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Method for treating power plant circulating sewage by electrochemical crystallization granulation system

A technology of circulating sewage and electrochemistry, applied in chemical instruments and methods, water softening, inorganic chemistry, etc., can solve the problems of difficult crystallization and granulation of crystals, and achieve the effect of fast decomposition rate and rapid potential homogenization

Active Publication Date: 2020-09-18
国能朗新明环保科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The present invention aims to solve the problem of excessive COD concentration, CaCO 3 Crystals are difficult to crystallize and granulate. The present invention uses an electrochemical crystallization method to efficiently and quickly remove COD in the circulating sewage of power plants and obtain CaCO 3 crystals, and does not produce high-water sludge, saving sludge and solid waste disposal costs

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  • Method for treating power plant circulating sewage by electrochemical crystallization granulation system
  • Method for treating power plant circulating sewage by electrochemical crystallization granulation system

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Experimental program
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Embodiment 1

[0040] Such as figure 1 As shown, the present invention provides a kind of method that electrochemical crystallization granulation system handles the circulating sewage of power plant, comprises the following steps:

[0041] S1. The circulating sewage of the power plant enters the interior of the cylinder 1 from the water distribution system 2 of the electrochemical crystallization granulation system;

[0042] S2. The sewage is kept in a fluidized state under the action of the agitator 3 in the reaction zone, and the power supply of the cathode electrode 7 is started, and the anode electrode 8 generates a high apparent current density of 1000-4000 A / m under the action of liquid fluidization, and the current efficiency is 10 % to 90%; using NaCl in the circulating sewage of power plants as the electrolyte, the organic matter is decomposed under the action of a uniformly distributed potential to remove COD;

[0043] S3. The sewage is discharged from the outlet pipe 6, and enter...

Embodiment 2

[0047] Such as figure 1 As shown, the present invention provides a kind of method that electrochemical crystallization granulation system handles the circulating sewage of power plant, comprises the following steps:

[0048] S1. The circulating sewage of the power plant enters the interior of the cylinder 1 from the water distribution system 2 of the electrochemical crystallization granulation system;

[0049] S2. The sewage is kept in a fluidized state under the action of the agitator 3 in the reaction zone, and the power supply of the cathode electrode 7 is started, and the anode electrode 8 generates a high apparent current density of 1000-4000 A / m under the action of liquid fluidization, and the current efficiency is 10 % to 90%; using NaCl in the circulating sewage of power plants as the electrolyte, the organic matter is decomposed under the action of a uniformly distributed potential to remove COD;

[0050] S3. The sewage is discharged from the outlet pipe 6, and enter...

Embodiment 3

[0054] Such as figure 1 As shown, the present invention provides a kind of method that electrochemical crystallization granulation system handles the circulating sewage of power plant, comprises the following steps:

[0055] S1. The circulating sewage of the power plant enters the interior of the cylinder 1 from the water distribution system 2 of the electrochemical crystallization granulation system;

[0056] S2. The sewage is kept in a fluidized state under the action of the agitator 3 in the reaction zone, and the power supply of the cathode electrode 7 is started, and the anode electrode 8 generates a high apparent current density of 1000-4000 A / m under the action of liquid fluidization, and the current efficiency is 10 % to 90%; using NaCl in the circulating sewage of power plants as the electrolyte, the organic matter is decomposed under the action of a uniformly distributed potential to remove COD;

[0057] S3. The sewage is discharged from the outlet pipe 6, and enter...

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Abstract

The invention provides a method for treating circulating sewage of a power plant by an electrochemical crystallization granulation system. The method comprises the following steps: introducing circulating sewage of a power plant into a cylinder (1), starting a power supply of the negative electrode (7) of an electrochemical crystallization granulation reactor to generate high current on the positive electrode (8), decomposing organic matters under the action of uniformly distributed potentials to obtain wastewater with reduced COD; carrying out a COD removal treatment; after a circular treatment, filling a crystal seed material into the cylinder (1) through a crystal seed feeding device (5), adding an alkaline agent, adjusting the pH value and the wastewater flow rate, obtaining CaCO3 crystals by utilizing chemical crystallization, and discharging the sewage to finish the treatment. The invention aims to solve the problems that the COD concentration is too high and CaCO3 crystals are difficult to crystallize and granulate, an electrochemical crystallization method is adopted, COD in the circulating sewage of a power plant is efficiently and quickly removed, CaCO3 crystals are obtained, meanwhile, sludge with a high water content is not generated, and the sludge solid waste treatment cost is saved.

Description

technical field [0001] The invention relates to the technical field of water treatment, in particular to a method for treating circulating sewage of power plants with an electrochemical crystallization granulation system. Background technique [0002] In recent years, thermal power plants, as large water consumers, have experienced a sharp increase in water resource constraints and discharge restrictions. Among them, the amount of water used and discharged by the circulating water system accounts for 80% to 90% of the total water consumption and total discharge of circulating cooling thermal power plants. focus. At present, most circulating cooling power plants have increased the concentration ratio by strengthening raw water pretreatment, optimizing water stabilizers, and upgrading condenser pipes; circulating water and sewage are reused as water for desulfurization, coal transportation, and slag removal, but there are still a large number of The remaining circulating wat...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F5/02C02F5/06C02F9/06B01D9/02C01F11/18C02F1/461C02F101/10C02F101/30
CPCC02F5/02C02F5/06C02F1/46114C02F1/66B01D9/0036C01F11/18C01F11/181C01F11/182C02F2101/10C02F2101/30
Inventor 陆梦楠徐志清赵焰郭旭涛苏双青杨燕陈雪陈文婷孙斌范鑫帝
Owner 国能朗新明环保科技有限公司