High-aluminum-content fine-grain low-density full-high-temperature ferrite steel and preparation method thereof

A technology of high-temperature ferrite and ferritic steel, which is applied in manufacturing tools, heat treatment equipment, and improving energy efficiency, etc. It can solve the problem of limiting the original size of slabs, the final size of plates, high cost of rare earth elements, and low corrosion resistance. problems, to achieve the effect of improving pitting corrosion resistance and intergranular corrosion resistance, marine atmospheric corrosion resistance, and good mechanical properties

Active Publication Date: 2021-01-15
UNIV OF SCI & TECH BEIJING
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  • Abstract
  • Description
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  • Application Information

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Problems solved by technology

The alloy composition provided in this patent CN110066969B, the content of Ni, Mo, and Nb elements in the composition system is relatively high. This patent mainly uses Mo solid solution in δ ferrite to improve pitting resistance and intergranular corrosion resistance. Ni is dissolved in δ ferrite to improve corrosion resistance, but Ni and Mo elements are more expensive alloy elements, and the cost is higher
This patent uses Nb to inhibit grain growth and refine δ ferrite grains, but Nb also has the effect of inhibiting recrystallization, so it can be predicted that Nb has limited effect on δ ferrite grain refinement, and at the same time, the cost of Nb element is relatively high
This patent uses rare earth elements to refine δ ferrite grains and improve corrosion resistance, but the cost of rare earth elements is also high, and the smelting process is extremely difficult to control
In addition, the rolling process provided by this patent is complicated, the rolling direction needs to be changed during the rolling process, the demand for equipment is high, and the original size of the slab and the final size of the plate are also limited
Therefore, the preparation process of this patent is complex, there are many technical problems that are not conducive to industrial production and application, and the cost is relatively high
[0004] Patent Nos. CN103484771B and CN106498278 both disclose the preparation method of non-full delta ferritic low-density steel. The final structure is a multi-phase structure. Due to the different alloy content of each phase of the multi-phase structure, galvanic couples will occur during the corrosion process. Corrosion, corrosion resistance is much lower than single-phase microstructure

Method used

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  • High-aluminum-content fine-grain low-density full-high-temperature ferrite steel and preparation method thereof
  • High-aluminum-content fine-grain low-density full-high-temperature ferrite steel and preparation method thereof
  • High-aluminum-content fine-grain low-density full-high-temperature ferrite steel and preparation method thereof

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Embodiment 1

[0029] The steel grade composition (mass fraction) of embodiment 1 of the present invention is as shown in table 1

[0030] Table 1: Alloy composition (wt%)

[0031] C Al mn Ni B Ti Nb Cr Fe 0.009 4.17 0.25 0.22 0.0022 0.021 0.004 1.21 margin

[0032] After casting, heat at a homogenization temperature of 1050°C for 60 minutes for homogenization treatment, and then start rolling at 1000°C. The rolling is divided into two stages. The first stage is controlled rolling by subgrain polymerization, growth and recrystallization mechanism: 3 passes , the pass reduction rate is 21.6%, 22.5%, 24.3% respectively, the pass interval is not more than 10s, and the strain rate is less than 0.2s -1 , the final rolling temperature is not lower than 950°C; the second stage is grain boundary bow recrystallization mechanism controlled rolling: 3 passes, pass reduction rates are 16.2%, 17.8%, 18.6% respectively, and the pass interval is not much In 10s, the...

Embodiment 2

[0035] The steel grade composition (mass fraction) of embodiment 2 of the present invention is as shown in table 2

[0036] Table 2: Alloy composition (wt%)

[0037] C Al mn Ni B Ti Nb Cr Fe 0.008 4.21 0.23 0.19 0.0025 0.025 0.006 1.69 margin

[0038] After casting, heat at a homogenization temperature of 1050°C for 60 minutes for homogenization treatment, and then start rolling at 1000°C. The rolling is divided into two stages. The first stage is controlled rolling by subgrain polymerization, growth and recrystallization mechanism: 3 passes , the pass reduction rates are 22.5%, 23.2%, 23.7%, the pass interval is not more than 10s, and the strain rate is less than 0.2s -1 , the final rolling temperature is not lower than 950°C; the second stage is grain boundary arching recrystallization mechanism controlled rolling: 3 passes, the pass reduction rates are 15.9%, 16.8%, 19.6% respectively, and the pass interval is not much In 10s, the st...

Embodiment 3

[0041] The steel composition (mass fraction) of embodiment 3 of the present invention is as shown in table 3

[0042] Table 3: Alloy composition (wt%)

[0043] C Al mn Ni B Ti Nb Cr Fe 0.004 4.35 0.28 0.31 0.0027 0.03 0.003 1.85 margin

[0044] After casting, heat at a homogenization temperature of 1050°C for 60 minutes for homogenization treatment, and then start rolling at 1000°C. The rolling is divided into two stages. The first stage is controlled rolling by subgrain polymerization, growth and recrystallization mechanism: 3 passes , the pass reduction rates are 22.9%, 23.7%, 24.5%, the pass interval is not more than 10s, and the strain rate is less than 0.2s -1 , the final rolling temperature is not lower than 950°C; the second stage is grain boundary arching and recrystallization mechanism controlled rolling: 3 passes, the pass reduction rates are 16.4%, 18.2%, and 19.1% respectively, and the pass interval is not much In 10s, the s...

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Abstract

The invention provides a high-aluminum-content fine-grain low-density full-high-temperature ferrite medium-thickness plate for an ocean platform and a preparation method for the high-aluminum-contentfine-grain low-density full-high-temperature ferrite medium-thickness plate. The steel is prepared from the following chemical components in percentage by mass: 0.01-0.039 percent of C, 4.01-6.00 percent of Al, 0.01-1.40 percent of Mn, 0.01-2.00 percent of Cr, 0.002-0.003 percent of B, 0.02-0.06 percent of Ti, 0.01-0.39 percent of Ni, less than or equal to 0.007 percent of Nb, less than or equal to 0.015 percent of P, less than or equal to 0.005 percent of S and the balance of Fe and other inevitable impurities. For the high-aluminum-content fine-grain low-density full-high-temperature ferritemedium-thickness plate and preparation method thereof, by controlling the components and a structure, the corrosion resistance in a marine atmospheric environment is better than that of currently commonly used weathering steel Corten-A by 70 percent or above, and the average grain size of the steel is refined to 50 microns or below.

Description

technical field [0001] The invention belongs to the field of metal materials, in particular to a method for preparing high-aluminum-content fine-grained low-density full-temperature ferritic steel for offshore platforms. Background technique [0002] With the continuous development of the marine economy, the demand for steel for offshore platforms is also showing a gradual increase. Due to the extremely complex marine environment, it has to withstand the erosion and damage of natural forces such as waves, earthquakes in Haiti, and low temperature. Marine engineering equipment serves in severe marine environments and must withstand severe loads and complex corrosion environments. From the perspective of energy saving and emission reduction and the structural safety of offshore platforms, there is a demand for weight reduction in steel for offshore engineering. Adding Al to steel reduces the density and improves the corrosion resistance of the steel plate. Therefore, the addi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C38/04C22C38/06C22C38/48C22C38/50C22C38/54C21D1/10C21D1/26C21D6/00C21D8/02C21D9/00
CPCC22C38/004C22C38/06C22C38/04C22C38/54C22C38/50C22C38/48C21D1/26C21D1/10C21D6/004C21D6/005C21D8/0221C21D9/0081C21D2211/005Y02P10/25
Inventor 延泽鹏王学敏徐翔宇尚成嘉
Owner UNIV OF SCI & TECH BEIJING
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