Process for Extracting and Separating Platinum Group Metals from Waste Catalysts
A technology of waste catalysts and platinum group metals, applied in the direction of improving process efficiency, etc., can solve the problems of large differences in grades and properties, achieve efficient extraction, simplify the process flow, and solve the effects of complex recycling principles
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[0043] Please refer to the attached figure 1 As shown, the technology for extracting and separating platinum group metals in a kind of spent catalyst provided by the invention comprises the following steps:
[0044] ⑴ Pretreatment
[0045] Take the waste catalyst, carry out crushing, roasting, pre-soaking treatment, and then separate the liquid and solid, put the leaching residue in a constant temperature drying box for heat preservation treatment, and obtain the pretreatment material; among them, the crushing is to crush the waste catalyst and put it in a grinder Grinding treatment, grinding to 40-300 mesh, roasting is roasting at 300-700 ° C for 2 hours, pre-soaking treatment is in hydrochloric acid with a concentration of 5mol / L, and the spent catalyst powder after roasting is in a liquid-solid ratio of 6: 1. Leach for 2 hours at a temperature of 85°C, heat preservation treatment is to control the temperature in a constant temperature drying oven at 100°C, and hold for 4 h...
experiment example
[0064] 1. Determination of the residual rate of various metals in the pre-soaking treatment of spent catalysts
[0065] Experimental principle: In addition to platinum group metals, spent catalysts also contain a large amount of MgO, A 2 lO 3 and SiO 2 These substances will reduce the leaching efficiency during the leaching process of platinum group metals and affect the recovery rate and purity of platinum group metals. Therefore, before the leaching of the platinum group metals, the spent catalyst is pre-soaked, and most of the soluble metal oxides are dissolved in the liquid solution. After the liquid-solid separation, the platinum group metals remain in the solid slag.
[0066] Experimental equipment: constant temperature drying oven, model YHG-300BS; disc vacuum filter, model RK / IL-240-120. of,
[0067] Experimental method: After the spent catalyst is roasted, it is pre-soaked with hydrochloric acid. The concentration of hydrochloric acid is 5 mol / L, the liquid-solid ...
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