The invention provides a composite additive for an electrolytic
copper foil, a preparation method of the electrolytic
copper foil and the electrolytic
copper foil, and belongs to the technical field of electrolytic copper foils. The
lithium battery
copper foil additive is an
aqueous solution and comprises an agent A, an agent B, an agent C and an agent D. The agent A is one or more of
sodium hydroxymethyl sulfonate,
sodium 3-mercaptopropanesulfonate and
sodium N, N-mercaptopropanesulfonate, the agent B is one or more of fish
gelatin, polyethyleneimine and
polyacrylamide, the agent C is polyoxyethylene
polypropylene ether and
polypropylene glycol, and the agent D is one or more of
polyethylene glycol,
polyethylene glycol and
polyethylene glycol. The agent D is one or more of cyclopentyl methyl
ether and a water-soluble additive with the code name of HG. The action mechanism of the composite additive
system in the
electrolysis process is explored, the optimal composite additive proportion is explored according to the additive action mechanism under the standard
electrolysis process parameters, and the
copper foil good in appearance and
mechanical property is prepared; and the characteristics of tensile strength, elongation, roughness, purity, uniformity, surface
wetting tension and the like are excellent.