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UV viscosity-reducing adhesive and UV viscosity-reducing adhesive tape

A viscose and resin technology, applied in the direction of adhesives, film/sheet adhesives, non-polymer organic compound adhesives, etc. Excellent adhesion, good effect

Pending Publication Date: 2022-02-18
宁波安特弗新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] In order to solve the problem that the peeling strength of the detachment film formed by the existing UV detachment adhesive is high after UV irradiation, the present invention provides a UV detackification adhesive and a UV detackification tape

Method used

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  • UV viscosity-reducing adhesive and UV viscosity-reducing adhesive tape
  • UV viscosity-reducing adhesive and UV viscosity-reducing adhesive tape
  • UV viscosity-reducing adhesive and UV viscosity-reducing adhesive tape

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0067] The invention provides a kind of acrylate resin, weighing 10g methyl methacrylate, 20g 2-ethylhexyl acrylate, 8g n-octyl acrylate, 10g butyl acrylate, 6g hydroxyethyl acrylate, 1.5g methacrylic acid shrinkage Glyceride and 0.1% thermal initiator azobisisobutyronitrile (AIBN) accounting for the total weight of the aforementioned monomers. Under the protection of nitrogen, heat and control the temperature at 80°C, and stir the reaction for 0.5h. Then add fluorinated diphenyl titanocene as a catalyst accounting for 1% of the total weight of the aforementioned monomers, and continue the reaction for 1 h. Cool to obtain acrylate resin A1.

[0068] The invention provides a UV viscosifying adhesive, which comprises the following components: 40g of acrylate resin, 8g of cationic curing resin, 8g of multifunctional monomer, 0.3g of cationic photoinitiator, 0.3g of free radical photoinitiator, 3g of curing agent, and 50g of solvent, the parts are parts by mass.

[0069] The ac...

Embodiment 2

[0075] The invention provides an acrylate resin, the preparation method of the acrylate resin is as follows: weigh 10g methyl methacrylate, 20g 2-ethylhexyl acrylate, 8g n-octyl acrylate, 10g butyl acrylate, 6g acrylic acid Hydroxyethyl ester, 1.5 g of glycidyl methacrylate and 0.1% of thermal initiator azobisisobutyronitrile (AIBN) accounting for the total weight of the aforementioned monomers. Under the protection of nitrogen, heat and control the temperature at 80°C, and stir the reaction for 0.5h. Then add fluorinated diphenyl titanocene as a catalyst accounting for 1% of the total weight of the aforementioned monomers, and continue the reaction for 1 h. Cool to obtain acrylate resin A2.

[0076] The invention provides a UV viscosifying adhesive, which comprises the following components: 40g of acrylate resin, 10g of cationic curing resin, 8g of multifunctional monomer, 0.3g of cationic photoinitiator, 0.3g of free radical photoinitiator, 3g of curing agent, and 25g of s...

Embodiment 3

[0083] The invention provides an acrylate resin, the preparation method of the acrylate resin is as follows: weigh 10g methyl methacrylate, 20g 2-ethylhexyl acrylate, 8g n-octyl acrylate, 10g butyl acrylate, 5g acrylic acid Hydroxyethyl ester, 1.5 g of glycidyl methacrylate and 0.1% of thermal initiator azobisisobutyronitrile (AIBN) accounting for the total weight of the aforementioned monomers. Under the protection of nitrogen, heat and control the temperature at 80°C, and stir the reaction for 0.5h. Then add fluorinated diphenyl titanocene as a catalyst accounting for 1% of the total weight of the aforementioned monomers, and continue the reaction for 1 h. Cool to obtain acrylate resin A3.

[0084] The present invention provides a UV viscosifying adhesive, which comprises the following components: 40g of acrylate resin, 10g of cationic curing resin, 7g of multifunctional monomer, 1g of cationic photoinitiator, 0.1 g of free radical photoinitiator, 2g of curing agent, and 5...

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Abstract

The invention belongs to the technical field of adhesive materials, and relates to a UV viscosity-reducing adhesive and a UV viscosity-reducing adhesive tape. In order to solve the problem of high peel strength of a viscosity-reducing film formed by an existing UV viscosity-reducing adhesive after UV irradiation, the invention provides the UV viscosity-reducing adhesive and the UV viscosity-reducing adhesive tape. The UV viscosity-reducing adhesive is prepared from the following components in parts by mass: 30 to 50 parts of acrylate resin, 5 to 10 parts of cationic cured resin, 7 to 14 parts of a polyfunctional monomer, 0.1 to 1 part of a free radical photoinitiator, 0.1 to 1 part of a cationic photoinitiator and 2 to 4 parts of a cross-linking agent. The peeling strength of a glue film formed by the UV viscosity-reducing glue is high before UV irradiation, and the peeling strength is low after UV irradiation. The UV viscosity-reducing adhesive tape prepared from the UV viscosity-reducing adhesive is high in initial adhesive force, can be adhered to a protected material without falling off, is low in adhesive force after being irradiated by UV light, is easy to peel off from the protected material, and is not easy to leave residual adhesive.

Description

technical field [0001] The invention belongs to the technical field of adhesive materials, and relates to a UV visbreaking adhesive and a UV visbreaking tape. Background technique [0002] With the rapid development of science and technology, the upgrading of the electronics industry is also very rapid. Wafer dicing, semiconductor chips, OCA bonding and positioning, and many other fields have an increasing demand for UV adhesion-reducing protective films. This kind of tape should have the purpose of stable positioning in the initial stage, and play a protective role in cutting or etching processes. After UV irradiation, it should be easily removed without leaving any residue. It maintains a high adhesive force at the initial stage, and rapidly reduces the adhesive force after UV irradiation. The principle of realizing this process is that after UV irradiation, the double bonds of a large number of oligomers inside the tape undergo cross-linking reactions. g Rapidly rises ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J7/38C09J4/02C09J4/06C09J7/24
CPCC09J7/385C09J4/06C09J7/241C09J2203/326C09J2433/00C09J2423/006
Inventor 周孟博张克然
Owner 宁波安特弗新材料科技有限公司
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