485 results about "Barium sulphate" patented technology

The invention discloses a water-borne epoxy resin coating which comprises a component A and a component B, the component A is prepared from 60 to 80 parts of 50 percent modified water-borne epoxy resin emulsion, 5 to 15 parts of deionized water, 0.5 to 1 part of wetting dispersant, 0.2 to 0.8 part of defoaming agent, 5 to 10 parts of modified zinc phosphate, 3 to 5 parts of ion exchange antirust pigment, 4 to 6 parts of sericite powder, 3 to 5 parts of glass flake, 5 to 10 parts of precipitated barium sulphate, 1 to 5 parts of nano silicon dioxide and 0.5 to 1 part of rheological additive; 1 to 2 parts of modified organic bentonite slurry; 0.1 to 0.3 part of a pH conditioning agent; and 0.2 to 0.8 part of a flash rust inhibitor. The component B is prepared from 40 to 50 parts of waterborne epoxy-amine adduct, 20 to 30 parts of 50 percent modified polyamide curing agent, 5 to 15 parts of 60 percent Mannich base phenolic aldehyde amine curing agent, 0.5 to 1.5 parts of epoxy silane coupling agent, 1 to 2 parts of nonionic surfactant and 15 to 20 parts of deionized water. The emulsion stability of the waterborne epoxy resin coating is improved through a bisphenol A / F mixed epoxy emulsion and a grafted polyethylene glycol hydrophilic chain segment.

The invention belongs to the technical field of drilling fluid, and particularly relates to a free radical polymerization water-based drilling fluid composition and a preparation method thereof. The invention relates to a core-shell composite particle-containing water reducer which comprises deionized water, salts (NaCl / KCl), alkalis (Na2CO3 and NaOH), barium sulfate and core-shell composite particles X. The particle is composed of a silicon dioxide core and a polymer shell layer, and the shell layer is formed by free radical copolymerization of acrylamide, 2-acrylamido-2-methylpropanesulfonic acid and acrylic acid and is covalently connected with the core through silanization treatment. Under the conditions of high salinity, strong alkali and high solid phase weighting, the drilling fluid simultaneously realizes the following effects: (1) high-density bearing and low-viscosity pumpability are realized; (2) compact plugging and water loss reduction and low formation damage flowback can be realized; and (3) stable rheology rock carrying, lubrication and friction resistance reduction. The problem that three aspects of performance are difficult to consider in the prior art is solved, and the drilling fluid is suitable for drilling of deep wells, ultra-deep wells and complex stratums and has remarkable industrial application value.

The invention relates to the technical field of polypropylene materials, in particular to a self-cleaning and scratch-resistant composite PP material and a preparation method thereof.The composite PP material is prepared from, by weight, 55-75 parts of polypropylene resin, 4-10 parts of filler, 1-3 parts of scratch-resistant agent, 5-10 parts of compatilizer, 1-5 parts of surfactant, 0.1-0.5 part of antioxidant and 0.7-1.5 parts of lubricant; the scratch-resistant agent is silicone powder; the filler is a micron-sized filler and a nano-sized filler, the micron-sized filler is one or two of barium sulfate and calcium sulfate, and the nano-sized filler is modified nano silicon carbide or a mixture of modified nano silicon carbide and hydrophobic modified gas-phase nano silicon dioxide; the modified nano silicon carbide is characterized in that the surface of nano silicon carbide is modified through a silane coupling agent; the self-cleaning composite PP material has the advantage that the scratch resistance of the self-cleaning composite PP material is improved.

The invention discloses a nano two-dimensional sheet modified flexible wear-resistant fluorocarbon coating as well as preparation and application thereof. The nano two-dimensional sheet modified flexible wear-resistant fluorocarbon coating comprises paint and an isocyanate curing agent in a mass ratio of (7-10): 1, the paint vehicle comprises the following components in parts by mass: 15-25 parts of an organic solvent, 30-40 parts of fluorocarbon resin, 5-10 parts of castor oil polyol, 1-3 parts of a dispersing agent, 0.5-1 part of a defoaming agent, 20-30 parts of titanium dioxide, 10-20 parts of barium sulfate, 0.1-1 part of a nano two-dimensional sheet, 0.5-2 parts of a thickening agent and 0.1-1 part of a flatting agent; according to the invention, after the castor oil polyol is added into the fluorocarbon resin for mixing and dissolving, in the curing process, hydroxyl of the castor oil polyol can be cured with isocyanate to form a film, and a polyurethane-fluorocarbon interpenetrating polymer network is formed, so that the flexibility of the fluorocarbon coating is improved; meanwhile, the flexibility and wear resistance of a coating film can be improved by adding the nano two-dimensional sheet into the paint vehicle, and the nano two-dimensional sheet modified flexible wear-resistant fluorocarbon coating disclosed by the invention is good in wear resistance and flexibility.

A “Passive Radiative Coating” (PRC) is designed to dissipate heat generated mainly by solar radiation, intended for use in the manufacture of overhead conductors and cables. Additionally, this coating can dissipate heat produced by the conductors themselves, known as the Joule effect, providing environmental protection and significantly improving heat dissipation capacity. The PRC is composed of at least one filler, at least one binder, and at least one surfactant. In particular, the use of calcium carbonate and / or barium sulfate as fillers, and epoxy resins, alkyd varnishes, polyurethane dispersions, casting resins, silicone-based varnishes, and sodium silicate as binders are highlighted. The surfactant is used to stabilize the mixture and acts as a stabilization additive.

The invention relates to the technical field of high polymer materials, in particular to a light-aging-resistant flame-retardant ABS material for an electric fitting box and a preparation method of the light-aging-resistant flame-retardant ABS material. Comprising the following raw materials: ABS resin, AS resin, ABS high rubber powder, CPE, bromotriazine, carrier-free antimony trioxide master batch, a flame retardant synergist, precipitated barium sulphate, titanium dioxide, a main antioxidant, an auxiliary antioxidant, a lubricant, an anti-dripping agent, a dispersing agent and an ultraviolet absorbent. The material has excellent flame retardant property, and the synergistic effect of the flame retardant components such as the bromotriazine and the like reaches a high flame retardant grade; the ultraviolet absorbent and the titanium dioxide can delay aging and stabilize the color; the melt flow rate is high, and the fluidity is improved through cooperation of high-melt-index ABS and low-molecular-weight AS resin; the mechanical property is good, and the raw materials cooperate to guarantee strength and toughness; the appearance quality is good, pocking marks are avoided, and the glossiness is good. The preparation process is simple, and conventional equipment and reasonable parameters ensure stability and operability.

The present invention addresses the problem of providing a curable resin composition having excellent abradability and excellent chemical resistance and permeation resistance during printing. [Solution] A curable resin composition comprising (A) an epoxy resin, (B) an epoxy resin curing agent, and (C) an inorganic filler, the (C) inorganic filler comprising at least three types of silica (C1), calcium carbonate (C2), and barium sulfate (C3).

The invention provides an environment-friendly self-repairing single-component waterborne polyurethane waterproof coating and a preparation method thereof. The environment-friendly self-repairing single-component waterborne polyurethane waterproof coating is prepared from the following components in percentage by mass: 35 to 45 percent of waterborne hyperbranched polyurethane resin, 10 to 15 percent of titanium dioxide, 15 to 20 percent of barium sulfate, 5 to 10 percent of modified quartz powder, 0.1 to 1 percent of a thickening agent, 0.2 to 0.3 percent of a sterilizing agent, 3.5 to 6.5 percent of an auxiliary agent and the balance of water. The waterproof coating contains certain fluorine atoms, so that a paint film has relatively stable long-acting hydrophobic performance after being dried, and the paint film can be kept clean and self-cleaning for a long time; in addition, the modified quartz powder has the effect of enhancing the mechanical property and stability of the paint film; and meanwhile, the paint film forms a compact network structure in the drying process, so that the paint film has relatively good flexibility and relatively high hardness. In addition, the components contain more active groups, so that the paint film can be self-repaired.

The invention belongs to the technical field of wear-resistant coatings, and particularly relates to a wear-resistant coating for a metal plate of a compressed garbage truck and a preparation method of the wear-resistant coating. The invention aims to solve the problem that an existing coating for the metal plate of the garbage truck is difficult to keep good protection performance under corrosion and abrasion. The preparation method comprises the following steps: carrying out pre-reaction grafting modification on epoxy resin and amine-terminated polyether to obtain an epoxy prepolymer; alpha-aluminum oxide and barium sulfate are mixed, dispersed, ground and subjected to surface activation, and a basic filler is obtained; adding a mica filler into the basic filler, and shearing and mixing to obtain a composite filler; mixing the epoxy prepolymer with a phosphate auxiliary agent to obtain a primer; dispersing and mixing the epoxy prepolymer and the composite filler to obtain a functional coating; after a metal base material is subjected to sand blasting treatment, primer is pre-sprayed on the surface of the metal base material, and then functional paint is covered and sprayed to obtain the wear-resistant coating. The wear-resistant coating prepared by the invention can keep good protection performance under corrosion and wear, and has high application value.

The invention discloses anti-radiation hydrogel capable of being used for interventional radiosurgery and a preparation method and application thereof.The anti-radiation hydrogel is in bridge connection with polymer chains of sodium alginate and sodium hyaluronate through the physical interaction between Fe < 3 + > and carboxyl, and the reversible interaction between Fe < 3 + > and carboxyl endows the hydrogel with the shear thinning characteristic; the injectability is ensured; the bismuth oxide nano-particles and the barium sulfate nano-particles are doped to achieve efficient attenuation of X-rays in the range of 20-100 keV, and meanwhile, the complementary K-edge absorption characteristics of the bismuth oxide nano-particles and the barium sulfate nano-particles are utilized, and the radiation absorption effect of a hydrogel network structure is combined, so that broad-spectrum radiation protection is achieved; according to the invention, acrylamide is taken as a raw material, an interpenetrating network elastic hydrogel of three polymers is formed under the action of polymerization under thermal initiation of acrylamide, the conversion from an injectable state to a solid state is realized, and at the moment, the cured hydrogel has tough mechanical properties, can also form a protective layer similar to gloves, and can be used for radiation protection in interventional operations.

To provide a coating composition capable of forming a coating film excellent in blocking resistance and anticorrosion properties.SOLUTION: The coating composition contains: (A-1) at least one pigment having an aspect ratio of 1 or more and less than 5 and selected from barium sulfate, silica, and calcium carbonate; and (A-2) a scaly pigment having an average particle diameter of 2-30 μm and an aspect ratio of 5 or more and less than 30. The mass ratio of (A-1):(A-2) is within the range of 90:10-70:30.SELECTED DRAWING: None

To provide an aqueous coating composition which enables formation of a metallic coating film having high designability, and enables formation of a coating film exhibiting good coating film physical property.SOLUTION: An aqueous coating composition set for multilayer coating film formation contains a first base coating composition forming a first base coating film, and a second base coating composition forming a second base coating film, wherein the first base coating composition contains a first coating film forming resin, a first curing agent, a first inorganic brightener and a first hydrophobic association type viscous agent, the first inorganic brightener is one or more kinds selected from the group consisting of silica, talc, calcium carbonate, kaolin, barium sulfate, and diatomaceous earth, the second base coating composition contains a second coating film forming resin, a second curing agent, a second bright material, a second inorganic viscous agent, a second hydrophobic association type viscous agent, and a second dispersion agent, and the second inorganic viscous agent contains a layered material having such a laminated structure that a large number of inorganic crystal layers are laminated.SELECTED DRAWING: None

The invention relates to a tinting base for a tinted coating composition, in particular for forming a tinted coating on a board material, comprising - at least one organic polymer binder with a glass transition temperature (TG) according to EN ISO 16805 > 45°C, preferably > 50°C, furthermore preferably > 55°C, - at least one filler made of barium sulfate and / or calcium carbonate, having (iii) an average particle size D50 of 1-20 µm, preferably of 1-15 µm, furthermore preferably of 2-10 µm, and (iv) an oil absorption according to DIN EN ISO 787-5 of 1-22 g / 100 g, preferably of 2-18 g / 100 g, furthermore preferably of 3-15 g / 100 g, - at least one wax, - conventional additives and - water. The invention further relates to a tinted coating composition for forming a tinted coating on a panel material.

The utility model discloses a liquid-phase synthesis system of lithium sulfide. Comprising a first lithium sulfate dissolving device, a first barium sulfide dissolving device, a chemical combination reaction device, a first separation device and a second separation device, the liquid phase after-treatment unit is used for concentrating, purifying and drying the liquid phase to obtain lithium sulfide, and the solid phase after-treatment unit is used for washing and drying the solid phase to obtain barium sulfate; the first lithium sulfate dissolving device and the first barium sulfide dissolving device are both connected with a raw material inlet of the combination reaction device; and a reaction product outlet of the combination reaction device is connected with the first separation device. The liquid-phase synthesis system of the lithium sulfide has the advantages that products are easy to separate, the purity of the lithium sulfide products is high, the liquid-phase synthesis system of the lithium sulfide is very suitable for industrial-scale production, and the produced high-purity anhydrous lithium sulfide is very suitable for solid-state battery anode materials and has huge potential economic benefits.

The application relates to the technical field of paint, and particularly discloses a water-based insulating paint and a preparation method; the water-based insulating paint comprises components A and B, the mass ratio of the components A and B is (7-9):1, the component A comprises the following raw materials in parts by weight: deionized water 100-150 parts, bentonite 3-8 parts, fumed silica 3-8 parts, titanium white 40-80 parts, barium sulfate 90-110 parts, mica powder 40-60 parts, zinc phosphate 60-80 parts, feldspar powder 40-60 parts, epoxy emulsion 400-500 parts, base material wetting agent 3-5 parts and dispersant 30-80 parts; the component B comprises the following raw materials in parts by weight: curing agent 40-60 parts and solvent 40-60 parts; the dispersant comprises a sulfonate dispersant and a polycarboxylate dispersant; the application promotes the insulating performance of the paint through the synergistic effect of various components, reduces the agglomeration of particles in the paint system, and improves the dispersing performance of the paint.

The invention relates to the technical field of sound insulation materials, in particular to a high-performance sound insulation material for buildings and a preparation method thereof, and the high-performance sound insulation material comprises the following raw materials in parts by weight: 60-80 parts of polypropylene, 15-25 parts of filler, 10-20 parts of talcum powder, 5-15 parts of flexibilizer, 0.2-1 part of antioxidant and 0.2-0.4 part of light stabilizer. According to the invention, the SEBS with high damping performance is utilized to provide a main viscoelastic effect, and the density performance of the material can be directly increased by combining the barium sulfate material with high density, so that the low and medium frequency sound insulation function is improved, and the hollow glass beads can utilize the spherical surfaces to cause scattering and refraction of sound waves and disturb the propagation direction of the sound waves in the hollow glass beads; meanwhile, in cooperation with the high radius-thickness ratio state of the mica sheet, sound waves are further dispersed and refracted in combination with the hollow glass beads, the conduction path of the sound waves is prolonged, and therefore the medium-high frequency sound insulation performance is improved, and the sound insulation performance of the material is effectively improved.

This application discloses a method for producing an anticorrosion coating having excellent adhesion to rusted, low-treatment surfaces, which relates to the field of paint chemical industry. The anticorrosion coating comprises Component A and Component B, where Component A comprises an epoxy resin, double-coated hollow glass microbeads, a thixotropic agent, a wetting and dispersing agent, a pigment, barium sulfate, talc, Solvent A, an antifoaming agent, a first silane coupling agent, and an aluminum powder paste, and Component B comprises a curing agent, an accelerator, and Solvent B.

The invention belongs to the technical field of water treatment, and particularly discloses a green scale inhibitor for barium sulfate and a preparation method thereof, the scale inhibitor is a product generated by esterification reaction of polysuccinimide and hydroxyethyl methylacrylate under alkaline conditions, and a copolymer formed by graft copolymerization of aconitic acid and sodium lignin sulfonate, wherein the mass ratio of polysuccinimide to hydroxyethyl methylacrylate to aconitic acid to sodium lignin sulfonate is 2: 4: (1-6): (1-4). The scale inhibitor is a composite copolymer formed by polymerizing and grafting a product obtained after esterification of polysuccinimide / hydroxyethyl methylacrylate, aconitic acid and sodium lignin sulfonate, has carboxyl, hydroxyl, amino, sulfonic acid and other groups at the same time, and can generate strong interaction with key ions or sites in the BaSO4 crystal growth process, so that the scale inhibitor can be used for inhibiting the growth of BaSO4 crystals. The normal growth and aggregation of BaSO4 crystals are prevented, so that the formation of BaSO4 scales is effectively inhibited.

The invention discloses a high-temperature-resistant composite nanofluid scale inhibitor and a preparation method thereof, and belongs to the technical field of oilfield chemistry. The composite nano fluid scale inhibitor is prepared from modified graphene oxide nano AP-GO, a calcium-based nano modifier calcium-based polysulfonic acid Ca-PAMPS, a surfactant, an inorganic salt and deionized water, the calcium-based nano modifier calcium-based polysulfonic acid contains a large amount of sulfonic acid, carboxylic acid and hydroxyl groups, has strong hydrophilicity, calcium ion tolerance and calcium ion chelating property, and has a good scale inhibition effect on calcium carbonate scale and barium sulfate scale; meanwhile, the modified graphene oxide nanoparticles have large-scale conjugated rings, a large amount of carboxylic acid and hydroxyl groups, and have synergistic interaction with calcium-based polysulfonic acid under the action of anion shielding and large steric hindrance effects, so that the high temperature resistance and scale inhibition performance of the nano scale inhibitor are further improved, a good scale inhibition effect is achieved, and the problems of oilfield water injection and fracturing flowback scaling are effectively solved; good popularization prospects are realized.

The invention provides a long-acting anticorrosive epoxy powder coating and a preparation method thereof. The coating comprises epoxy resin, polyester resin, thiadiazole corrosion inhibitor loaded cerium-doped hydrotalcite composite particles, silane modified mica iron oxide, zinc phosphate, barium sulfate and the like. The core innovation lies in that 2-amino-5-(4-hydroxyphenyl)-1, 3, 4-thiadiazole corrosion inhibitor molecules are designed and synthesized, the molecules are loaded between cerium-doped magnesium-aluminum hydrotalcite nano container layers through an anion exchange method, corrosion environment pH responsive gradient release is achieved, a coating constructs a passive shielding, active corrosion inhibition and interface anchoring triple protection mechanism in the coating, and the corrosion resistance of the coating is improved. The neutral salt spray test resistance exceeds 2000h, and the coating is suitable for long-acting corrosion protection of iron accessories and cable bridges.

The invention provides a high-weather-resistance powder coating and a preparation method thereof, and belongs to the technical field of powder coatings. According to the invention, a hyperbranched polyester skeleton is constructed through esterification reaction of trimethylolpropane, adipic acid and maleic anhydride, hydroxyl-terminated polyether, pentaerythritol and 2, 4-dihydroxybenzophenone are introduced to adjust flexibility, thermal stability and ultraviolet aging resistance, and allyl glycidyl ether is utilized to improve chemical activity and network stability; phosphorus-containing heterocyclic ring-polynitrogen imide oligomer is generated through substitution reaction and subsequent modification of phosphonitrilic chloride trimer, aniline and ethanolamine, and the coating is endowed with flame retardance, heat resistance and adhesive force. In the preparation of the coating, carboxyl polyester resin and a curing agent are crosslinked to form a three-dimensional network, and filler and auxiliaries such as precipitated barium sulfate, silica powder and bismuth vanadate yellow pigment are combined, so that the mechanical strength, chemical resistance and ultraviolet aging resistance of a coating film are optimized.

The invention provides an additive for negative electrode lead paste of an ultralow-temperature lead storage battery, a preparation method of the negative electrode lead paste of the ultralow-temperature lead storage battery and the ultralow-temperature lead storage battery. The additive for the negative electrode lead paste of the ultralow-temperature lead storage battery comprises the following components in parts by mass: 4-5 parts of sodium lignosulfonate, 1-3 parts of L-cysteine, 1-2 parts of monopotassium phosphate, 2-3 parts of acetylene black, 0.5-1 part of graphene, 6-8 parts of barium sulfate, 1-2 parts of bismuth oxide and 1-1.5 parts of polyester staple fibers. According to the invention, L-cysteine and monopotassium phosphate which have a decisive effect on the realization of the ultralow-temperature capacity of an ultralow-temperature battery product are introduced, and the L-cysteine and the monopotassium phosphate are matched and cooperated to promote the realization of the ultralow-temperature charging and discharging capacity.

The invention discloses a protective base film for optical cement, comprising: a core layer sandwiched between a first surface layer and a second surface layer; the core layer comprises first polyester; each of the first surface layer and the second surface layer comprises first polyester and functional master batches in a mass ratio of (45-50): (50-55), and the functional master batches comprise polyethylene naphthalate, second polyester and modified barium sulfate. The dispersity is improved by mixing the functional master batch and the first polyester, so that the haze and the light transmittance of the base film are optimized; through the functional master batch prepared from the polyethylene naphthalate, the heat resistance and the stability of the base film are optimized, the transmittance of the base film is improved, and the haze is reduced.

The invention discloses a passive radiation cooling powder coating and a preparation method of a refrigeration coating, and relates to the technical field of powder paints.The specific powder combination of titanium dioxide, barium sulfate, aluminum oxide and zirconium silicate is added into a powder coating formula, so that the solar reflectivity of the coating cured on a substrate is increased to 85% or above, and the coating has the advantages of being high in heat resistance, good in heat resistance and the like. Meanwhile, the infrared emissivity is improved to 90% or above, a synergistic cooling effect is generated, and the material is an ideal radiation refrigeration material.

A low-absorption and high-emission thermal control coating resistant to high-dose ionizing radiation and its preparation method, which relates to the field of spacecraft thermal control coatings. The thermal control coating includes a bottom coating, a middle coating, and a top coating sequentially arranged on the surface of a substrate; the bottom coating includes barium sulfate, cerium oxide, and a binder; the middle coating includes hollow glass microspheres, a binder, and an inorganic dispersant; the top coating includes indium tin oxide and a binder. It greatly increases the scattering ability of different spectral energies of sunlight and the tolerance to vacuum ionizing radiation, enabling it to meet the design requirements of high precision and long life of modern new spacecraft.

The invention provides a powder coating gypsum board with scratch resistance and a preparation method thereof, and belongs to the technical field of paints.The preparation method comprises the following steps that modified polyester, modified glass beads, polytetrafluoroethylene, barium sulfate, titanium dioxide, a flatting agent and a curing agent are mixed and stirred, melt extrusion is conducted, tabletting is conducted after cooling, smashing, grinding and sieving are conducted, and the powder coating gypsum board is obtained. Powder coating is obtained; and sanding and dedusting the surface of the gypsum board substrate, electrostatically spraying the powder coating onto the surface of the substrate, heating, curing and cooling to obtain the gypsum board. Wherein the modified polyester is prepared from polyester, a reinforcing agent and 3-glycidyl ether oxypropyl triethoxy silane. The powder coating gypsum board prepared by the invention has excellent scratch resistance, impact resistance and wear resistance.

The invention discloses a self-crosslinking exterior wall coating containing reinforcing fibers and a preparation method thereof. The coating comprises the following components by mass: 10-20% water, 0.1-0.5% bentonite, 0.1-0.5% cellulose, 3-8% reinforcing fibers, 0.5-2% ethylene glycol, 0.5-1.5% dispersant, 0.1-0.5% wetting agent, 0.1-0.3% multifunctional additive, 15-25% titanium dioxide, 8-15% precipitated barium sulfate, 2-8% silane-modified nano-silica, 5-10% water-based polyurethane emulsion, 30-40% organosilicon-modified acrylic emulsion, 1-3% film-forming aid, 0.1-0.3% bactericide, 0.1-0.2% preservative, 0.5-1% mildew inhibitor, 0.3-1.1% defoaming agent, and 0.5-1.8% leveling agent. By compounding silicone-modified acrylic emulsion and water-based polyurethane emulsion, and adding silane-modified nano-silica and reinforcing fibers, the coating has excellent resistance to artificial weathering, wear resistance, impact resistance, corrosion resistance and high hardness.

The invention discloses a carbonate reservoir fracture permeability test method, and relates to the technical field of ore exploration, the test steps are as follows: S1, blending a tracer agent: preparing iohexol, iopamidol and barium sulfate suspension, and blending to obtain the tracer agent; s2, injecting the prepared tracer agent into the rock stratum, and waiting for diffusion of the tracer agent; s3, a CT scanning device is used for scanning the rock stratum, the flowing path of the tracer agent on the rock stratum is tracked, image data are collected and obtained, and the collected data image is preprocessed; and S4, constructing a three-dimensional model of the crack network by using a three-dimensional imaging technology, displaying a three-dimensional flow path of the tracer agent in the crack, analyzing the acquired CT image data, and measuring to obtain the concentration distribution of the tracer agent at different positions. By means of the tracer agent injection method, the rock stratum fracture permeability closer to the actual situation is obtained, and a more reliable basis is provided for development and evaluation of carbonate rock reservoirs.

The invention belongs to the technical field of material chemistry, and relates to nano barium sulfate and a preparation method thereof. The invention provides a preparation method of nano barium sulfate, which comprises the following steps: adding a barium acetate solution, sulfhydrylated chitosan and sodium stearate into a sodium sulfate solution for mixing reaction, collecting the obtained product after the reaction is ended, filtering, drying and grinding to obtain the nano barium sulfate, the concentration of the sodium sulfate solution is 1.4 to 2.6 mol / L, and the concentration of the barium acetate solution is 1.4 to 2.6 mol / L; 0.05 to 0.15 g of thiolated chitosan and 0.05 to 0.15 g of sodium stearate are correspondingly added into each 100 mL of the sodium sulfate solution. The invention solves the technical problems of high particle size and non-uniform particle size distribution of nano barium sulfate particles when the nano barium sulfate particles are prepared by adopting a direct precipitation method.

The invention discloses a solvent-free epoxy anticorrosive coating and a preparation method thereof, and relates to the technical field of coatings. The invention discloses a solvent-free epoxy anticorrosive coating. The coating comprises the following raw materials in parts by weight: 40-60 parts of modified epoxy resin, 5-10 parts of modified nano zinc oxide, 15-25 parts of a polyamide curing agent, 5-10 parts of butyl glycidyl ether, 10-15 parts of titanium dioxide, 8-12 parts of talcum powder, 5-8 parts of barium sulfate, 0.5-1 part of an organic silicon defoaming agent, 0.5-1 part of an acrylate flatting agent, 1-2 parts of a silane coupling agent KH-550 and 3-5 parts of carboxyl-terminated nitrile rubber. And 1-2 parts of fumed silica. The solvent-free epoxy anticorrosive paint adopts a solvent-free formula, and is environment-friendly and low in volatility. The modified epoxy resin and the modified nano-zinc oxide have a synergistic effect, a chain is accurately controlled through'water diversion-viscosity feedback ', and molecular weight distribution is narrow. The pigment filler is uniformly dispersed at a high speed after being pretreated by the silane coupling agent, and is matched with the defoaming agent and the leveling agent, so that the coating has good leveling property, few bubbles, accurate viscosity regulation and control and stable and reliable comprehensive performance.