Bio-based heat-resistant flame-retardant polyester, polyester product, preparation method and application thereof
A flame-retardant polyester and bio-based technology, applied in the field of polymers, can solve problems such as insufficient heat resistance and unsatisfactory flame-retardant performance
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[0049] In some embodiments, the preparation method includes: reacting the first mixed reaction system at 160-260°C for 1-10 hours to obtain an intermediate product.
[0050] In some embodiments, the preparation method includes: making the first mixed reaction system react in a vacuum environment at 200-300°C for 1-10 hours to obtain a bio-based heat-resistant and flame-retardant polyester, and the vacuum of the vacuum environment The degree is below 300Pa.
[0051] In some embodiments, the preparation method specifically includes: reacting the first dibasic alcohol, dibasic acid or its esterified product, the second dibasic alcohol and an esterification or transesterification catalyst at 160-260°C for 1-10 hours, and then Adding a polycondensation catalyst and a stabilizer, reacting for 1-10 hours in an environment with a temperature of 200-300° C. and a vacuum degree below 300 Pa, to obtain a bio-based heat-resistant and flame-retardant polyester.
[0052] In some embodiment...
Embodiment 1
[0094] Example 1 Add terephthalic acid, phosphorus-containing aromatic dihydric alcohol, and ethylene glycol into the reactor in a molar ratio of 1:0.15:2.1, then add anhydrous manganese acetate with a molar mass of terephthalic acid of 0.8‰, and heat up To 240°C, react for 5.0h, then add antimony trioxide with a molar mass of terephthalic acid of 0.4‰, triphenyl phosphate with a molar mass of terephthalic acid of 0.5‰, vacuum 30Pa, heat up to 280°C, and react for 4.0h , to obtain polyethylene terephthalate phosphorus-containing aromatic diol copolyester, the copolyester structure is shown in formula V, 1 H-NMR such as figure 1 Shown; the glass transition temperature is 97°C, and the DSC spectrum is as follows figure 2 Shown; T in nitrogen 5% The thermal weight loss temperature is 410°C, and the TGA spectrum is as follows image 3 Shown, flame retardant performance test V1 level.
[0095]
[0096] Formula V (m, n is an integer of 1-20; y is an integer of 10-200)
Embodiment 2
[0097] Example 2 Add terephthalic acid, phosphorus-containing aromatic dihydric alcohol, and ethylene glycol into the reactor in a molar ratio of 1:0.06:2.1, then add anhydrous manganese acetate with a terephthalic acid molar mass of 1.0‰, and heat up To 240°C, react for 4.0h, then add antimony trioxide with a molar mass of terephthalic acid of 0.5‰, triphenyl phosphate with a molar mass of terephthalic acid of 0.6‰, vacuum degree 50Pa, heat up to 278°C, and react for 4.0h , to obtain polyethylene terephthalate copolyester containing aromatic diol phosphorus, glass transition temperature 87 ℃, flame retardant performance test level V1.
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