Back etching solution and etching method for ultrathin wafer
A backside etching, wafer technology, used in chemical instruments and methods, crystal growth, electrical components, etc., can solve problems such as poor wafer quality, achieve good etching uniformity, and improve the effect of flatness
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Embodiment 1
[0063] Proportion: Take the parts by weight as an example, two parts of the mixed solution made of sulfuric acid, nitric acid and hydrofluoric acid with a mass ratio of 5:2:0.5 are placed in the first etching tank and the second etching tank respectively. in the slot. Wherein, the molar concentration of sulfuric acid is 97%, the molar concentration of nitric acid is 64%, and the molar concentration of hydrofluoric acid is 48%. A hydrofluoric acid solution with a molar concentration of 48% is placed in the hydrofluoric acid tank. Take two parts of hydrochloric acid whose mass percentage content is 0.01% of the mixed solution, and the molar concentration of the hydrochloric acid is 30%.
[0064] Etching method: the wafer is loaded through the loading area; after a portion of hydrochloric acid is dripped into the first etching tank by hand or a metering pump, the wafer is placed in the first etching tank from the loading area, and the wafer The wafer is immersed in the mixed so...
Embodiment 2
[0066] Proportion: Take the parts by weight as an example, two parts of the mixed solution made of sulfuric acid, nitric acid and hydrofluoric acid with a mass ratio of 7:4:1.5 are placed in the first etching tank and the second etching tank respectively. in the slot. Wherein, the molar concentration of sulfuric acid is 98%, the molar concentration of nitric acid is 65%, and the molar concentration of hydrofluoric acid is 49%. A hydrofluoric acid solution with a molar concentration of 49% is placed in the hydrofluoric acid tank. Take two parts of hydrochloric acid whose mass percentage content is 0.05% of the mixed solution, and the molar concentration of hydrochloric acid is 35%.
[0067] Etching method: In addition to etching at 25°C for 60 seconds in the first etching tank, etching at 35°C for 150 seconds in the second etching tank, and staying at 20°C for 20 seconds in the hydrofluoric acid tank , the same as in Example 1 to obtain wafer B.
Embodiment 3
[0069] Proportion: Taking parts by weight as an example, two parts of the mixed solution made of sulfuric acid, nitric acid and hydrofluoric acid with a mass ratio of 6:3:1 are placed in the first etching tank and the second etching tank respectively. in the slot. Wherein, the molar concentration of sulfuric acid is 98%, the molar concentration of nitric acid is 65%, and the molar concentration of hydrofluoric acid is 49%. A hydrofluoric acid solution with a molar concentration of 48.5% is placed in the hydrofluoric acid tank. Take two parts of hydrochloric acid whose mass percentage content is 0.03% of the mixed solution, and the molar concentration of hydrochloric acid is 32%.
[0070] Etching method: In addition to etching at 22°C for 30 seconds in the first etching tank, etching at 35°C for 120 seconds in the second etching tank, and staying at 13°C for 15 seconds in the hydrofluoric acid tank , the same as in Example 1 to obtain wafer C.
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