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A kind of photocatalyst paint and coating thereof

A photocatalyst and coating technology, which is applied in coatings, devices for coating liquid on the surface, pretreatment of surfaces, etc., can solve the problems of lack of stability of free radicals, poor stability of free radicals, low efficiency of free radicals, etc., and achieve increased Effects of relative specific surface area, reduction of reflection, and improvement of photon quantum efficiency

Active Publication Date: 2021-11-09
宁波派特勒新材料股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Therefore, the use of titanium dioxide photocatalyst needs to be excited by ultraviolet light sources that are harmful to the human body, which is inconvenient to use, and extending its application range to the visible light region has become an urgent problem to be solved.
[0007] Second, the light absorption efficiency is low and the utilization rate is low
The existing titanium dioxide photocatalyst absorbs light energy and also reflects most of it. The absorption of light is limited, which in turn reduces the utilization rate of light energy, which is a waste of electric energy.
[0008] Third, the stability of free radicals is poor and the catalytic efficiency is low
The photocatalysts used in the market are not efficient in converting light energy into free radicals, and the lack of stability of free radicals further reduces the catalytic efficiency

Method used

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  • A kind of photocatalyst paint and coating thereof
  • A kind of photocatalyst paint and coating thereof
  • A kind of photocatalyst paint and coating thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] A photocatalyst coating comprises a wrinkled graphene ball carrier and a titanium dioxide functional layer coated on the surface of the wrinkled graphene ball carrier. The wrinkled graphene sphere is obtained by a spray drying method, the wrinkled graphene sphere is an AB stacked structure, and the stacking thickness is 35 layers, I D / I G is 0.005. The particle size of nano-titanium dioxide is 3-6nm, and the mass ratio of wrinkled graphene balls and titanium dioxide is 1:0.2.

[0031] The present invention also provides a kind of photocatalyst coating and preparation method thereof, and photocatalyst coating is made up of above-mentioned photocatalyst coating, comprises following preparation steps:

[0032] (1) Spraying 1 part by weight of wrinkled graphene balls on the copper foil substrate to obtain a carrier layer;

[0033] (2) 0.2 parts by weight of nano-titanium dioxide, 0.02 parts by weight of chloroplatinic acid, and 0.01 parts by weight of sodium borohydride...

Embodiment 2

[0039] A photocatalyst coating comprises a wrinkled graphene ball carrier and a titanium dioxide functional layer coated on the surface of the wrinkled graphene ball carrier. The wrinkled graphene sphere is obtained by a spray drying method, the wrinkled graphene sphere is an AB stacked structure, and the stacking thickness is 35 layers, I D / I G is 0.005. The particle size of nano-titanium dioxide is 3-6nm, and the mass ratio of wrinkled graphene balls and titanium dioxide is 1:2.

[0040] The present invention also provides a kind of photocatalyst coating and preparation method thereof, and photocatalyst coating is made up of above-mentioned photocatalyst coating, comprises following preparation steps:

[0041] (1) 1 part by weight of crumpled graphene balls is sprayed on the aluminum foil substrate to obtain a carrier layer;

[0042] (2) 2 parts by weight of nano titanium dioxide, 0.1 part by weight of chloroplatinic acid, and 0.05 parts by weight of sodium borohydride w...

Embodiment 3

[0048] A photocatalyst coating comprises a wrinkled graphene ball carrier and a titanium dioxide functional layer coated on the surface of the wrinkled graphene ball carrier. The wrinkled graphene sphere is obtained by a spray drying method, the wrinkled graphene sphere is an AB stacked structure, and the stacking thickness is 35 layers, I D / I G is 0.005. The particle size of nano-titanium dioxide is 3-6nm, and the mass ratio of wrinkled graphene balls and titanium dioxide is 1:0.5.

[0049] The present invention also provides a kind of photocatalyst coating and preparation method thereof, and photocatalyst coating is made up of above-mentioned photocatalyst coating, comprises following preparation steps:

[0050](1) Spraying 1 part by weight of crumpled graphene balls on the artificial graphite film substrate to obtain a carrier layer;

[0051] (2) 0.5 parts by weight of nano-titanium dioxide, 0.05 parts by weight of chloroplatinic acid, and 0.02 parts by weight of sodium...

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Abstract

The invention belongs to the technical field of photocatalyst materials, and specifically relates to a photocatalyst coating, which includes a wrinkled graphene ball carrier and a titanium dioxide functional layer coated on the surface of the wrinkled graphene ball carrier, and the mass ratio of the wrinkled graphene ball to titanium dioxide is 1:0.2 ~2, I D / I G Less than 0.01; the wrinkled graphene sphere is an AB stack structure, and the stack thickness is greater than 30 layers. The invention also includes a photocatalyst coating and a preparation method thereof. The wrinkled graphene spheres used have thermal electron accumulation effect, reduce the potential barrier between graphene and titanium dioxide, and improve the light quantum efficiency. At the same time, the titanium dioxide modified by chloroplatinic acid and sodium borohydride As a functional layer, the valence structure of titanium atoms is increased, the band gap is reduced from multiple angles, and the expansion of light wavelength by titanium dioxide is promoted, finally realizing the photocatalyst applied to visible light and near-infrared light. The photocatalyst coating of the present invention not only expands the light absorption wavelength, enables the photocatalyst to be widely and efficiently applied under visible light, but also improves the energy utilization rate and reduces the cost.

Description

technical field [0001] The invention belongs to the technical field of photocatalyst materials, and in particular relates to a photocatalyst paint and a coating thereof. Background technique [0002] With the development of society, social materials have been greatly enriched. However, with the extensive use of chemical products, harmful gases such as formaldehyde will inevitably have an impact on the living and working environment, and even induce body diseases, seriously affecting people's health. [0003] Photocatalyst, also called photocatalyst, is a general term for semiconductor materials with photocatalytic function represented by nano-scale titanium dioxide. As early as the 1930s, scientists had discovered photocatalyst materials based on zinc oxide, which degraded harmful substances into harmless substances through photocatalysis, which brought hope for the improvement of human living environment. In particular, the discovery of Professor Kenichi Honda of the Univ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D1/00C09D5/00C09D7/61B05D7/14B05D7/00B05D7/24B05D3/02B05D3/14
CPCB05D3/0254B05D3/145B05D7/00B05D7/14B05D7/24B05D7/54B05D2202/25B05D2202/45B05D2203/30C09D1/00C09D5/00C09D7/61
Inventor 韩金沈宇鹏冯祎平马佳奇沈介泽仇涛磊钟明强
Owner 宁波派特勒新材料股份有限公司