Electrolyte and lithium ion battery containing same
A lithium-ion battery and electrolyte technology, applied in the field of electrolyte, can solve problems such as the difficulty in desolvation of polyether solvents, poor wettability of electrode materials, and difficulty in lithium deposition, so as to overcome difficulties in lithium deposition, high degree of polymerization, and improve The effect of Coulombic efficiency
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Embodiment 1
[0053] This embodiment is to illustrate the lithium ion battery prepared by using the electrolyte solution of the present invention.
[0054] (1) Preparation of electrolyte
[0055] In 100g of dimethoxyethane (DME) solvent, add additive A after dry treatment is 4-methyl vinyl sulfate 6g and additive B 4g, the oxidation potential of described additive B is 3.68V, and used additive B The structural formula of is as follows, denoted as B1,
[0056]
[0057] Then, lithium bisfluoroxanthinimide (LiFSI) was added to prepare an electrolyte solution with a concentration of 1.5M, and the electrolyte solution was denoted as E1.
[0058] (2) Preparation of lithium ion battery
[0059] Lithium metal negative electrode: roll a metal lithium strip with a thickness of 40 μm on a Cu current collector to obtain a negative lithium metal strip, and then cut it into a negative electrode sheet with a length of 44 mm and a width of 20 mm.
[0060] The positive electrode uses LiCoO 2 material...
Embodiment 2
[0063] This embodiment is to illustrate the lithium ion battery prepared by using the electrolyte solution of the present invention.
[0064] Lithium ion battery is prepared according to the same method as in Example 1, the difference is: in step (1), "additive B1" is replaced by additive B2, the oxidation potential of said additive B2 is 4.05V, and said The structural formula of additive B2 is as follows:
[0065]
[0066] The resulting lithium-ion battery was labeled L2.
Embodiment 3
[0068] This embodiment is to illustrate the lithium ion battery prepared by using the electrolyte solution of the present invention.
[0069] Lithium-ion batteries are prepared according to the same method as in Example 1, except that: in step (1), "additive A ethylene sulfate" is replaced by "propane sultone", and "additive B1" is replaced It is additive B3, the oxidation potential of said additive B3 is 3.90V, and the structural formula of said additive B3 is as follows:
[0070]
[0071] The resulting lithium-ion battery was labeled L3.
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