Preparation method and application of antimony-sulfur-selenium film with V-shaped energy band structure
A technology of energy band structure and thin film, applied in the direction of final product manufacturing, sustainable manufacturing/processing, climate sustainability, etc., can solve the problems of open circuit voltage and short circuit current limitation of antimony sulfur selenium solar cells, and achieve small surface roughness , The surface of the film is smooth and the effect of improving efficiency
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[0036] refer to figure 1 , combined with Figure 2-4 , a kind of preparation method of antimony sulfur selenium film with V-type energy band structure provided by the invention, comprises the following steps:
[0037] S1: Mix potassium antimony tartrate, sodium thiosulfate, and selenourea to obtain a first precursor solution; after the first precursor solution undergoes a water bath reaction, it is placed on a substrate for deposition, thereby forming a first precursor solution on the substrate. A layer of precursor thin film;
[0038] S2: Mix potassium antimony tartrate, sodium thiosulfate, and selenourea to obtain a second precursor solution; after the second precursor solution is subjected to a water bath reaction, put it into the substrate deposited in step S1 to continue deposition, thereby Forming a second layer of precursor film on the first layer of precursor film;
[0039] S3: Mix potassium antimony tartrate, sodium thiosulfate, and selenourea to obtain a third pre...
Embodiment 1
[0054] In the first step, mix 0.03g ethylenediaminetetraacetic acid, 0.534g antimony potassium tartrate and 1.6g sodium thiosulfate in a 50mL glass bottle filled with 40mL deionized water, and add 1mg of selenourea after the solution turns yellow , to obtain the first precursor solution, cover the mouth of the bottle with a plastic cap without tightening it, then place the glass bottle in a water bath at 60°C for 20 minutes, and then put the CdS deposited FTO glass substrate into the first precursor solution After reacting at 60°C for 1 hour, take it out immediately to obtain the first layer of antimony sulfur selenium precursor thin film, which is numbered 1 hour.
[0055] In the second step, mix 0.03g ethylenediaminetetraacetic acid, 0.534g antimony potassium tartrate and 1.6g sodium thiosulfate in a 50mL glass bottle filled with 40mL deionized water, and add 40mg of selenourea after the solution turns yellow , to obtain the second precursor solution, cover the mouth of the ...
Embodiment 2
[0060] In the first step, mix 0.03g ethylenediaminetetraacetic acid, 0.534g antimony potassium tartrate and 1.6g sodium thiosulfate in a 50mL glass bottle filled with 40mL deionized water, and add 10mg of selenourea after the solution turns yellow , to obtain the first precursor solution, cover the mouth of the bottle with a plastic cap without tightening it, then place the glass bottle in a water bath at 100°C for 20 minutes, and then put the CdS-deposited FTO glass substrate into the first precursor solution After reacting at 100°C for 1 hour, it was taken out immediately to obtain the first layer of antimony sulfur selenium precursor thin film, numbered 1 hour.
[0061] In the second step, mix 0.03g ethylenediaminetetraacetic acid, 0.534g antimony potassium tartrate and 1.6g sodium thiosulfate in a 50mL glass bottle filled with 40mL deionized water, and add 60mg of selenourea after the solution turns yellow , to obtain the second precursor solution, cover the bottle mouth w...
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