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Circulating fluidized bed slag resource utilization method

A circulating fluidized bed and recycling technology, which is applied in the direction of sustainable waste treatment, solid waste management, climate sustainability, etc., can solve the problems of expansion cracking and low utilization rate, achieve strength improvement and improve resource utilization rate , important environmental value and economic effect

Pending Publication Date: 2022-07-08
WUHAN UNIV OF TECH +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the current research, CFB slag is mainly used as a concrete admixture after being ground by mechanical equipment, but the high calcium and sulfur content makes CFB slag produce hydration products such as ettringite when it is applied, which causes expansion and cracking problems. Therefore, when the CFB slag is used, the dosage is often not more than 20%, and the utilization rate has been low. How to improve the CFB slag utilization rate through simple methods is an urgent task.

Method used

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  • Circulating fluidized bed slag resource utilization method
  • Circulating fluidized bed slag resource utilization method
  • Circulating fluidized bed slag resource utilization method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] The original CFB slag used in this example has a CaO content of 7.33%, SO 3 The content is 6.19%; the particle size distribution is shown in Table 1 below:

[0031] Table 1

[0032] particle size <0.6

0.6-1.18 1.18-2.36 2.36-4.75 CFB slag 39.71 19.43 23.04 17.82

[0033] 1) Preliminary sorting

[0034] CFB slag with a particle size less than 0.6mm was obtained through 0.6mm sieve sorting, and its CaO content was 13.57%, SO 3 content of 12.62%; CFB slag with a particle size of more than 0.6mm, its CaO content is 3.22%, SO 3 The content is 1.95%.

[0035] 2) Preparation of expansion agent

[0036] The composition and mass fraction of the expansion agent are: 60 parts of CFB slag with a particle size of less than 0.6 mm, 20 parts of anhydrite, 10 parts of quicklime, and 10 parts of CFB fly ash. The above-mentioned raw materials were mixed and ground with a ball mill for 30 min to obtain a concrete expansion agent.

[0037] The specific su...

Embodiment 2

[0044] The present embodiment provides concrete based on the CFB slag above 0.6mm obtained in Example 1 and the fine aggregate of machine-made sand, and is compared with ordinary concrete, wherein the specific mixing ratio is shown in Table 3 below:

[0045] table 3

[0046]

[0047] *: Because the water absorption rate of CFB slag is higher than that of machine-made sand, the total water consumption of concrete is slightly higher than that of original concrete under equal slump.

[0048] The compressive strength properties of the two types of concrete in this example are: the compressive strengths of the original concrete 7d and 28d are 34.89MPa and 45.53MPa respectively; the 7d and 28d compressive strengths of the adjusted CFB slag concrete are 35.42MPa and 47.91MPa respectively, and the strength is slightly improved . The unilateral cost of the adjusted concrete is 52.3 yuan lower than that of the original concrete, which has better economic benefits.

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Abstract

The invention discloses a method for resource utilization of CFB (circulating fluidized bed) slag in the field of concrete. The method specifically comprises the following steps that (1) the CFB furnace slag is sorted into fine-grain furnace slag with the particle size smaller than 0.6 mm and coarse-grain furnace slag with the particle size larger than or equal to 0.6 mm; (2) mixing the fine-grained slag with the particle size of less than 0.6 mm with an auxiliary material, and grinding to prepare an expanding agent; and replacing part of the concrete fine aggregate with the coarse-grained slag with the particle size of more than or equal to 0.6 mm for preparing the concrete. The characteristics that the CFB slag is high in calcium and sulfur content and can be used for concrete aggregate are effectively separated through a simple method, the adverse effect of the high calcium and sulfur content in the slag on concrete is avoided, meanwhile, the characteristic of the high calcium and sulfur content of the slag is fully utilized, the resource utilization rate of the CFB slag is remarkably increased, and the cost is reduced. The method has important environmental protection value and economic benefit.

Description

technical field [0001] The invention belongs to the field of resource utilization of industrial solid waste, and in particular relates to a method for resource utilization of circulating fluidized bed coal-fired slag in the field of concrete. Background technique [0002] Circulating fluidized bed combustion slag, referred to as CFB slag, is a granular solid waste discharged from the bottom of the boiler after coal is burned in a circulating fluidized bed boiler. The building materials industry is an important way of industrial solid waste utilization, but the special desulfurization technology during the combustion of circulating fluidized bed boilers causes the chemical composition of CFB slag emitted by it to be mainly composed of SiO. 2 , Al 2 O 3 , SO 3 , CaO-based. Therefore, CFB slag has high calcium and sulfur content, and has the characteristics of pozzolanic activity. In the current research, CFB slag is mainly used as a concrete admixture after being ground b...

Claims

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Application Information

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IPC IPC(8): C04B22/14C04B18/10C04B22/06C04B22/12C04B18/14C04B18/12
CPCC04B40/0046C04B18/103C04B22/143C04B22/064C04B18/106C04B14/06Y02W30/91
Inventor 陈潇张嘉琛麻泉周明凯郭向兵郭文斌李海潮
Owner WUHAN UNIV OF TECH