High-optical-absorption carbon nanomaterial and preparation method thereof

A carbon nanomaterial and nanomaterial technology, which are applied in the field of high optical absorption carbon nanomaterials and their preparation, can solve the problems of low impedance matching degree, reduce the light absorption ability of materials, limit the development of light absorption coating, etc., and achieve good interface impedance matching, The effect of efficient optical absorption

Active Publication Date: 2021-11-02
西安应用光学研究所
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

The structure of traditional absorbing coating materials is relatively dense, and there is a sudden change in refractive index between the coating and the air, and their interface impedance matching is low, resulting in high reflection of light at the interface and reducing the light absorption capacity of the material.
However, there are almost no materials with a refractive index less than 1.3 in nature, and it is difficult to achieve a low refractive index difference at the material-air interface, which limits the development of traditional light-absorbing coatings.

Method used

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  • High-optical-absorption carbon nanomaterial and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] refer to figure 1 , a high optical absorption carbon nanomaterial, using carbon black with an average particle size of 1000nm as a substrate, and vertically growing carbon nanowalls on its surface through a tubular radio frequency-plasma enhanced chemical vapor deposition system, the preparation method is as follows:

[0022] (1) Evenly spread the dry carbon black particles in the quartz boat, and place the quartz boat in the quartz tube heating zone of the chemical vapor deposition system, and then vacuumize the deposition device.

[0023] (2) Feed the reducing gas hydrogen into the deposition device, the flow rate is 30 sccm, and the temperature is raised to 700° C., and kept at this temperature for 40 minutes to reduce or eliminate defects such as stress, dislocation and impurities on the carbon black surface.

[0024] (3) Regulate the power of the radio frequency device to be 300W, and keep the temperature and hydrogen flow of step (2), feed 30sccm methane and 30scc...

Embodiment 2

[0028] A kind of high optical absorption carbon nano material, adopts the carbon black that average particle size is 2000nm as matrix, grows carbon nano wall vertically on its surface by tubular radio frequency-plasma enhanced chemical vapor deposition system, and its preparation method is as follows:

[0029] (1) Evenly spread the dry carbon black particles in the quartz boat, and place the quartz boat in the quartz tube heating zone of the chemical vapor deposition system, and then vacuumize the deposition device.

[0030] (2) Feed the reducing gas hydrogen into the deposition device, the flow rate is 30 sccm, and the temperature is raised to 700° C., and kept at this temperature for 40 minutes to reduce or eliminate defects such as stress, dislocation and impurities on the carbon black surface.

[0031] (3) Regulate the power of the radio frequency device to be 300W, and keep the temperature and hydrogen flow of step (2), feed 30sccm methane and 30sccm argon to grow the carb...

Embodiment 3

[0035] A kind of high optical absorption carbon nano material, adopts the carbon black that average particle size is 2000nm as matrix, grows carbon nano wall vertically on its surface by tubular radio frequency-plasma enhanced chemical vapor deposition system, and its preparation method is as follows:

[0036] (1) Evenly spread the dry carbon black particles in the quartz boat, and place the quartz boat in the quartz tube heating zone of the chemical vapor deposition system, and then vacuumize the deposition device.

[0037] (2) Feed the reducing gas hydrogen into the deposition device, the flow rate is 30 sccm, and the temperature is raised to 700° C., and kept at this temperature for 40 minutes to reduce or eliminate defects such as stress, dislocation and impurities on the carbon black surface.

[0038] (3) Regulate the power of the radio frequency device to be 300W, and keep the temperature and hydrogen flow of step (2), feed 30sccm methane and 30sccm argon to grow the carb...

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Abstract

The invention belongs to the field of optical absorption, and discloses a high-optical-absorption carbon nanomaterial which comprises carbon black and carbon nanowalls which grow on the surface of the carbon black through a chemical vapor deposition method and have light trapping capacity, and light absorption is achieved through gap structures between the walls. A radio frequency plasma enhanced chemical vapor deposition process is adopted, a mode of increasing plasma energy density by using inert gas is adopted, chemical bonds of carbon source gas are opened under the action of reducing gas hydrogen, a vertically arranged carbon nano wall is constructed on the surface of carbon black through the processes of nucleation, migration, orientation, growth and the like, the effective refractive index is close to 1, the material has good interface impedance matching, incident light penetrates through the surface of the material to enter clearance spaces of walls in an almost non-reflection mode and is finally absorbed and converted into heat energy through multiple times of reflection between the walls, and efficient optical absorption in ultraviolet-visible light wave bands is achieved under the combined action of the physical mechanisms.

Description

technical field [0001] The invention belongs to the technical field of optical materials, and relates to a high optical absorption carbon nanometer material and a preparation method thereof. Background technique [0002] Optical absorbing materials are functional materials widely used in space optical load systems such as reconnaissance, observation, and remote sensing. The effective observation of weak signal targets plays an important role in the application fields of space cameras, star sensors, and space telescopes. The structure of traditional absorbing coating materials is relatively dense, and there is a sudden change in refractive index between the coating and air, and their interface impedance matching is low, resulting in high reflection of light at the interface and reducing the light absorption capacity of the material. However, there are almost no materials with a refractive index less than 1.3 in nature, and it is difficult to achieve a low refractive index di...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01B32/15
CPCC01B32/15
Inventor 俞兵王啸范纪红李朝龙袁林光史浩飞李燕朴明星
Owner 西安应用光学研究所
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