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Method for floating silicon from silicon slag

A silicon slag and silicon-poor technology, applied in the field of silicon slag treatment

Active Publication Date: 2020-10-27
UNIV OF JINAN
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] At present, there are few researches on flotation separation and recovery of industrial silicon. Flotation separation is applied to the recovery of industrial silicon in silicon slag, which does not need to melt the silicon slag, effectively saves energy, is simple to operate, and has low production costs. value is significant

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] 1) Silicon slag crushing: first use a crusher to crush the silicon slag to less than 2mm, then put it into a stainless steel ball mill tank, and mill for 5 minutes;

[0035] 2) Sieving: Screen the finely ground silicon slag to obtain 10kg of 140~170 mesh silicon slag powder;

[0036] 3) Surface treatment: Then use hydrofluoric acid with a concentration of 3kg / t to carry out surface treatment on the silicon slag powder;

[0037] 4) Flotation: Add 700~750kg of hydrofluoric acid and one or two kinds of flotation wastewater filtrate to the surface-treated silicon slag, stir for 10 minutes, and add the collector cetyltrimethylammonium bromide The amount is 0.05kg / t, the foaming agent polyethylene glycol cetyl ether is added in an amount of 0.05kg / t, stirred for 7 minutes, and the bubbling switch is turned on. After the foam is abundant, then scrape and foam for 25 minutes to obtain a silicon-rich phase and Silicon-poor phase;

[0038] 5) Silicon-rich phase treatment: filte...

Embodiment 2

[0041] 1) Silicon slag crushing: first use a crusher to crush the silicon slag to less than 2mm, then put it into a stainless steel ball mill tank, and mill for 5 minutes;

[0042] 2) Sieving: Screen the finely ground silicon slag to obtain 10kg of 110~140 mesh silicon slag powder;

[0043] 3) Surface treatment: Then use hydrofluoric acid with a concentration of 3kg / t to carry out surface treatment on the silicon slag powder;

[0044] 4) Flotation: Add 700~750kg of hydrofluoric acid and one or two kinds of flotation wastewater filtrate to the surface-treated silicon slag, stir for 10 minutes, and add the collector cetyltrimethylammonium bromide The amount is 0.05kg / t, the foaming agent polyethylene glycol cetyl ether is added in an amount of 0.05kg / t, stirred for 7 minutes, and the bubbling switch is turned on. After the foam is abundant, then scrape and foam for 25 minutes to obtain a silicon-rich phase and Silicon-poor phase;

[0045] 5) Silicon-rich phase treatment: filte...

Embodiment 3

[0048] 1) Silicon slag crushing: first use a crusher to crush the silicon slag to less than 2mm, then put it into a stainless steel ball mill tank, and mill for 5 minutes;

[0049] 2) Screening: Screen the finely ground silicon slag to obtain 10kg 80~110 mesh silicon slag powder;

[0050] 3) Surface treatment: Then use hydrofluoric acid with a concentration of 3kg / t to carry out surface treatment on the silicon slag powder;

[0051] 4) Flotation: Add 700~750kg of hydrofluoric acid and one or two kinds of flotation wastewater filtrate to the surface-treated silicon slag, stir for 10 minutes, and add the collector cetyltrimethylammonium bromide The amount is 0.05kg / t, the foaming agent polyethylene glycol cetyl ether is added in an amount of 0.05kg / t, stirred for 7 minutes, and the bubbling switch is turned on. After the foam is abundant, then scrape and foam for 25 minutes to obtain a silicon-rich phase and Silicon-poor phase;

[0052] 5) Silicon-rich phase treatment: filter ...

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Abstract

The invention discloses a method for recovering metallic silicon from silicon slag through flotation, comprising the following steps of: 1) silicon slag crushing: crushing the silicon slag by using acrusher, and putting the crushed silicon slag into a ball milling tank made of stainless steel for ball milling; 2) sieving: sieving the ground silicon slag to obtain silicon slag powder with the particle size of not more than 170 meshes; 3) surface treatment: carrying out surface treatment on the silicon slag powder by using a surface treatment agent, and stirring to fully mix the silicon slag powder to form silicon slag slurry; 4) flotation: adding a collecting agent foaming agent into the fully-mixed silicon slag slurry and stirring uniformly, putting the mixture into a flotation machine for flotation, and starting foam scraping after foam is rich, thereby obtaining a silicon-rich phase and a silicon-poor phase; and 5) silicon-rich phase treatment: filtering the silicon-rich phase, washing and drying to obtain a silicon-rich product, so that efficient recycling of silicon slag resources is achieved.

Description

technical field [0001] The invention belongs to the technical field of silicon slag treatment, and in particular relates to a method for recovering metal silicon from silicon slag by flotation. Background technique [0002] At present, China has grown into the world's largest producer of industrial silicon, with steady growth in production capacity and output. After 2012, the output of industrial silicon has increased, and the proportion of China's industrial silicon in the world has also increased year by year, but the increase rate has decreased year by year. This is due to Due to the characteristics of the industrial silicon industry. Industrial silicon production is greatly affected by seasonality, and industrial silicon smelting needs to consume a large amount of power resources, resulting in high production costs. Yield will be affected to some extent. The contradiction between demand and production has become increasingly prominent, so many industrial silicon manufa...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B03D1/02B03B7/00C01B33/037
CPCB03D1/02B03B7/00C01B33/037Y02P10/20
Inventor 崔玉乔丹孙国新
Owner UNIV OF JINAN
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