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Heat-resistant UV viscosity-reducing adhesive tape

A heat-resistant, adhesive tape technology, applied in the direction of adhesives, adhesive types, ester copolymer adhesives, etc., can solve the problems of residual adhesive pollution on the surface of the adherend, large peeling force, difficult peeling, etc., to improve operation Efficiency, improvement of residual glue, and easy peeling effect

Active Publication Date: 2022-03-25
深圳市云启科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in the prior art, the adhesive tape in the prior art often falls off or bubbles due to insufficient viscosity during the high-temperature molding process, and the surface of the adherend will be polluted by residual glue. After molding, the peeling force is large under normal temperature conditions, making it difficult to peel off.

Method used

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  • Heat-resistant UV viscosity-reducing adhesive tape
  • Heat-resistant UV viscosity-reducing adhesive tape
  • Heat-resistant UV viscosity-reducing adhesive tape

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0052] Use acrylate monomers such as butyl acrylate and acrylic acid. After mixing the monomer components, the polymerization temperature is 60°C. Under the action of the initiator AIBN, the soluble part is obtained by free radical copolymerization in ethyl acetate. The weight-average molecular weight of the acrylic base polymer is 800,000, and the specific formula composition is shown in Table 1; 5 parts by weight, 1 part by weight of curing agent, wherein the photocurable resin is a modified epoxy acrylic resin, and the photoinitiator is specifically 0.9 part by weight of photoinitiator 184, 0.6 part by weight of photoinitiator 127, and the amino resin is Melamine formaldehyde resin, the curing agent is an isocyanate fixing agent (reaction product of trimethylolpropane and toluene diisocyanate, trade name "CORONATE L", abbreviated C / L), and the Young's modulus is 80000Pa under 100 ℃. Adhesive substance; use PO base material to make adhesive tape with adhesive layer 1 thickne...

Embodiment 2

[0057] Using 2-ethylhexyl acrylate, acrylic acid and other acrylate monomers, after mixing the monomer components, the polymerization temperature is 60°C, and the radical copolymerization is carried out in ethyl acetate under the action of the initiator AIBN After obtaining the acrylic base polymer with a weight average molecular weight of 800,000 containing the soluble part, the specific formula composition is shown in Table 1; Parts by weight, 5 parts by weight of amino resin, 1 part by weight of curing agent, wherein, the photocurable resin is modified epoxy acrylic resin, and the photoinitiator is specifically respectively 0.9 parts by weight of photoinitiator 184 and 0.6 part by weight of photoinitiator 127 Weight, amino resin is melamine formaldehyde resin, curing agent is isocyanate fixing agent (reaction product of trimethylolpropane and toluene diisocyanate, trade name "CORONATE L", abbreviated C / L), and Young's Adhesive substance with a modulus of 50000Pa; a tape wit...

Embodiment 3

[0059] Using acrylate-based monomers such as 2-ethylhexyl acrylate and acrylamide, after mixing the monomer components, the polymerization temperature is 60°C, under the action of the initiator AIBN, through free radical copolymerization in ethyl acetate Polymerization obtains the acrylic base polymer with a weight-average molecular weight of 750,000 containing the soluble part, and the specific formula composition is shown in Table 1; Parts by weight, 5 parts by weight of amino resin, 1 part by weight of curing agent, wherein, the photocurable resin is modified epoxy acrylic resin, and the photoinitiator is specifically respectively 0.9 parts by weight of photoinitiator 184 and 0.6 part by weight of photoinitiator 127 Weight, amino resin is melamine formaldehyde resin, curing agent is isocyanate fixing agent (reaction product of trimethylolpropane and toluene diisocyanate, trade name "CORONATE L", abbreviated C / L), and Young's Adhesive substance with a modulus of 50000Pa; a t...

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Abstract

The invention provides a heat-resistant UV viscosity-reducing adhesive tape which comprises a base material and an adhesive layer arranged on one side of the base material, a release coating is arranged on the side, opposite to the side where the adhesive layer is arranged, of the base material, the Young modulus of the adhesive layer at the temperature of 100 DEG C is 50000 Pa or above, the adhesive force of the adhesive layer to an adherend reaches 100 gf / 25 mm or above when the adhesive layer is used at the high temperature of 120 DEG C, and the adhesive force of the adhesive layer to the adherend reaches 100 gf / 25 mm or above when the adhesive layer is used at the high temperature of 120 DEG C. According to the present invention, the adhesive has good adhesion, can effectively prevent the falling, can substantially improve the yield, has the peeling force of less than 50 gf / 25 mm on the adherend under the normal temperature condition after the high temperature molding, can easily peel off, and can effectively improve the residual adhesive. By selecting the high-modulus acrylic acid series adhesive under the high-temperature condition, it is guaranteed that the high-modulus acrylic acid series adhesive has high elastic modulus during high-temperature forming, meanwhile, the photosensitizer and the UV resin are matched, viscosity reduction can be rapidly achieved in a UV short-time irradiation mode after use, the working efficiency is improved, and the amino-containing resin is adopted, so that the viscosity of the adhesive is reduced, and the service life of the adhesive is prolonged. And self-crosslinking curing can be carried out in a high-temperature environment, so that the hardness of the adhesive is improved, and the adhesive residue is effectively improved.

Description

technical field [0001] The invention relates to the technical field of composite material processing technology, in particular to a heat-resistant UV adhesive tape. Background technique [0002] With the continuous development of smart phones, especially 5G smart phones, in order to avoid interference of 5G signals, the back cover of smart phones no longer uses metal materials, but uses glass and composite materials, such as PC-PMMA composite materials, etc. . The processing of composite materials involves high-temperature molding process. In order to protect the surface of the material from being damaged during the molding process, it is necessary to attach a protective tape to one side of the composite material. The material is softened, and the composite material is molded with a mold. After the high-temperature molding process, it is cooled to room temperature and then the protective tape is peeled off. In the prior art, the adhesive tape in the prior art often falls o...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J7/30C09J7/20C09J133/08C09J163/10C09J11/08
CPCC09J7/30C09J7/201C09J133/066C09J11/08C09J2301/122C09J2301/408C09J2203/326C08L63/10C08L61/28
Inventor 马文君
Owner 深圳市云启科技有限公司
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