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Nano active material as well as preparation method and application thereof

A technology of active materials and nano-materials, applied in the field of nano-materials, can solve the problems of reduced foaming ability and stability of foam discharge agents, high energy consumption for preparation, complicated process, etc., achieves large foaming volume, simple preparation process, and improved The effect of salt resistance

Pending Publication Date: 2021-11-16
NINGBO FENGCHENG ADVANCED ENERGY MATERIALS RES INST CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, conventional foam unloading agents are generally suitable for formations below 80°C. As the ambient temperature increases, the foaming ability and stability of the foam unloading agents will be greatly reduced, especially in high-temperature formations above 100°C, many The foam produced by the foaming agent will disappear within 2 minutes, and even no bubbles will be produced
However, the existing high-temperature anti-foaming agents have the problems of high energy consumption, complicated process and high cost.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] Preparation of nano active material, the steps are as follows:

[0044] Step (1) Add 50ml of deionized water and 5g of montmorillonite nanomaterials into a single-necked flask, and then add 10ml of γ-(methacryloyloxy)propyltrimethoxy with a mass fraction of 30% in advance Silane aqueous solution, the system was reacted at 60°C for 5 hours, the system was filtered and washed repeatedly after the reaction, the obtained filter cake was dried at 105°C and ground through a 300-mesh sieve to obtain organically modified montmorillonite nanoparticles Material.

[0045] Step (2) Weigh 3g of the organically modified montmorillonite nanomaterial obtained in step (1) in a 50ml beaker, and dissolve it with 17ml of deionized water, stir it magnetically for 20min, then put it into an ultrasonic instrument and sonicate it for 40s to obtain the modified montmorillonite nanomaterial. montmorillonite nanomaterial dispersion.

[0046]Step (3) gets the maleic acid of 20g and adds glass be...

Embodiment 2

[0050] Prepare water-soluble nanomaterials, the steps are as follows:

[0051] Step (1) Add 50ml of deionized water and 5g of montmorillonite nanomaterials into a single-necked flask, and then add 10ml of γ-(methacryloyloxy)propyltrimethoxy with a mass fraction of 30% in advance Silane aqueous solution, the system was reacted at 60°C for 5 hours, the system was filtered and washed repeatedly after the reaction, the obtained filter cake was dried at 105°C and ground through a 300-mesh sieve to obtain organically modified montmorillonite nanoparticles Material.

[0052] Step (2) Weigh 3g of the organically modified montmorillonite nanomaterial obtained in step (1) in a 50ml beaker, dissolve it with 17ml of deionized water, stir it magnetically for 30min, then put it into an ultrasonic instrument and sonicate it for 20s to obtain the modified montmorillonite nanomaterial. montmorillonite nanomaterial dispersion.

[0053] Step (3) gets the maleic acid of 20g and adds glass beake...

Embodiment 3

[0057] Preparation of nano active material, the steps are as follows:

[0058] Step (1) Add 50ml of deionized water and 5g of montmorillonite nanomaterials into a single-necked flask, and then add 10ml of γ-(methacryloyloxy)propyltrimethoxy with a mass fraction of 30% in advance Silane aqueous solution, the system was reacted at 60°C for 5 hours, the system was filtered and washed repeatedly after the reaction, the obtained filter cake was dried at 105°C and ground through a 300-mesh sieve to obtain organically modified montmorillonite nanoparticles Material.

[0059] Step (2) Weigh 3g of the organically modified montmorillonite nanomaterial obtained in step (1) in a 50ml beaker, and dissolve it with 17ml of deionized water, stir it magnetically for 20min, then put it into an ultrasonic instrument and sonicate it for 40s to obtain the modified montmorillonite nanomaterial. montmorillonite nanomaterial dispersion.

[0060] Step (3) gets the maleic acid of 20g and adds glass b...

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PUM

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Abstract

The invention discloses a nano active material. The nano active material is obtained by carrying out surface modification on organic modified montmorillonite by adopting maleic acid and a small molecular surfactant monomer. On one hand, modified montmorillonite and a traditional polymer monomer are copolymerized to form a net structure by taking a nucleation effect of a nano material as theoretical guidance, inward curling of a molecular structure can be inhibited under high-temperature and high-salt oil reservoir conditions, a polymer molecular chain keeps an intramolecular / intermolecular specific molecular structure, and foaming and liquid carrying performance reduction caused by degradation and curling of polymer molecular chains due to temperature and mineralization degree are reduced. On the other hand, by introducing a salt-resistant monomer, the salt resistance of the foam scrubbing agent under a hypersalinity condition is improved. The foam scrubbing agent developed by the invention is convenient in raw material source, relatively simple in preparation process, low in cost and low in energy consumption, and compared with a conventional foam scrubbing agent, the foam scrubbing agent is high in foam scrubbing temperature, rapid in foaming, large in foaming amount and long in foam stabilizing time.

Description

technical field [0001] The application relates to a nano active material and its preparation method and application, belonging to the technical field of nano materials. Background technique [0002] In the middle and late stages of natural gas well development, formation energy decreases, and formation water enters the near-wellbore area or wellbore with natural gas flow, and accumulates there, resulting in water flooding and a decrease in gas well production. At present, in order to solve the problem that the production of gas wells is affected by formation water, the foam drainage gas recovery technology is adopted, that is, the foam drainage agent is injected into the wellbore. Aqueous foam that is brought to the surface by air flow, reducing fluid accumulation in the wellbore. In the natural gas exploitation technology, the foam row technology has attracted more and more attention due to its advantages of convenient construction, simple equipment, low cost, wide range o...

Claims

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Application Information

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IPC IPC(8): C09K8/58E21B43/22
CPCC09K8/58E21B43/16
Inventor 吴向阳邓青春刘艳华方叶青俞波王耀国
Owner NINGBO FENGCHENG ADVANCED ENERGY MATERIALS RES INST CO LTD
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