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Carbon nanotube master batch and preparation method and application thereof

A carbon nanotube and masterbatch technology, applied in the field of carbon nanotube masterbatch and its preparation, can solve the problems of unstable production, fluctuation of material conductivity, dust pollution, etc., and achieves convenient production method, high degree of design freedom, high The effect of conductivity

Pending Publication Date: 2021-01-05
KINGFA SCI & TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Due to the low density of multi-walled carbon nanotubes (MWCNT) and the difficulty of dispersing, when used to prepare conductive polypropylene compositions, MWCNT is not easy to disperse and is likely to cause dust pollution in the production process, while currently commercially available MWCNT masterbatches are mostly In order to adopt the method of banburying and high shear for production, professional equipment technology and professional formula design are required at the same time. The degree of freedom of formula design is low and cumbersome, so an efficient, convenient and cost-saving preparation method of MWCNT masterbatch is needed To improve the dispersion of MWCNT in the matrix resin and reduce dust pollution in the production process
At the same time, because polypropylene is more difficult to achieve conductivity than other polar resins, there are relatively few reports on conductive polypropylene products on the market, and conventional solutions to achieve material conductivity will fail in polypropylene systems. Encountered the problems of extremely high dosage, unstable production and fluctuating material conductivity, so this field still needs to develop a simple and feasible method for preparing conductive polypropylene materials, which is also suitable for automotive interior and exterior trims that require electromagnetic shielding

Method used

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  • Carbon nanotube master batch and preparation method and application thereof
  • Carbon nanotube master batch and preparation method and application thereof
  • Carbon nanotube master batch and preparation method and application thereof

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Embodiment Construction

[0035] In order to better illustrate the purpose, technical solutions and advantages of the present invention, the present invention will be further described below in conjunction with specific examples. The following examples are only typical examples of the present invention, and the protection scope of the present invention is not limited thereto. In the following examples and comparative examples, the electrical conductivity test method is: the surface resistance of the material is tested according to ASTM D-4496 and D-257 standards; the test standard of impact strength is ISO 527; the test of flexural modulus is expressed as ISO 178 .

[0036] The main representative material used in embodiment and comparative example is as follows:

[0037] PP resin: polypropylene copolymer, with a melt mass flow rate of 40g / 10min at 230°C and a load of 2.16Kg, Sinopec Maoming;

[0038] MWCNT: tube diameter 8-15nm, length 10-70um, LG Chem;

[0039] Filler 1 (talcum powder): particle s...

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Abstract

The invention discloses a carbon nanotube master batch which comprises the following components in parts by weight: 50-80 parts of PP resin, 10-40 parts of a filler, 3-10 parts of MWCNT and 0.1-3 parts of auxiliaries, wherein the MWCNT is a multi-walled carbon nanotube, and the filler is at least one of talcum powder, calcium carbonate, barium sulfate and glass fiber. According to the carbon nanotube master batch disclosed by the invention, the MWCNT master batch with high dispersion degree can be prepared under the condition of common double-screw extrusion by controlling all the components and contents, and the problem that the MWCNT structure is easily damaged due to the fact that professional equipment is required to be used for banburying in the traditional master batch preparation issolved. Meanwhile, the invention also discloses a preparation method and application of the carbon nanotube master batch.

Description

technical field [0001] The invention relates to the field of polymer material modification, in particular to a carbon nanotube masterbatch and a preparation method and application thereof. Background technique [0002] As a cost-effective general-purpose plastic, polypropylene (PP) has excellent mechanical properties after toughening and modification, and is easy to form and process. It is widely used in home appliances and automotive products. [0003] In the future automotive automated driving technology, automatic cruise control (ACC), collision avoidance system (CA) and lane change assistance systems will use millimeter-wave radar in large quantities, and with the development of technology, 77GHz millimeter-wave radar will be widely industrialized in the industry and Replacing 24GHz millimeter-wave radar has become the mainstream of automotive millimeter-wave radar applications. In this case, radar anti-jamming is particularly important. [0004] Due to the low density ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/14C08L23/12C08L23/08C08K13/02C08K3/04C08K3/34C08K5/098C08J3/22
CPCC08J3/226C08J2323/14C08J2323/12C08J2423/14C08J2423/12C08J2423/08C08K13/02C08K3/04C08K3/34C08K5/098C08K2201/003C08K2201/004C08K2201/011C08K2201/005C08K3/041C08K2201/001
Inventor 卢朝亮叶南飚黄险波杨波吴亦建吴志强苏娟霞罗忠富
Owner KINGFA SCI & TECH CO LTD
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