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Moulding type rubber foam composition, silicon rubber foam and method for procucing it

A technology of silicone rubber and composition, used in shafts and bearings, transportation and packaging, thin material handling, etc., can solve the problems of limited use, harmful decomposition products, and poor mechanical strength of silicone rubber sponges.

Inactive Publication Date: 2003-10-08
DOW CORNING TORAY SILICONE CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the former two compositions are very problematic from the viewpoint of environmental pollution because the decomposition products produced by the thermally decomposing foaming agent during foaming are harmful to humans.
Silicone rubber sponges produced according to the composition described in Japanese Patent Application Laid-Open No. Heisei 10-36544 have poor mechanical strength and are therefore of limited use

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 2

[0028] A dichloromethane solution with a solid content of 10% was prepared by dissolving an acrylic resin with a softening point of 85° C. (Elvacite 2008, a product of DuPont Company) in dichloromethane. This dichloromethane solution and distilled water are continuously sprayed into the spray dryer using a two-fluid nozzle. The injection speed of the dichloromethane solution is 100 cc / min, and the injection speed of distilled water is 25 cc / min. The hot nitrogen flow is used as a propellant. During this process, the temperature of the hot nitrogen flow is 80°C and the pressure is 0.25kg / cm 2 (0.025MPa). The obtained hollow acrylic resin particles were immersed in an aqueous solution formed by 100 parts of distilled water and 1 part of nonionic surfactant (ethylene oxide adduct of trimethylnonanol) for 24 hours, and the floating hollow particles were separated and collected. Acrylic resin powder. The obtained hollow acrylic resin powder had an average particle diameter of 20 ...

Embodiment 1

[0030] Add the following materials into a kneading mixer and mix well: 100 parts of dimethylethylene composed of 99.85% (mol) dimethylsiloxane structural units and 0.15% (mol) methylvinylsiloxane structural units Dimethylsiloxane-methylvinylsiloxane copolymer gum (weight average molecular weight=500000) end-capped by methylsiloxy group, 45 parts of BET surface area is 130m 2 / g of wet-process silica (Nipsil LP, a product of Silica Kogyo Kabushiki Kaisha, Japan), and 3 parts of hydroxyl-terminated dimethylsiloxane oligomers with a viscosity of 50 mPa·s. The resulting mixture was heated at 175°C for 60 minutes to form a silicone rubber base compound having a Williams plasticity of 260. Then, a molded silicone rubber sponge composition was prepared by uniformly mixing the following materials with 100 parts of a silicone rubber base compound on a two-roller mill: 1 part of trimethylsiloxy-terminated Dimethylsiloxane-methylhydroxysiloxane copolymer (the ratio of the number of mole...

Embodiment 3

[0035] Add the following materials into a kneading mixer and mix well: 100 parts of dimethylethylene composed of 99.85% (mol) dimethylsiloxane structural units and 0.15% (mol) methylvinylsiloxane structural units Dimethylsiloxane-methylvinylsiloxane copolymer gum (weight average molecular weight=500000) end-capped by methylsiloxy group, 45 parts of BET surface area is 130m 2 / g of wet-process silica (Nipsil LP, a product of Silica Kogyo Kabushiki Kaisha, Japan), and 3 parts of hydroxyl-terminated dimethylsiloxane oligomers with a viscosity of 50 mPa·s. The resulting mixture was heated at 175°C for 60 minutes to form a silicone rubber base compound having a Williams plasticity of 260. Then, a molded silicone rubber sponge composition was prepared by uniformly mixing the following materials with 100 parts of a silicone rubber base compound on a two-roll mill: 0.3 parts of o-methyl peroxide, 0.6 parts of dicumyl peroxide Base, and 1 part of hollow silicone resin powder prepared ...

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Abstract

A moldable silicone rubber sponge composition comprising (A) 100 weight parts silicone rubber base compound with a Williams plasticity at 25 DEG C. of 50 to 600, comprising (a) 100 weight parts diorganopolysiloxane gum that contains at least two alkenyl groups in each molecule and (b) 1 to 120 weight parts wet-process silica, (B) 0.01 to 50 weight parts hollow gas-containing thermoplastic resin powder, and (C) curing agent in an amount sufficient to effect curing of the composition. The invention is further a silicone rubber sponge afforded by the thermosetting of the above-defined moldable silicone rubber sponge composition and a method for producing the silicone rubber sponge.

Description

technical field [0001] The invention relates to a molded silicone rubber sponge composition, a silicone rubber sponge and a method for producing the silicone rubber sponge. Background technique [0002] Silicone rubber sponges are used for automotive parts such as packaging materials, gaskets, and O-rings, for surface coverings of copier rolls, and for Various sealing materials. Many molded silicone rubber sponge compositions have been disclosed, for example, Japanese Patent Application Publication No. Showa 44-461 (464 / 1969) and Japanese Patent Application Publication No. Heisei 7-247436 (247,436 / 1995) describe containing azobis Molded silicone rubber sponge made of pyrolytic foaming agent represented by isobutyronitrile. Japanese Patent Application Laid-Open No. Heisei 10-36544 (36,544 / 1998) describes a composition comprising hollow thermoplastic silicone resin particles mixed into a liquid silicone rubber composition capable of releasing gas upon curing. However, the d...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): F16C13/00C08J3/24C08J9/00C08J9/32C08K3/36C08L83/04C08L83/07
CPCY10T428/249972Y10T428/2985C08J2383/04C08J9/32Y10T428/1376C08J9/0066C08K3/36C08G77/20C08L83/04C08G77/12C08L2666/04C08L2666/54C08L2666/14
Inventor 本间博浜田光男
Owner DOW CORNING TORAY SILICONE CO LTD