A kind of flexible conductive film and preparation method thereof

A flexible conductive and thin film technology, which is applied in the direction of equipment for manufacturing conductive/semiconductive layers, cable/conductor manufacturing, conductive layers on insulating carriers, etc., can solve the problem of low tensile strength of flexible cellulose films, which affects the conductivity of films Uniformity, graphene surface damage and other issues, to achieve the effect of uniform and dense deposition, good conductivity, and accurate thickness control

Active Publication Date: 2021-10-19
浙江柔震科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0003] Based on the excellence of flexible conductive films, the preparation methods of various flexible conductive films have also been proposed, such as CN111446453A proposed to obtain flexible conductive films by the method of chemical deposition, although this method has prepared flexible conductive films, there are also the following Problems: ①The processing steps are cumbersome, take a long time, and the efficiency is low; ②Acid treatment is required in the preparation process, and large-scale production will have a great impact on the environment
CN 111312431A proposes to prepare a flexible conductive film through anisotropic nanocellulose, which also has the disadvantages of complicated preparation process and low tensile strength of flexible cellulose film
Similarly, CN106158144A also proposes to prepare ultra-thin ultra-flexible graphene conductive film by chemical vapor deposition method, but it also has high equipment requirements for preparing graphene by chemical vapor deposition, and low preparation efficiency. At the same time, the prepared graphene needs to be transferred to The surface of the substrate will cause damage to the graphene surface, which will affect the uniformity of the film's conductivity

Method used

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  • A kind of flexible conductive film and preparation method thereof
  • A kind of flexible conductive film and preparation method thereof
  • A kind of flexible conductive film and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0044] The flexible conductive film is prepared by the following steps:

[0045] 1. Vacuum the equipment to 8.0×10 -4 mba, then heat the equipment to a certain temperature, and pre-melt the wire film material at a wire feeding speed of 250mm / min;

[0046] 2. The PET polymer film is injected with a mixed gas of oxygen and argon with a ratio of 1:0.1-10 for plasma blowing treatment, and the surface of the film is oxidized to add oxygen-containing functional groups;

[0047] 3. After the treatment, remove the baffle for evaporation, and deposit a metal reinforcement layer with a thickness of 8nm on the polymer film substrate. The thickness of the reinforcement layer is controlled by the optical density probe. After the film thickness meets the requirements, use the baffle Cover the evaporation source and stop heating;

[0048] 4. After the film coating is completed, inflate the coating chamber, and take out the coating coil when the pressure in the chamber reaches atmospheric p...

Embodiment 2

[0053] In this embodiment, a flexible conductive film is prepared through the following steps:

[0054] 1. Vacuum the equipment to 8.0×10 -4 mba, then heat the equipment to a certain temperature, and pre-melt the wire film material at a wire feeding speed of 250mm / min;

[0055] 2. The PET polymer film is injected with a mixed gas of oxygen and argon with a ratio of 1:0.1-10 for plasma blowing treatment, and the surface of the film is oxidized to add oxygen-containing functional groups;

[0056] 3. After the treatment, remove the baffle for evaporation, and deposit a metal reinforcement layer with a thickness of 8nm on the polymer film substrate. The thickness of the reinforcement layer is controlled by the optical density probe. After the film thickness meets the requirements, use the baffle Cover the evaporation source and stop heating;

[0057] 4. After the film coating is completed, inflate the coating chamber, and take out the coating coil when the pressure in the chambe...

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Abstract

The invention provides a flexible conductive film capable of large-scale production and a preparation method thereof. In the flexible conductive film, metal layers are plated on the upper and lower surfaces of the substrate, and a reinforcing layer is provided between the substrate and the metal layer, so that the gap between the conductive layer and the substrate is Has a strong binding force. The flexible conductive film has excellent mechanical properties and conductive properties, the conductive layer and the reinforcing layer are evenly and densely distributed on the two surfaces of the flexible substrate, and the surface density of the flexible conductive film is 0.52-4.5 mg / cm 2 , the resistivity can reach 2×10 ‑8 ~6×10 ‑8 Ω·m, with lower areal density and better electrical conductivity. Both the conductive layer and the reinforcing layer are prepared by vacuum evaporation. This method has simple process, high efficiency, low cost, and no strict requirements on the preparation environment. It can be industrialized on a large scale. The vacuum degree is high, and the obtained coating contains oxygen. Low amount, high density, ensure uniform and dense deposition of metal conductive layer, and fully ensure the excellent conductivity of the film.

Description

technical field [0001] The invention relates to the technical field of conductive materials, in particular to a flexible conductive film and its preparation method and application. Background technique [0002] With the rapid development of electronic technology, electronic devices and equipment are gradually developing in the direction of mobility, lightness, and flexibility, so new flexible conductive film materials have been developed rapidly. Compared with traditional hard conductive materials, new flexible conductive materials not only have low surface resistance, but also are easy to bend and light, and have become a research hotspot in recent years. [0003] Based on the excellence of flexible conductive films, the preparation methods of various flexible conductive films have also been proposed, such as CN111446453A proposed to obtain flexible conductive films by the method of chemical deposition, although this method has prepared flexible conductive films, there are ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01B5/14H01B13/00
CPCH01B5/14H01B13/0026
Inventor 吴明忠朱正录黄云辉伽龙曾祥平焦鑫鹏
Owner 浙江柔震科技有限公司
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