Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Halogen-free flame-retardant PC/ABS alloy material and preparation method thereof

A technology of alloy material and polycarbonate, which is applied in the field of halogen-free flame-retardant PC/ABS alloy material and its preparation, can solve problems such as buckle fracture, performance retention decline, and cracking

Inactive Publication Date: 2021-05-18
ORINKO NEW MATERIAL CO LTD
View PDF5 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Nowadays, electronic and electrical equipment has become an indispensable part of people's life and work. The application site and use environment will inevitably encounter high temperature, high humidity and contact with chemical reagents, and the shell of electronic and electrical equipment is generally made of polymer materials, and its shell structure is often There will be screw posts and buckles; while the conventional halogen-free flame-retardant PC / ABS material is used as the shell because of its large internal stress, the screw posts will often crack and the buckles will break. In addition, under high temperature and high humidity environment The long-term service performance retention rate drops greatly, and the retention rate is less than 50%. After contact with chemical reagents, internal stress is induced to cause cracks or even cracks; Material development is particularly important

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Halogen-free flame-retardant PC/ABS alloy material and preparation method thereof
  • Halogen-free flame-retardant PC/ABS alloy material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] According to parts by weight, 40 parts of the flame-retardant PC masterbatch, 15 parts of the first polycarbonate, 10 parts of the second polycarbonate, 5 parts of acrylonitrile-butadiene-styrene copolymer, 3 parts of MBS EM500, ethylene After 1 part of acrylate copolymer, 0.4 part of polytetrafluoroethylene, 0.2 part of dipentaerythritol stearate and 0.3 part of 168 antioxidant are mixed uniformly, they are put into the twin-screw extruder through the main feeding port, and passed through the twin-screw extruder. The halogen-free flame-retardant PC / ABS alloy material is obtained by shearing, melting and plasticizing, extruding and granulating in a screw extruder, and homogenizing. The barrel temperature of the twin-screw extruder from zone 1 to zone 9 and the machine head are as follows: 180°C, 250°C, 250°C, 250°C, 250°C, 240°C, 240°C, 230°C, 210°C, 240°C ℃; main engine speed 400r / min, vacuum -0.08MPa.

Embodiment 2

[0035] According to parts by weight, 50 parts of the flame-retardant PC masterbatch, 20 parts of the first polycarbonate, 22 parts of the second polycarbonate, 7 parts of acrylonitrile-butadiene-styrene copolymer, 3 parts of MBS M724, ethylene After 1 part of acrylate copolymer, 0.3 part of polytetrafluoroethylene, 0.3 part of dipentaerythritol stearate and 0.2 part of 168 antioxidant are mixed uniformly, they are put into the twin-screw extruder through the main feeding port, and passed through the twin-screw extruder. The halogen-free flame-retardant PC / ABS alloy material is obtained by shearing, melting and plasticizing, extruding and granulating in a screw extruder, and homogenizing. The barrel temperature of the twin-screw extruder from Zone 1 to Zone 9 and the machine head are as follows: 180°C, 250°C, 250°C, 250°C, 250°C, 240°C, 240°C, 230°C, 210°C, 240°C ℃; main engine speed 400r / min, vacuum -0.08MPa.

Embodiment 3

[0037] According to parts by weight, 60 parts of the flame-retardant PC masterbatch, 30 parts of the first polycarbonate, 15 parts of the second polycarbonate, 10 parts of acrylonitrile-butadiene-styrene copolymer, 2 parts of MBS M724, ethylene After 2 parts of acrylate copolymer, 0.6 part of polytetrafluoroethylene, 0.4 part of dipentaerythritol stearate and 0.1 part of 168 antioxidant are mixed uniformly, they are put into the twin-screw extruder through the main feeding port, and passed through the twin-screw extruder. The halogen-free flame-retardant PC / ABS alloy material is obtained by shearing, melting and plasticizing, extruding and granulating in a screw extruder, and homogenizing. The barrel temperature of the twin-screw extruder from Zone 1 to Zone 9 and the machine head are as follows: 180°C, 250°C, 250°C, 250°C, 250°C, 240°C, 240°C, 230°C, 210°C, 240°C ℃; main engine speed 400r / min, vacuum -0.08MPa.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention discloses a halogen-free flame-retardant PC / ABS alloy material, which is prepared from the following components in parts by weight: 40 to 60 parts of flame-retardant PC master batch, 15 to 30 parts of first polycarbonate, 10 to 22 parts of second polycarbonate, 5 to 10 parts of acrylonitrile-butadiene-styrene copolymer, 2 to 4 parts of methacrylate-butadiene-styrene copolymer, 1 to 2 parts of ethylene acrylate copolymer, 0.3 to 0.6 part of polytetrafluoroethylene, 0.2 to 0.4 part of stearate and 0.1 to 0.3 part of antioxidant. According to the halogen-free flame-retardant PC / ABS alloy material and the preparation method thereof provided by the invention, the halogen-free flame-retardant PC / ABS alloy material has relatively high elongation at break, high performance retention rate under high temperature and high humidity, and strong chemical reagent resistance, and can improve the problems that the PC / ABS is easy to break when being applied to a screw stud and a buckle on an electronic and electrical appliance shell, the performance is severely degraded under high temperature and high humidity, and the PC / ABS alloy material is easy to induce cracking when being in contact with a chemical reagent and the like, so that the PC / ABS material can be widely applied in the field of electronic and electrical appliances and under severe environment requirements.

Description

technical field [0001] The invention belongs to the field of polymer material modification, in particular to a halogen-free flame-retardant PC / ABS alloy material and a preparation method thereof. Background technique [0002] Nowadays, electronic and electrical equipment has become an indispensable part of people's life and work. The application site and use environment will inevitably encounter high temperature, high humidity and contact with chemical reagents, and the shell of electronic and electrical equipment is generally made of polymer materials, and its shell structure is often There will be screw posts and buckles; while the conventional halogen-free flame-retardant PC / ABS material is used as the shell because of its large internal stress, the screw posts will often crack and the buckles will break. In addition, under high temperature and high humidity environment The long-term service performance retention rate drops greatly, and the retention rate is less than 50%...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): C08L69/00C08L55/02C08L51/04C08L23/08C08L27/18C08K5/521
CPCC08L69/00C08L2201/02C08L2201/22C08L2201/08C08L2205/025C08L2205/035
Inventor 陈贤宏魏子芳张正李荣群
Owner ORINKO NEW MATERIAL CO LTD
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products