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524results about How to "Improve etching effect" patented technology

Black surface treatment process of electrolytic copper foil

The invention relates to a black surface treatment process of an electrolytic copper foil, belonging to the technical field of production processes of high and precision electrolytic copper foils. The black surface treatment process of an electrolytic copper foil is characterized in that a VLP (Very Low Profile) electrolytic copper foil of 8-12 mu m is used as an electrode, and then copper or copper alloy is roughened, solidified, weakly roughened and electrically deposited at a running speed of 25.0+/-0.1m/min; a layer of nano-scale nickel or cobalt alloy and a layer of nano-scale zinc alloy are sequentially and electrically deposited; and then alkaline chromate passivation is carried out and a layer of coupling agent is coated. In the invention, the black copper foil for an FPC (Flexible Printing Circuit) is obtained by carrying out a series of special surface treatments on the ultrathin and VLP electrolytic copper foil of 8-12 mu m, wherein the surface roughness Ra of the obtained copper foil is smaller than or equal to 0.30 mu m, Rz is smaller than or equal to 2.5 mu m; the thickness of the copper foil subjected to the surface treatments is increased by 1.40-1.80 mu m; the copper foil does not contain elements having serious damages to the human body, such as lead, mercury, cadmium, stibium, and the like and has excellent oxidation resistance as well as corrosion and etching resistance; the peel strength of the copper foil on a PI (Polyimide) film reaches higher than 1.0N/mm, and the folding strength on the PI film reach more than 100 thousand numbers of times; the copper foil has good appearance characteristics after the copper foil is microetched, and after the copper foil is made into an FCCL (Flexible Copper Clad Laminate), the copper foil has similar appearance characteristics to a rolled copper foil; and the properties of the copper foil product are equivalent to that of an electrolytic copper foil with the same specification for the FCCL.
Owner:SHANDONG JINBAO ELECTRONICS

Surface treatment process of reddened copper foil for high-grade FR-4 copper-clad plate

ActiveCN101935836AImprove appearance characteristics and corrosion resistanceExcellent anti-plating diffusion performanceInsulating substrate metal adhesion improvementPrinted circuit secondary treatmentCopper foilSurface finishing
The invention relates to a surface treatment process of reddened copper foil for a high-grade FR-4 copper-clad plate, belonging to the field of a copper foil production process. The surface treatment process of the reddened copper foil for the high-grade FR-4 copper-clad plate is characterized by comprising the following steps: taking 12-70mu m high-temperature high-extensibility copper foil as a cathode, operating at a rate of 25.0+/-0.1m/min, carrying out coarsening and solidifying fractal electro-deposition of tuberculiform metallic copper on the surface of the copper foil; electrodepositing a nano-level copper alloy layer, wherein the copper alloy can be observed that the crystal is in a punctiform shape by utilizing an electron scanning microscope, and the crystal belongs to whisker; and electrodepositing a nano-level zinc layer; and finally carrying out alkaline chromating, and coating a layer of silane coupling agent. In the process of electrodepositing a nano-level punctiform whisker copper-nitrogen alloy layer, the invention adopts nitrogen-containing heterocyclic ring organic addition agent to improve the appearance characteristic and the corrosion resistance after surface treatment. The reddened copper foil in the invention has the advantages of favorable normal temperature resistance, high-temperature oxydation performance, plating diffusion resistance, corrosion and etching resistance, favorable peeling resistance and high-temperature conversion resistance.
Owner:SHANDONG JINBAO ELECTRONICS

Method for recovering copper from alkaline etching waste liquid and recycling alkaline etching liquid

InactiveCN102019430AIncrease profitImprove copper yieldRecovery methodHydrazine compound
The invention discloses a method for recovering copper from alkaline etching waste liquid and recycling the alkaline etching liquid, comprising the step of adding a hydrazine hydrate reducing agent and a catalyst into the alkaline etching waste liquid to recover copper powder, wherein the alkaline etching waste liquid can be recycled after the copper powder is recovered. The invention has the optimum conditions of: placing the alkaline etching waste liquid into a reactor; adding hydrazine hydrate with mass percent concentration of 40 percent according to added quantity of 160-200mL / L; adding a solution of various salts of ruthenium, palladium, nickel and cobalt as the catalyst with added quantity of 0.01-0.2g / L (metered by the masses of the ruthenium, the palladium, the nickel and the cobalt), reacting for 30-35 minutes at temperature between 70DEG C and 100DEG C; and separating to obtain the copper powder. The invention has the beneficial effect that after the copper is recovered from the alkaline etching waste liquid, the alkaline etching waste liquid can be regenerated and recycled, therefore, various resources in the alkaline etching waste liquid can be used fully, and the etching cost of a printing plate and the discharge of pollutants can be reduced.
Owner:FUQING BRANCH OF FUJIAN NORMAL UNIV
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