Carbon dioxide foam fracturing system foaming agent as well as preparation method and application thereof

A carbon dioxide and foaming agent technology, which is applied in chemical instruments and methods, drilling compositions, etc., can solve the problem that the foaming agent has poor acid resistance, poor temperature resistance, no biodegradability, and affects the foam stability of foam fracturing fluid. effect and other issues, to achieve the effect of high foaming height and long half-life

Active Publication Date: 2021-01-08
SHAANXI YANCHANG PETROLEUM GRP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The foaming agents used in conventional fracturing are mostly anionic surfactant system or cationic surfactant system, the foaming agent of anionic surfactant system is incompatible with high salinity fracturing fluid and formation water, while The foam stabilizer of the cationic surfactant system is seriously absorbed by the sandstone formation rock, which affects the foam stabilization effect of the foam fracturing fluid
Moreover, the foaming agent used in conventional fracturing has poor acid resistance and temperature resistance, and is not biodegradable, so it is not suitable for acidic CO 2 foam fracturing

Method used

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  • Carbon dioxide foam fracturing system foaming agent as well as preparation method and application thereof
  • Carbon dioxide foam fracturing system foaming agent as well as preparation method and application thereof
  • Carbon dioxide foam fracturing system foaming agent as well as preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] A carbon dioxide foam fracturing system foaming agent, based on 100% by weight, including the following raw materials: 38% polyoxyethylated carboxybetaine, 5% sodium fluorocarbon lauryl polyoxyethylene ether ethylene diformate monoester sulfonate , Welan gum 0.05%, ethanol 5%, and the balance is water.

[0024] It can be prepared by mixing and stirring the raw materials evenly.

Embodiment 2

[0026] A carbon dioxide foam fracturing system foaming agent, based on 100% by weight, comprising the following raw materials: polyoxyethylated carboxybetaine 40%, fluorocarbon lauryl polyoxyethylene ether ethylene glycol monoester sulfonate sodium 6% , Welan gum 0.1%, ethanol 5%, and the balance is water.

[0027] It can be prepared by mixing and stirring the raw materials evenly.

Embodiment 3

[0029] A carbon dioxide foam fracturing system foaming agent, based on 100% by weight, including the following raw materials: 42% polyoxyethylenated carboxybetaine, 8% sodium fluorocarbon lauryl polyoxyethylene ether ethylene diformate monoester sulfonate , Welan gum 0.05%, ethanol 7.5%, and the balance is water.

[0030] It can be prepared by mixing and stirring the raw materials evenly.

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Abstract

The invention discloses a carbon dioxide foam fracturing system foaming agent which is prepared from the following raw materials in percentage by weight: 38-42% of zwitterionic surfactant, 5-8% of C12-18 nonionic surfactant, 0.05-0.2% of high-molecular compound, 5-10% of solvent and the balance of water. Wherein the zwitterionic surfactant is any one of didodecyl methyl carboxyl glycine betaine, adamantyl glycine betaine, dicarboxyl glycine betaine and polyoxyethylene carboxyl glycine betaine. Meanwhile, the invention further discloses a preparation method and application of the foaming agent.The foaming agent has good temperature resistance, acid resistance and salt resistance, and is suitable for being used in a carbon dioxide foam fracturing system.

Description

technical field [0001] The invention belongs to the technical field of oil and gas field exploitation, and in particular relates to a carbon dioxide foam fracturing system foaming agent and its preparation method and application. Background technique [0002] Foam fracturing fluid is a gas-in-liquid emulsion, which is a uniform dispersion of a large amount of gas in a small amount of liquid. The development of foam fracturing fluid at home and abroad has gone through the following four stages: the first generation foam fracturing fluid: water + foaming agent, easy to flow back after fracturing, and can be used for low-pressure gas well fracturing; the second generation foam fracturing fluid: water + foaming agent + polymer, the fracturing fluid has high viscosity and high stability, and is suitable for high-pressure oil and gas reservoir fracturing; the third generation foam fracturing fluid: water + foaming agent + polymer + fracturing fluid, viscosity And the stability is...

Claims

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Application Information

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IPC IPC(8): C09K8/60C09K8/70
CPCC09K8/703C09K8/602
Inventor 何静段玉秀吴金桥郭锦涛王仙仙
Owner SHAANXI YANCHANG PETROLEUM GRP
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