Polyacrylate polymer
A technology of polyacrylate and acrylate, applied in the direction of coating, etc., can solve problems such as high cost and peculiar smell
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Embodiment approach 1-19
[0171] 20. A process for the preparation of polymers according to one or more of embodiments 1-19, comprising at least the following steps:
[0172] a) polymerizing a mixture comprising at least one acrylate monomer of the general formula (II) in the presence of at least one free-radical-forming initiator and the at least one compound of the general formula (I):
[0173]
[0174] where R 1 selected from substituted or unsubstituted linear or branched C 1 -C 22 Alkyl, substituted or unsubstituted aryl;
[0175]
[0176] wherein X, Y and Z are independently selected from hydrogen; halogen; substituted or unsubstituted linear or branched C 1 -C 10 Alkyl; OR and C(=O)-OR, wherein R is substituted or unsubstituted linear or branched C 1 -C 10 alkyl.
[0177] 21. The method according to embodiment 20, wherein the at least one acrylate monomer of general formula (II) is present in an amount ranging from > 40% by weight to < 80% by weight, based on the total weight of the...
Embodiment
[0203] The invention is illustrated by the following non-limiting working examples. More specifically, the test methods described below form part of the general disclosure of this application and are not limited to specific working examples. Material:
[0204] n-Butyl Acrylate (nBA)
[0205] 2-Ethylhexyl Acrylate (EHA)
[0206] 2-Hydroxyethyl Acrylate (HEA)
[0207] Acrylic (AA), and
[0208] Styrene (SY)
[0209] Available from BASF SE.
[0210] Benzyl alcohol was purchased from Sigma Aldrich.
[0211] 100 was purchased from Bernd Kraft.
[0212] physical method
[0213] Method for determining the content of aromatic moieties: 1 H NMR spectroscopy, gravimetric analysis
[0214] Determination of M w , M n and PDI method: gel permeation chromatography (polystyrene standard)
[0215] General procedure for preparing polymers
[0216] The solvent benzyl alcohol was added to the reactor in advance and heated to 100-150°C. The monomer mixture is dosed over a period ...
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