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Carbon Nanotube Filled Copper Metal Complex Nanocomposite Burning Rate Catalyst

A metal complex, burning rate catalyst technology, applied in non-explosive/non-thermal agent components, explosives, offensive equipment and other directions, can solve the problem that the combustion catalytic performance of composite materials has not been studied, and achieve improved combustion catalytic performance and catalytic performance. Improve, good catalytic effect

Active Publication Date: 2022-03-11
SHAANXI NORMAL UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

In 2012, Zhang Yan and others filled nano-CuO particles into carbon nanotubes to obtain a uniformly filled nanocomposite (Zhang Yan, Xue Jian. Preparation and characterization of nano-CuO particles filled multi-walled carbon nanotube composites[J ]. Applied Chemical Industry, 2012,41(03):476-479.), but no research has been done on the combustion catalytic performance of the composite material

Method used

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  • Carbon Nanotube Filled Copper Metal Complex Nanocomposite Burning Rate Catalyst
  • Carbon Nanotube Filled Copper Metal Complex Nanocomposite Burning Rate Catalyst
  • Carbon Nanotube Filled Copper Metal Complex Nanocomposite Burning Rate Catalyst

Examples

Experimental program
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Effect test

Embodiment 1

[0026]Add 150 mg of multi-walled carbon nanotubes with a diameter of 4 to 6 nm into 15 mL of a mixed acid solution with a volume ratio of concentrated sulfuric acid and concentrated nitric acid of 3:1, and perform ultrasonic treatment for 4 h at a temperature of 30 ° C and a power of 300 W to obtain a black viscous Thick solution, add deionized water to this solution, stir it evenly with a glass rod, then let it settle at room temperature for 12 hours, you can see that there are obvious layers in the beaker, pour off the upper layer of transparent solution, add deionized water again, and so on After several times a black suspension was obtained. The black suspension was separated by suction filtration, and washed repeatedly with deionized water until the pH of the obtained black solid precipitate was neutral. After the black solid precipitate was transferred to a blast drying oven at 80°C for 12 hours, it was ground evenly. The oxidized carbon nanotubes with open ends were obt...

Embodiment 2

[0028] In this embodiment, the multi-walled carbon nanotubes with a diameter of 5 to 15 nm of equal mass are used to replace the multi-walled carbon nanotubes with a diameter of 4 to 6 nm in Example 1, and the other steps are the same as in Example 1, and the obtained black powder Filling the carbon nanotubes with Cu(NO 3 ) 2 ·3H 2 O nanocomposite burning rate catalyst, Cu(NO 3 ) 2 ·3H 2 The filling ratio of O is 8.2%.

Embodiment 3

[0030] In this embodiment, the multi-walled carbon nanotubes with a diameter of 10 to 20 nm of equal mass are used to replace the multi-walled carbon nanotubes with a diameter of 4 to 6 nm in Example 1. The other steps are the same as in Example 1, and the obtained black powder Filling the carbon nanotubes with Cu(NO 3 ) 2 ·3H 2 O nanocomposite burning rate catalyst, Cu(NO 3 ) 2 ·3H 2 The filling ratio of O is 6.8%.

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Abstract

The invention discloses a carbon nanotube-filled copper metal complex nanocomposite burning rate catalyst. Multi-wall carbon nanotubes with different diameters are ultrasonically treated with a mixed acid solution to obtain oxidized carbon nanotubes with openings at both ends. The oxidized carbon nanotubes are Add Cu(NO 3 ) 2 ·3H 2 O, [Cu(TMEDA) 2 ](NO 3 ) 2 (TMEDA=Tetramethylethylenediamine), [Cu(MIM) 4 ] (DCA) 2 (MIM=1‑methylimidazole, DCA=dicyanamide anion) or [Cu(NMIM) 4 ] (DCA) 2 (NMIM=2-nitro-1-methylimidazole, DCA=dicyanamide anion) in a saturated solution, ultrasonic treatment, so that these copper metal complexes are filled in the official cavity of the oxidized carbon nanotubes, thereby obtaining carbon nanotubes filled Copper metal complex nanocomposite burning rate catalyst. The preparation method of the invention is simple, and the obtained nanocomposite burning rate catalyst has good catalytic effect and is easy to enlarge and prepare.

Description

technical field [0001] The invention belongs to the technical field of solid propellants, in particular to a carbon nanotube filled copper metal complex nanocomposite burning rate catalyst. Background technique [0002] Solid propellant is a commonly used rocket engine power source, and its combustion state will directly affect the performance of aerospace rockets. After long-term research, solid propellants have formed a development trend of high energy, high specific impulse, and low signal characteristics. Ammonium perchlorate (AP), a strong oxidant, is a common energetic material component in solid propellants, especially in double-base propellants and their modified propellants. Since ammonium perchlorate generally has a relatively large proportion, the combustion rate, thermal decomposition peak temperature and heat release of its decomposition process have a great influence on the combustion of solid propellants. Among the existing methods for improving the combustio...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C06B23/00
CPCC06B23/007
Inventor 张国防许锐哲杨蕗菲石晓玲何倩方海超
Owner SHAANXI NORMAL UNIV
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