When a voltage is applied to the electrodes at its two ends, and the positive a...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01L51/50H01L51/54
CPCH10K85/622H10K50/11H10K2101/40H10K50/18H10K50/15H10K50/17
Inventor 赵鑫栋李崇王芳张兆超吴秀芹
Owner JIANGSU SUNERA TECH CO LTD