Polyimide precursor composition and polyimide film/substrate laminate
A polyimide precursor, polyimide film technology, applied in semiconductor/solid-state device manufacturing, electric solid-state devices, semiconductor devices, etc., can solve the problem that the flexible film is difficult to maintain planarity, and achieve excellent stability , excellent storage stability, excellent transparency effect
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[0218] The polyimide precursor composition can be prepared by adding and mixing an imidazole compound or a solution of an imidazole compound to the polyimide precursor solution obtained by the above method. A tetracarboxylic-acid component and a diamine component can also be made to react in presence of an imidazole compound.
[0219] >
[0220] The polyimide film / substrate laminate of the present invention can be manufactured through the following steps: (a) the step of applying the polyimide precursor composition to the substrate; (b) applying the polyimide precursor composition to the substrate The process of heat-processing the said polyimide precursor, and manufacturing the laminated body (polyimide film / substrate laminated body) in which the polyimide film was laminated|stacked on the said base material. The manufacturing method of the flexible electronic device of the present invention uses the polyimide film / substrate laminate produced by the above-mentioned step (a) ...
Embodiment 1
[0336] [Preparation of polyimide precursor composition]
[0337] 2.27 g (0.010 mol) of DABAN was added to a reaction vessel replaced with nitrogen, and 32.11 g of N-methyl-2 - Pyrrolidone, stirred at 50°C for 1 hour. 3.84 g (0.010 mol) of CpODA was slowly added to this solution. It was stirred at 70°C for 4 hours to obtain a uniform and viscous polyimide precursor solution.
[0338] 2-Phenylimidazole, which is an imidazole compound, was dissolved in 4 times the mass of N-methyl-2-pyrrolidone to obtain a uniform solution with a solid content concentration of 20% by mass of 2-phenylimidazole. The solution of the imidazole compound and the polyimide precursor solution synthesized above were stirred at room temperature for 3 hours to obtain a uniform and Viscous polyimide precursor composition.
[0339] [Manufacture of polyimide film / substrate laminate]
[0340] In order to manufacture the polyimide film / base material laminated body for polyimide film evaluation, the Eagle-...
Embodiment 2~15、 comparative example 1~14
[0345] In Example 1, except that the tetracarboxylic acid component, the diamine component, the imidazole compound, and the maximum temperature during film formation were changed to the compounds shown in Table 2 to Table 5, polyimide was produced in the same manner as in Example 1. For the amine film / reference base material laminate, the warpage of the laminate was measured in the same manner as in Example 1, and the residual stress at 23° C. was obtained. The results are shown in Tables 2 to 5. In addition, in Table 2 to Table 4, the polyimide film / substrate using the sixth generation glass substrate (Eagle-XG (registered trademark) 500 μm thick, elastic modulus: 73.6 GPa) is also shown together. The estimated warpage value of the laminate.
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