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Resin foam

A resin foam, resin technology, applied in synthetic resin layered products, film/sheet adhesives, chemical instruments and methods, etc., can solve the problem of no disclosure or enlightenment of high impact absorption, and achieve impact Effects of excellent absorbency and excellent flame retardancy

Pending Publication Date: 2022-06-03
NITTO DENKO CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there is no disclosure or suggestion in these gazettes about thin layers and imparting high shock absorbency

Method used

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  • Resin foam

Examples

Experimental program
Comparison scheme
Effect test

Embodiment approach 1

[0118] As an embodiment 1 of forming the above-described resin foam body, for example, the following ways may be cited: after the emulsion resin composition (emulsion comprising a resin material (polymer) or the like) mechanical foaming foaming process (process A) to form a resin foam body. As a foaming device, it may be listed, for example: a device for high-speed shearing mode, a device for vibration mode, a device for the injection method of pressurized gas, etc. Among these foaming devices, from the perspective of micro-refinement of bubble diameter and large-capacity production, the high-speed shearing method device is preferred. The embodiment 1 of the formation of the above-described resin foam body may be applied regardless of which resin composition is formed.

[0119] From the point of view of film formation, it is preferable to have a high concentration of solid components of the emulsion. The concentration of the solid component of the emulsion is preferably more than 30...

Embodiment approach 2

[0125] As an embodiment 2 of forming the above-described resin foam body, it may be cited that the use of a blowing agent to foam the resin composition to form a foam body. As a blowing agent, the blowing agent commonly used in foam molding can be used, and from the perspective of environmental protection and low pollution of the foamed body, it is preferable to use a high-pressure inactive gas.

[0126]As an inactive gas, as long as the resin composition is inactive and can be infiltrated, any suitable inactive gas may be employed. As such inactive gases, you can cite, for example: carbon dioxide, nitrogen, air and the like. These gases can also be mixed. Among them, from the point of view of the amount of impregnation of the resin material (polymer) and the rapid impregnation rate, carbon dioxide is preferred.

[0127] Inactive gases are preferably supercritical. I.e., the use of carbon dioxide in a supercritical state is particularly preferred. In the supercritical state, the s...

Embodiment 1

[0182] Using a twin-screw mixer manufactured by Nippon Steel Co., Ltd., polypropylene (melt flow rate (MFR) (230°C): 0.40g / 10min) 65 parts by weight, polyolefin elastomer (melt flow rate (MFR): 6 g / 10 min, JIS A hardness: 79° by weight, magnesium hydroxide (trade name "KISUMA 5P" Concord Chemical Industry) 80 parts by weight, carbon (trade name "Asahi #35" Asahi Carbon Co., Ltd.) 10 parts by weight, and monoglyceride stearate 1 part by weight at a temperature of 200 ° C, extruded in the form of wire, and formed into granules after water cooling. The pellets were fed into a single screw extruder manufactured by Nippon Steel Co., Ltd., and carbon dioxide gas was injected at a pressure of 13 MPa (12 MPa after injection) in an atmosphere of 220 °C. Carbon dioxide gas was injected in the proportion of 4.5 parts by weight relative to the resin by 100 parts by weight. After the carbon dioxide gas is fully saturated, it is cooled to a temperature suitable for foaming, and then extruded fr...

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Abstract

Provided is a resin foam having excellent impact absorption properties and excellent flame retardancy even if the resin foam is thin. The resin foam according to the present invention has an apparent density of 0.02-0.5 g / cm3, a 25% compressive load of 3 N / cm2 or more, and a residue R of 20 wt% or more at 650 DEG C, and has a bubble structure. In one embodiment, the elastic strain energy of the resin foam when compressed is 10 kPa or more. In one embodiment, the resin foam has an aspect ratio of air bubbles of 1.5 or more.

Description

Technical field [0001] The present invention relates to a resin foam body. Background [0002] As a cushioning material for the protection of electronic devices and the protection of substrates, we use a large number of resin foams. In recent years, in response to the thinning tendency of electronic devices, cushioning materials have been required to exert high impact absorption even when they are configured in a position with narrow gaps. In addition, the use of battery peripherals has also increased, and it is also required to be able to cope with battery fire accidents, that is, it is required to be flame retardant. [0003] Patent document 1 discloses a method for obtaining a resin foam body with excellent impact absorption. However, there is no publicity or revelation in the communiqué about conferring flame retardancy. Further, in patent document 2 disclosed a method of obtaining a thin layer and a resin foam body with excellent impact absorption. However, while impact abso...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08J9/12C08L23/12C08L23/00C08K3/22C08K3/04C08K5/103C09J7/24
CPCC08J9/122C08J2323/12C08J9/0061C08J9/0066C08J9/0023C08J9/0095C09J7/26C08J2423/00C08J2423/12C08J2323/00B32B5/18C08J9/12B32B27/32
Inventor 儿玉清明伊关亮佐佐木彰吾
Owner NITTO DENKO CORP