The invention provides a preparation method of WC-Co series nano-composite hard 
alloy powder, which includes: installing the 
front cover plate and 
electrode rod of the 
ball mill tank, and connecting the 
front cover plate and 
electrode rod to the two poles of the 
plasma power supply respectively  ; Put 
grinding balls and a certain proportion of W, C, Co raw materials in the ball milling tank, and when the 
electrode rod contacts the 
grinding balls and W, C, Co raw materials, cover the rear cover of the ball milling tank; pass the vacuum valve  Vacuum the closed 
ball mill tank to 0.01-0.1Pa, or pass the 
discharge gas medium through the vacuum valve until the pressure is 0.01-0.1MPa; turn on the 
plasma power supply, according to the 
discharge gas medium and its pressure  Adjust the 
discharge parameters and carry out different types of 
corona discharge 
plasma high-energy ball milling; take out the mixed 
powder of W, C, and Co, place it in a heat source environment for synthesis reaction, and obtain the corresponding 
cemented carbide.  The invention can not only save energy, but also improve synthesis efficiency.