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A kind of multilayer electrode for electric double layer capacitor and its preparation method

A technology of electric double-layer capacitors and multi-layer electrodes, which is applied in the field of capacitors, can solve the problems of insufficient electron transmission capacity and ion adsorption capacity, and achieve the effects of reducing redundant design, increasing density and capacity, and improving physical properties

Active Publication Date: 2022-05-03
NINGBO CRRC NEW ENERGY TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The ion adsorption of EDLC is mainly due to the pore structure of the carbon material on the outer layer of the electrode. From the current commercial EDLC electrode composition, there are deficiencies in both electron transport capacity and ion adsorption capacity.

Method used

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  • A kind of multilayer electrode for electric double layer capacitor and its preparation method

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] S1. Prepare the inner layer electrode slurry and the outer layer electrode slurry respectively according to the raw materials in the following mass percentages;

[0035] The inner layer electrode slurry includes the following raw materials by mass percentage: 9% conductive agent, 2.5% binder, 1.5% dispersant, 87% petroleum coke activated carbon (the average pore size distribution exceeds 90% in 1nm); the inner layer The slurry viscosity was 1500 cps.

[0036] The outer layer electrode slurry includes the following raw materials by mass percentage: 2% conductive agent, 1.6% binder, 1.2% dispersant, 95.2% coconut shell water vapor activated carbon (the average pore size distribution exceeds 95% at 2.5nm); The viscosity of the outer layer slurry is 1500cps;

[0037] The conductive agent is conductive carbon black and Ketjen carbon with a mass ratio of 1:1, the binder is SBR, and the dispersant is CMC.

[0038] S2. Pass the inner layer slurry and the outer layer slurry th...

Embodiment 2

[0044] S1. Prepare the inner layer electrode slurry and the outer layer electrode slurry respectively according to the raw materials in the following mass percentages;

[0045] The inner layer electrode paste includes the following raw materials by mass percentage: 10% conductive agent, 3% binder, 2% dispersant, 85% carbon aerogel (average pore size distribution of 0.5nm exceeds 90%); the inner layer The slurry viscosity was 2000 cps.

[0046] The outer layer electrode slurry includes the following raw materials by mass percentage: 3% conductive agent, 1.8% binder, 1.2% dispersant, 94% coconut shell water vapor activated carbon (the average pore size distribution exceeds 95% at 2.0nm); The viscosity of the outer layer slurry is 2000cps.

[0047] The conductive agent is conductive carbon black, the binder is SBR, and the dispersant is CMC.

[0048] S2. Pass the inner layer slurry and the outer layer slurry through an extrusion coating machine, and apply two layers of slurry o...

Embodiment 3

[0053] S1. Prepare the inner layer electrode slurry and the outer layer electrode slurry respectively according to the raw materials in the following mass percentages;

[0054] The inner layer electrode slurry includes the following raw materials by mass percentage: 8% conductive agent, 2.2% binder, 1.3% dispersant, 88.5% petroleum coke activated carbon (average pore size distribution of 1.5nm exceeds 90%); the inner layer The slurry viscosity was 1000 cps.

[0055] The outer electrode slurry includes the following raw materials by mass percentage: 1% conductive agent, 1.4% binder, 1% dispersant, 96.6% coconut shell water vapor activated carbon (average pore size distribution of 3.0nm exceeds 95%); The layer slurry viscosity was 1000 cps.

[0056] The conductive agent is conductive carbon black and carbon nanotubes with a mass ratio of 1:1, the binder is SBR, and the dispersant is CMC.

[0057] S2. Pass the inner layer slurry and the outer layer slurry through an extrusion c...

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Abstract

The invention belongs to the technical field of capacitors, and in particular relates to a multilayer electrode for an electric double layer capacitor and a preparation method thereof. The present invention adjusts the pore size of the porous carbon correspondingly according to the difference in the content of the conductive agent in the inner electrode layer and the outer electrode layer, wherein the content of the conductive agent in the inner electrode layer is higher than that in the outer electrode layer ; The pore size of the porous carbon in the inner electrode layer is smaller than that of the outer electrode layer, which greatly improves the density and capacity of the electrode; and through the rational design of the electrode structure, the different regions on the ion transport and electron transport channels are used for channel performance. The demand for electrode redundancy is reduced, and the physical performance of the electrode is improved.

Description

technical field [0001] The invention belongs to the technical field of capacitors, and in particular relates to a multilayer electrode for an electric double layer capacitor and a preparation method thereof. Background technique [0002] Electric double layer capacitor (also known as super capacitor) is one of the most popular high-power energy storage devices on the market. It is an energy storage device based on the principle of electric double layer energy storage. It has high power density, short charge and discharge time, and long cycle life. It has the advantages of long working temperature and wide operating temperature range, but also has the disadvantages of relatively low energy density. [0003] At present, the conventional EDLC electrodes are all single-layer electrodes, the addition ratio of conductive agent is 5-10%, and the electrode density is about 0.55g / cc-0.61g / cc. Taking the 60138 structure as an example, the monomer capacity is about 3300F, the DC (5s) ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01G11/26H01G11/24H01G11/30H01G11/32H01G11/86
CPCH01G11/26H01G11/24H01G11/30H01G11/32H01G11/86Y02E60/13
Inventor 袁峻晏鹤凤吴希强李晶张力荆葛
Owner NINGBO CRRC NEW ENERGY TECH CO LTD