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High-toughness magnesium alloy and preparation method thereof

A magnesium alloy, high-strength technology, applied in the field of magnesium alloys, can solve the problems of less than 10%, the mismatch of strength and plasticity, the description of mechanical properties of heat treatment process, etc., to achieve the effect of improving strength, strength and toughness, and small size

Active Publication Date: 2021-08-20
CHINA WEAPON SCI ACADEMY NINGBO BRANCH +1
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The patent (CN105088038A) proposes a high thermal conductivity and corrosion-resistant Mg-1.5~6%Sm-0.001~1.2%Ca-0.5~3.0%Zn-0.3~2.5%Mn alloy, and its extrusion deformation process is: the ingot is cast in 350-420°C for 2-24h homogenization treatment, extrusion speed 0.1-6mm / s, extrusion ratio 14-30, water quenching after extrusion, but no heat treatment process after extrusion deformation and mechanics after extrusion deformation The performance is explained; Guan Kai et al obtained fine dynamic recrystallization grains (~0.47m) by extrusion of Mg-3.5Sm-0.6Zn-0.5Zr alloy, and after further T5 aging treatment, the yield of the alloy The strength reached ~416MPa, and the elongation was ~5.1%. The patent (CN111485453.A) proposed a deformed magnesium alloy containing neodymium, samarium, light rare earth elements and high Mn content and its preparation method. The mass composition ratio is: calcium: 0.3-1.9%; aluminum: 0.3-1.5%; zinc: 0.2-1.7%; manganese: 0.3-2.8%; light rare earth (neodymium or samarium): 0.3-3.0%, the material can The tensile strength reaches 368-435MPa, and the elongation is 4-13%, but the disadvantage of this alloy is that the elongation of the patented alloy is less than 10% when the tensile strength reaches above 390MPa, showing obvious Mismatch of strength and plasticity
[0005] At present, high strength and low elongation at break are common problems in high-strength wrought magnesium alloy materials, which greatly limits its application. Therefore, the development of high strength and high elongation at break is of great significance to promote the application of magnesium alloy materials.

Method used

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  • High-toughness magnesium alloy and preparation method thereof
  • High-toughness magnesium alloy and preparation method thereof
  • High-toughness magnesium alloy and preparation method thereof

Examples

Experimental program
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Embodiment 1

[0031] The mass percent composition of the high strength and toughness magnesium alloy in this embodiment is: Sm: 2.0%, Mn: 0.8%, Ca: 0.6%, Zn: 0.5%, and the balance is Mg and unavoidable impurities.

[0032] The preparation of the high strength and toughness magnesium alloy of the present embodiment comprises the following steps:

[0033] 1) Preparation of magnesium alloy cast rod:

[0034] a) According to the alloy composition of the magnesium alloy, calculate the respective weights of the required Mg ingots, Zn ingots, Mg-25Sm master alloys, Mg-10Mn master alloys, and Mg-25Ca master alloys and prepare the materials, and dry them at 300 ° C. Time 1.5h;

[0035] b) in SF 6 +CO 2 Under gas protection, put the dried pure Mg ingot into a crucible that has been preheated to 550°C, and raise the furnace temperature to 730°C until the Mg is completely melted;

[0036] c) At 730°C, add the dried pure Zn ingot and Mg-10Mn master alloy into the magnesium melt, and fully stir until...

Embodiment 2

[0045] The difference between Example 2 and Example 1 is that the pouring speed of the semi-continuous ingot is 150mm / min, the flow rate of cooling water is 90L / min, and the stripped cast rod and extrusion die are preheated in a resistance furnace at 270°C for 1.5h , Preheat the ingot barrel of the extrusion machine to 270°C, the extrusion ratio is 16:1, extrude the deformed magnesium alloy extruded rod at 300°C, and anneal for 15 minutes.

Embodiment 3

[0047] The difference between this example and Example 1 is that the mass percent composition of the magnesium alloy is Sm: 1.7%, Mn: 0.8%, Ca: 0.5%, Zn: 0.5%, and the balance is Mg and unavoidable impurities. After peeling The cast rod and extrusion die were preheated in a resistance furnace at 270°C for 2h, the extrusion speed was 1mm / s, and the extruded deformed magnesium alloy extruded rod was annealed at 350°C for 15 minutes.

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Abstract

The invention discloses a high-toughness magnesium alloy. The alloy is characterized by comprising the following components in percentage by mass: 1.7 to 2.5 weight percent of Sm, 0.4 to 0.8 weight percent of Mn, 0.2 to 0.6 weight percent of Ca, 0.2 to 0.6 weight percent of Zn and the balance of Mg and inevitable impurities. By controlling the adding amount of Sm, Mg, Zn, Ca and Mn, on one hand, rare earth Sm, Mg, Zn and Ca form a large number of MgZnCaSm and MgZnSm nanophases, a large number of alpha-Mn nanophases exist in an alloy structure, the nanophases play a role in strengthening a magnesium matrix, the strength of the alloy is improved, the nanophases are small in size and can be dispersed and distributed on the magnesium alloy matrix, the influence on the ductility of the matrix is not large, the tensile strength of the magnesium alloy can be 400 MPa-450 MPa, the yield strength of the magnesium alloy can be 390 MPa-420 MPa, and the ductility of the magnesium alloy can be 15% or above.

Description

technical field [0001] The invention belongs to the technical field of magnesium alloys, and in particular relates to a high-strength and toughness magnesium alloy and a preparation method thereof. Background technique [0002] As the lightest metal structural material, magnesium alloy has a series of advantages such as low density, high specific strength, good thermal conductivity and excellent damping and shock absorption performance. It has broad application prospects in the fields of aerospace, transportation and mobile communication. However, the strength of traditional magnesium alloys is not high, which still faces some challenges in practical applications. At present, researchers mainly control the microstructure of magnesium alloys through alloying, plastic deformation and heat treatment, in order to obtain new magnesium alloys with excellent comprehensive mechanical properties, and then meet the needs of practical applications. [0003] Existing studies have shown...

Claims

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Application Information

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IPC IPC(8): C22C23/06C22C1/03B21C23/04C22F1/06
CPCC22C23/06C22C1/03B21C23/04C22F1/06
Inventor 王军张景怀曹召勋何玉莹王茹张志谢金书徐永东朱秀荣
Owner CHINA WEAPON SCI ACADEMY NINGBO BRANCH
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