Unlock instant, AI-driven research and patent intelligence for your innovation.

Degradable plastic with good heat resistance and preparation method thereof

A technology for degrading plastics and heat resistance, applied in the field of degradable plastics and its preparation, can solve the problems of mechanical strength, electrical insulation and chemical stability performance requirements, etc., to achieve improved thermal stability, strong flexibility, resistance The effect of high tensile strength

Pending Publication Date: 2020-12-11
深圳市百奥降解材料科技有限公司
View PDF2 Cites 1 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The existing degradable plastic technologies can be said to have their own advantages and disadvantages. The methods of simply relying on light, heat or biological / microbial degradation of plastics generally have limitations, and it is difficult to take into account the mechanical strength, electrical insulation, and chemical properties required for the practical use of degradable plastics. Stability and many other performance requirements

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Degradable plastic with good heat resistance and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0052] The second aspect of the present invention provides a method for preparing a degradable plastic with good heat resistance, and the specific steps include:

[0053] S1. In parts by weight, weigh 50-85 parts of base plastic, 2-8 parts of plasticizer, 5-12 parts of first filler, 3-10 parts of degradation agent, 0.5-1 part of stabilizer, and 0.8 parts of wetting agent - 2 parts are sent to a high-speed mixer for mixing for 5-10 hours, continue to add 1-3 parts of the second filler, and mix the raw materials for 1-2 hours to obtain a mixture;

[0054] S2. Send the mixed material obtained in S1 into the internal mixer for internal mixing and kneading to obtain the rubber compound;

[0055] S3. Send the rubber material obtained in S2 into a two-roll mill for mixing to obtain a molten material;

[0056] S4. The molten material obtained in S3 is fed into an extruder for plasticization, and then formed by a four-roller calender and shaped by a cooling wheel to obtain a shaped pl...

Embodiment 1

[0060] A degradable plastic with good heat resistance, its raw materials in parts by weight include: 84 parts of base plastic, 6 parts of plasticizer, 7 parts of degradation agent, 10 parts of first filler, 0.8 part of stabilizer, 1.2 parts of wetting agent Parts, 2 parts of the second filler.

[0061] The base plastic is PPO, the average molecular weight of PPO is 40000, purchased from Dongguan Guangyu Plastic Raw Material Co., Ltd.

[0062] The plasticizer is dimethyl phthalate and dibutyl oxalate, and the weight ratio of dimethyl phthalate and dibutyl oxalate is 3:1. Dimethyl phthalate was purchased from Guangzhou Liqing Trading Co., Ltd., with a CAS number of 131-11-3; dibutyl oxalate was purchased from Jinan Huifengda Chemical Co., Ltd., with a CAS number of 2050-60-4.

[0063] The degradation agent is PLA, PBS and PBAT, and the weight ratio of PLA, PBS and PBAT is 1:1:2.

[0064] The first filler is diatomite with a particle size of 35 μm, purchased from Lingshou Count...

Embodiment 2

[0075] A degradable plastic with good heat resistance, its raw materials include: 84 parts of base plastic, 6 parts of plasticizer, 7 parts of degradation agent, 10 parts of first filler, 0.8 parts of stabilizer, 1.2 parts of wetting agent, second Filling 2 parts.

[0076] The base plastic is PPO, and the average molecular weight of PPO is 40000.

[0077] The plasticizer is dimethyl phthalate and dibutyl oxalate, and the weight ratio of dimethyl phthalate and dibutyl oxalate is 3:1.

[0078] The degradation agent is PLA, PBS and PBAT, and the weight ratio of PLA, PBS and PBAT is 1:1:2.

[0079] The first filler is diatomite with a particle size of 74 μm, purchased from Jinan Ruifeng Chemical Co., Ltd.

[0080] The second filler is diatomite with a particle size of 74 μm, purchased from Jinan Ruifeng Chemical Co., Ltd.

[0081] The emollient is glyceryl laurate.

[0082] The stabilizer is 2-(2'-hydroxyl-3',5'-di-tert-phenyl)-5-chlorinated benzotriazole.

[0083] The specif...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
Particle sizeaaaaaaaaaa
Particle sizeaaaaaaaaaa
Particle sizeaaaaaaaaaa
Login to View More

Abstract

The invention relates to the technical field of high polymer materials, and particularly relates to degradable plastic with good heat resistance and a preparation method thereof. The plastic comprisesthe following raw materials in parts by weight: 50-85 parts of matrix plastic, 2-8 parts of a plasticizer, 3-10 parts of a degradation agent, 8-10 parts of a first filler, 0.5-1 part of a stabilizer,0.8-2 part of a humectant and 1-3 parts of a second filler. By adding a specific amount of the degradation agent, the plasticizer, the stabilizer and other raw materials, the thermal stability of thematrix plastic is effectively improved, the degradation rate of the plastic is increased, subsequent treatment of the waste plastic is further facilitated, and the plastic is green and environmentally friendly. The prepared plastic product is stable in performance, can still keep the advantages of high tensile strength, flame retardance and high flexibility of matrix plastic under a high-temperature condition, and is excellent in heat resistance. The method can be applied to various plastics, the preparation process is easy for quantitative production, the application field is wide, and the development prospect is good.

Description

technical field [0001] The invention relates to the technical field of polymer materials, in particular to a degradable plastic with good heat resistance and a preparation method thereof. Background technique [0002] Plastics are polymer compounds that are polymerized from monomers as raw materials through addition polymerization or polycondensation reactions. As an emerging material in the process of social development, plastics have been widely used in industry, agriculture and All aspects of people's lives provide great convenience for people's lives. However, the raw materials for the production of plastics mainly come from petrochemical resources, coupled with the fact that it is not easy to achieve natural degradation and recycling, which also makes it unfavorable to the sustainable development of the environment. [0003] Degradable plastic refers to the addition of some additives to promote its degradation or the use of renewable natural substances as raw material...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): C08L71/12C08L67/02C08L67/04C08K13/04C08K7/26C08K5/12C08K5/11C08K5/103C08K5/3475
CPCC08L71/123C08L2201/06C08L2201/08C08L2205/025C08L2205/035C08K2201/014
Inventor 吴超雄
Owner 深圳市百奥降解材料科技有限公司