Preparation method of button type germanium air battery

An air battery and air electrode technology, which is applied to battery electrodes, fuel cell-type half-cells, primary battery-type half-cells, circuits, etc. Achieve stable long-term discharge curve, prevent battery short circuit, and prevent leakage problems

Pending Publication Date: 2022-03-18
KUNMING UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, germanium-air batteries are mainly assembled by air battery molds (Phys.Chem.Chem.Phys., 2014, 16:22487-22494), which is large in size, which limits the application of this type of batter

Method used

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  • Preparation method of button type germanium air battery
  • Preparation method of button type germanium air battery
  • Preparation method of button type germanium air battery

Examples

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Embodiment 1

[0028] refer to Figure 1-2 , a method for preparing a button-type germanium-air battery, comprising setting a positive electrode case 1 (19 pores with a diameter of 1 mm) with several pores, an air electrode (the air electrode is sequentially integrated by a nickel mesh 2, a waterproof layer, and a carbon cloth 3 ), gel electrolyte 4, germanium sheet 5 (size: radius 0.7cm) and negative electrode shell 6, comprising the following steps:

[0029] S1. Put the germanium sheet 5, the negative electrode case 6 and the positive electrode case 1 provided with several pores into absolute ethanol for ultrasonic cleaning to remove surface impurities;

[0030] S2. Take 4.25mL of 6M KOH solution and 0.75g of CMC powder, and mix the two evenly to prepare a gel electrolyte 4 with a CMC content of 15wt%;

[0031] S3. Take 2.8 mg of Pt / C catalyst, add 700 μL Nafion solution and 300 μL isopropanol in sequence, and ultrasonically disperse the mixed solution for 30 minutes to make a catalyst co...

Embodiment 2

[0034] refer to Figure 1-2 , a method for preparing a button-type germanium-air battery, comprising setting a positive electrode case 1 (19 pores with a diameter of 1 mm) with several pores, an air electrode (the air electrode is sequentially integrated by a nickel mesh 2, a waterproof layer, and a carbon cloth 3 ), gel electrolyte 4, germanium sheet 5 (size: radius 0.7cm) and negative electrode shell 6, comprising the following steps:

[0035] S1. Put the germanium sheet 5, the negative electrode case 6 and the positive electrode case 1 provided with several pores into absolute ethanol for ultrasonic cleaning to remove surface impurities;

[0036] S2. Take 4.10 mL of 6M KOH solution and 0.90 g of CMC powder, and mix the two evenly to obtain a gel electrolyte 4 with a CMC content of 18 wt %;

[0037] S3. Take 2.8 mg of Pt / C catalyst, add 700 μL Nafion solution and 300 μL isopropanol in sequence, and ultrasonically disperse the mixed solution for 30 minutes to make a catalyst...

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Abstract

The invention discloses a preparation method of a button type germanium air battery. The battery comprises a positive electrode shell, an air electrode, a gel electrolyte, a germanium sheet and a negative electrode shell, wherein a plurality of air holes are formed in the positive electrode shell. The preparation method of the air battery is simple; the gel electrolyte can effectively prevent the electrolyte leakage problem, and the gel electrolyte is poor in fluidity, so that the problem of short circuit caused by contact of a positive electrode and a negative electrode in the battery can be prevented; a germanium sheet is adopted to show a stable long-term discharge curve; and moreover, the material has relatively high power and energy density, and has potential application in the fields of power supply of micro/nano electromechanical systems, hearing aids and the like.

Description

technical field [0001] The invention relates to the technical field of button-air batteries, in particular to a method for preparing button-type germanium-air batteries. Background technique [0002] Lithium-ion batteries, which have high energy efficiency and cycle capability, have captured most of the market share. However, considering its low storage capacity, safety concerns, instability of lithium in humid climates, and low electrochemical efficiency, it is necessary to investigate other battery technologies. Among potential battery candidates, metal-air batteries stand out for their high energy density, in addition to their small size, low cost, light weight, and environmental friendliness. Momentum has high prospects. Despite the high energy of these metal-air batteries, the immediate passivation of most of these metal anodes (e.g., aluminum, magnesium) during discharge severely reduces the available energy and renders the remaining anodes unusable. Therefore, it i...

Claims

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Application Information

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IPC IPC(8): H01M12/06H01M4/88H01M4/92
CPCH01M12/06H01M4/926H01M4/8828H01M2300/0085
Inventor 于英健张雨航高少帅赵庭宇胡素娟
Owner KUNMING UNIV
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