Efficient and environment-friendly aqueous film-forming foam extinguishing agent and preparation method thereof

A foam fire extinguishing agent and water film-forming technology, which can be used in fire protection equipment and other directions, can solve problems such as ecological damage and environmental pollution, and achieve the effects of good foam stability, high fire extinguishing efficiency, and not easy to corruption and deterioration.

Pending Publication Date: 2021-12-07
NANJING UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the aqueous film-forming foam fire extinguishing agent (AFFF) widely used in China is still a formula decades ago in developed countries, which has serious ecological destructive power and environmental pollution problems.

Method used

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  • Efficient and environment-friendly aqueous film-forming foam extinguishing agent and preparation method thereof
  • Efficient and environment-friendly aqueous film-forming foam extinguishing agent and preparation method thereof
  • Efficient and environment-friendly aqueous film-forming foam extinguishing agent and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0064] Weigh respectively 1kg of benzene ring side chain anionic fluorocarbon surfactant, 1kg of cetyltrimethylammonium bromide, and 30kg of imidazoline amphoteric surfactant (imidazoline), and mix uniformly to form mixture A; Mix 5kg of alcohol monobutyl ether, 0.3kg of xanthan gum, and 30kg of water to form a mixture B; add B to A and stir; weigh 3kg of urea, mix 20kg of ethylene glycol, slowly add to A, and add sodium benzoate 0.5kg, finally add water to 100kg, stir evenly to get 100kg foam fire extinguishing agent concentrate.

Embodiment 2

[0066] Weigh respectively 1kg of alkane side chain anionic fluorocarbon surfactant, 1kg of cetyltrimethylammonium bromide, and 30kg of imidazoline, and mix uniformly to form mixture A; weigh 5kg of diethylene glycol monobutyl ether, xanthan gum Mix 0.3kg and 30kg of water evenly to form mixture B; add B to A and stir; weigh 3kg of urea and 20kg of ethylene glycol, mix evenly, slowly add to A, add 0.5kg of sodium benzoate, and finally add water to 100kg, stir Evenly, 100kg foam fire extinguishing agent concentrate can be obtained.

Embodiment 3

[0068] Weigh respectively 1kg of phencyclic ether side chain anionic fluorocarbon surfactant, 1kg of cetyltrimethylammonium bromide, and 30kg of imidazoline, and mix them uniformly to form mixture A; weigh 5kg of diethylene glycol monobutyl ether, yellow Mix 0.3kg of raw gum and 30kg of water to form mixture B; add B to A and stir; weigh 3kg of urea, 20kg of ethylene glycol, mix evenly, slowly add to A, add 0.5kg of sodium benzoate, and finally add water to 100kg , stir evenly to get 100kg foam fire extinguishing agent concentrate.

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Abstract

The invention discloses an efficient and environment-friendly aqueous film-forming foam extinguishing agent and a preparation method thereof, and the extinguishing agent is composed of 0.5-5% of a fluorocarbon surfactant, 10-35% of a hydrocarbon surfactant, 0.1-1% of a foam stabilizer, 2-10% of a cosolvent, 1-5% of an anti-burning agent, 5-30% of an anti-freezing agent, 0.1-1% of a preservative and the balance of water. Te fluorocarbon surfactant is a perfluorinated branched short-chain anionic surfactant synthesized by taking an industrial cheap raw material hexafluoropropylene dipolymer as an initial raw material. The preparation method comprises the following steps: uniformly mixing the surfactant component A, the cosolvent, the foam stabilizer and the water of a compound system formed by mixing and stirring the two surfactants to form a component B, adding the component B into the continuously stirred component A, continuously stirring, and sequentially adding the anti-burning agent, the anti-freezing agent and the preservative into the mixed system of the component A and the component B. The fire extinguishing agent comprises a perfluorinated branched short-chain environment-friendly anion fluorocarbon surfactant, is low in toxicity and good in biodegradability, has excellent spreadability, burning resistance, fire extinguishing performance, stability and liquid separation performance, does not contain PFOS and is not prone to being enriched in the environment and living bodies, and therefore environmental pollution cannot be caused.

Description

technical field [0001] The invention belongs to the field of fire-fighting and fire-extinguishing materials, in particular to a foam fire-extinguishing agent, and more specifically to a high-efficiency and environment-friendly foam fire-extinguishing agent based on a perfluorinated branched short-chain fluorocarbon anion surfactant and a preparation method thereof. Background technique [0002] Aqueous film-forming foam fire extinguishing agent (AFFF), also known as "light water" foam fire extinguishing agent, is a high-efficiency fire extinguishing agent developed abroad in the 1960s. The aqueous film-forming foam solution uses fluorocarbon surfactant as the main raw material, and also includes hydrocarbon surfactant, foam stabilizer, antifreeze and other additives. With its high surface activity, AFFF can spread along the surface of the flammable liquid during the fire extinguishing process, and form a water film from the liquid separated from the foam to separate the foam...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): A62D1/02A62D1/04
CPCA62D1/0085A62D1/0064A62D1/0042
Inventor 张丁杨亚文潘仁明姜标沙敏林超
Owner NANJING UNIV OF SCI & TECH
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