Plant polyphenol polymer-based composite hair dye
A technology for plant polyphenols and hair dyes, which is used in hair care, medical preparations containing active ingredients, cosmetics, etc., to achieve the effects of strong adhesion, improved hair dyeing efficiency, and guaranteed hair dyeing effects.
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[0040] Preferably, the POSS linear polymer preparation method of the pyrogallic acid surface functionalization comprises:
[0041] Step 1, mixing acetone, phosphorus trichloride, and pyrogallic acid, stirring in an ice-water bath for 5-8 hours to obtain acetone-protected gallic acid;
[0042] Step 2, reacting the product of the previous step with 2-aminoethanethiol under the action of a catalyst to obtain the pyrogallic acid functionalized monomer protected by acetone;
[0043] Step 3, using T8 type POSS as the starting monomer to synthesize hexaethylenedicarboxy POSS and hexaethylenedihydroxy POSS, and polymerize to generate POSS linear polymer;
[0044] Step 4. After reacting the acetone-protected pyrogallic acid functionalized monomer with the POSS linear polymer, adding acetic acid to remove the acetone protection to obtain the POSS linear polymer with pyrogallic acid surface functionalized.
[0045] Preferably, the catalyst in step 2 is potassium iodide, and the conditio...
Embodiment 1
[0061] A kind of compound hair dye based on plant polyphenol polymer, comprises A agent, B agent, and described A agent and B agent mass ratio are 1:1;
[0062] The agent B is composed of 18% hydrogen peroxide, 8% oleyl alcohol, 8% oleic acid, 8% propylene glycol, 8% isopropanol, 1% sodium dodecylsulfonate, 1% phosphoric acid, deionized For the water balance, the mass percentage of each component is 100% in total;
[0063] Agent A consists of the following: 5,6-dihydroxyindole 1%, oleic acid 6%, cetearyl alcohol 6%, hydroxypropyl methylcellulose 1.2%, propylene glycol 6%, isopropanol 6%, Sodium dodecylsulfonate 1%, pyrogallic acid surface functionalized POSS linear polymer 5%, agar 5%, NaOH 0.24%, deionized water balance, the total mass percentage of each component is 100%;
[0064] The POSS linear polymer surface-functionalized with pyrogallic acid is composed of the following: 600 parts by weight of acetone, 20 parts by weight of phosphorus trichloride, 50 parts by weight o...
Embodiment 2
[0066] A kind of compound hair dye based on plant polyphenol polymer, comprises A agent, B agent, and described A agent and B agent mass ratio are 1:1
[0067] The agent B is composed of 22% hydrogen peroxide, 12% oleyl alcohol, 12% oleic acid, 12% propylene glycol, 12% isopropanol, 3% sodium dodecylsulfonate, 3% phosphoric acid, deionized For the water balance, the mass percentage of each component is 100% in total;
[0068] Agent A is composed of the following: 5,6-dihydroxyindole 5%, oleic acid 8%, cetearyl alcohol 8%, hydroxypropyl methylcellulose 1.3%, propylene glycol 9%, isopropanol 9%, Sodium dodecylsulfonate 3%, pyrogallic acid surface functionalized POSS linear polymer 10%, agar 6%, NaOH 1.9%, deionized water balance, the total mass percentage of each component is 100%;
[0069] The POSS linear polymer surface-functionalized with pyrogallic acid is composed of the following: 600 parts by weight of acetone, 20 parts by weight of phosphorus trichloride, 50 parts by we...
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