Carbon nanotube-filled copper acetylacetonate composite burning rate catalyst

A technology of copper acetylacetonate and burning rate catalyst, which is applied in the direction of ammonium perchlorate composition, non-explosive/non-thermal agent components, compressed gas generation, etc., can solve the problems that the combustion catalytic performance of composite materials has not been studied, and achieve Improved combustion catalytic performance, high yield, and large specific surface area

Active Publication Date: 2021-10-26
SHAANXI NORMAL UNIV
View PDF6 Cites 3 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In 2012, Zhang Yan and others filled nano-CuO particles into carbon nanotubes to obtain a uniformly filled nanocomposite (Zhang Yan, Xue Jian. Preparation and characterization of nano-CuO particles filled multi-walled carbon nanotube composites[J ]. Applied Chemical Industry, 2012,41(03):476-479.), but no research has been done on the combustion catalytic performance of the composite material

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Carbon nanotube-filled copper acetylacetonate composite burning rate catalyst
  • Carbon nanotube-filled copper acetylacetonate composite burning rate catalyst
  • Carbon nanotube-filled copper acetylacetonate composite burning rate catalyst

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] Add 150 mg of multi-walled carbon nanotubes with a diameter of 4 to 6 nm into 15 mL of a mixed acid solution with a volume ratio of concentrated sulfuric acid and concentrated nitric acid of 3:1, and perform ultrasonic treatment for 4 h at a temperature of 30 ° C and a power of 300 W to obtain a black viscous Thick solution, add deionized water to this solution, stir it evenly with a glass rod, then let it settle at room temperature for 12 hours, you can see that there are obvious layers in the beaker, pour off the upper layer of transparent solution, add deionized water again, and so on After several times a black suspension was obtained. The black suspension was separated by suction filtration, and washed repeatedly with deionized water until the pH of the obtained black solid precipitate was neutral. The black solid precipitate was transferred to a blast drying oven at 80°C for 12 hours, and then ground evenly. The oxidized carbon nanotubes with open ends were obtain...

Embodiment 2

[0029] In this embodiment, the multi-walled carbon nanotubes with a diameter of 5 to 15 nm of equal mass are used to replace the multi-walled carbon nanotubes with a diameter of 4 to 6 nm in Example 1, and the other steps are the same as in Example 1, and the obtained black powder Copper acetylacetonate composite combustion rate catalysts filled with carbon nanotubes.

Embodiment 3

[0031] In this embodiment, the multi-walled carbon nanotubes with a diameter of 10 to 20 nm of equal mass are used to replace the multi-walled carbon nanotubes with a diameter of 4 to 6 nm in Example 1, and the other steps are the same as in Example 1, and the obtained black powder Copper acetylacetonate composite combustion rate catalysts filled with carbon nanotubes.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
diameteraaaaaaaaaa
diameteraaaaaaaaaa
diameteraaaaaaaaaa
Login to view more

Abstract

The invention discloses a carbon nanotube-filled copper acetylacetonate composite burning rate catalyst, which is prepared by the following steps: carrying out ultrasonic treatment on multi-walled carbon nanotubes with different tube diameters through a mixed acid solution to obtain oxidized carbon nanotubes with openings at two ends, then adding the oxidized carbon nanotubes into a saturated solution of copper acetylacetonate, and carrying out ultrasonic treatment to fill the tube cavities of the oxidized carbon nano tubes with acetylacetone copper, thereby obtaining the composite burning rate catalyst with the carbon nano tubes filled with acetylacetone copper. The preparation method is simple, and the obtained carbon nano tube filled acetylacetone copper composite burning rate catalyst is good in catalytic effect and easy to prepare in an enlarged mode.

Description

technical field [0001] The invention belongs to the technical field of solid propellants, in particular to a carbon nanotube-filled copper acetylacetonate composite combustion rate catalyst. Background technique [0002] Solid propellant is a commonly used rocket engine power source, and its combustion state will directly affect the performance of aerospace rockets. After long-term research, solid propellants have formed a development trend of high energy, high specific impulse, and low signal characteristics. Ammonium perchlorate (AP), a strong oxidant, is a common energetic material component in solid propellants, especially in double-base propellants and their modified propellants. Since ammonium perchlorate generally has a relatively large proportion, the combustion rate, thermal decomposition peak temperature and heat release of its decomposition process have a great influence on the combustion of solid propellants. Among the existing methods for improving the combusti...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): C06B23/00C06B29/22C06D5/06
CPCC06B23/007C06B29/22C06D5/06
Inventor 张国防许锐哲吕雅芃杨蕗菲石晓玲何倩方海超
Owner SHAANXI NORMAL UNIV
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap