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Polyamide color master batch resistant to high-temperature carbon black coloring and preparation method of polyamide color master batch

A technology of high temperature resistance and polyamide, which is applied in the field of high temperature resistant carbon black colored polyamide color masterbatch and its preparation, can solve the problems of poor dyeing uniformity, poor compatibility, and difficulty in achieving effective dispersion of particles, and achieve a similar Capacitance improvement, improved stability and coloring effect, good thermal stability effect

Active Publication Date: 2022-07-15
广东九彩新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] (1) Mix carbon black, silane coupling agent, dispersant, compatibilizer and antioxidant, then add polyamide resin, transfer to internal mixer The polyamide masterbatch colored by high temperature resistant carbon black is obtained by extruding and granulating through a twin-screw extruder, which solves the problem that the existing polyamide masterbatch preparation process is difficult to achieve effective dispersion of particles and uniform dyeing poor compatibility, and there is a problem of poor compatibility between the colorant and the polyamide resin;

Method used

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  • Polyamide color master batch resistant to high-temperature carbon black coloring and preparation method of polyamide color master batch

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Embodiment 1

[0043] The present embodiment is a polyamide color masterbatch colored by high temperature resistant carbon black, and the polyamide color masterbatch colored by high temperature resistant carbon black is prepared by the following steps:

[0044] 60 parts of carbon black, 100 parts of polyamide resin, 8 parts of dispersant, 2 parts of silane coupling agent, 1 part of compatibilizer, 1 part of antioxidant;

[0045] S81: Mix carbon black, silane coupling agent, dispersant, compatibilizer and antioxidant, and ultrasonically disperse for 20 minutes;

[0046] S82: add polyamide resin, stir evenly, transfer to an internal mixer for mixing for 20 min, and then extrude and granulate through a twin-screw extruder to obtain the polyamide masterbatch colored with high temperature resistant carbon black;

[0047] The dispersant is prepared by the following steps:

[0048] S21: Place the weighed 21.6g polyoxypropylene glycol in a three-necked flask, add a thermometer, a condenser and a st...

Embodiment 2

[0056] The present embodiment is a polyamide color masterbatch colored by high temperature resistant carbon black, and the polyamide color masterbatch colored by high temperature resistant carbon black is prepared by the following steps:

[0057] 60 parts of carbon black, 100 parts of polyamide resin, 8 parts of dispersant, 5 parts of silane coupling agent, 5 parts of compatibilizer, 5 parts of antioxidant;

[0058] S81: Mix carbon black, silane coupling agent, dispersant, compatibilizer and antioxidant, and ultrasonically disperse for 20 minutes;

[0059] S82: add polyamide resin, stir evenly, transfer to an internal mixer for mixing for 20 min, and then extrude and granulate through a twin-screw extruder to obtain the polyamide masterbatch colored with high temperature resistant carbon black;

[0060] The dispersant is prepared by the following steps:

[0061] S21: Place the weighed 21.6g polyoxypropylene glycol in a three-necked flask, add a thermometer, a condenser and a ...

Embodiment 3

[0069] The present embodiment is a polyamide color masterbatch colored by high temperature resistant carbon black, and the polyamide color masterbatch colored by high temperature resistant carbon black is prepared by the following steps:

[0070] 60 parts of carbon black, 120 parts of polyamide resin, 10 parts of dispersant, 5 parts of silane coupling agent, 5 parts of compatibilizer, 5 parts of antioxidant;

[0071] S81: Mix carbon black, silane coupling agent, dispersant, compatibilizer and antioxidant, and ultrasonically disperse for 30 minutes;

[0072] S82: add polyamide resin, stir evenly, transfer to an internal mixer for mixing for 30 min, and then extrude and granulate through a twin-screw extruder to obtain the polyamide masterbatch colored with high temperature resistant carbon black;

[0073] The dispersant is prepared by the following steps:

[0074] S21: Place the weighed 21.6g polyoxypropylene glycol in a three-necked flask, add a thermometer, a condenser and a...

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Abstract

The invention discloses a high-temperature-resistant carbon black colored polyamide color master batch and a preparation method thereof, and relates to the field of polyamide color master batches, carbon black, a silane coupling agent, a dispersing agent, a compatilizer and an antioxidant are mixed, then polyamide resin is added, the mixture is transferred into an internal mixer for mixing and extrusion granulation, and the high-temperature-resistant carbon black colored polyamide color master batch is obtained. The problems that effective dispersion of particles is difficult to achieve, dyeing uniformity is poor, and compatibility between a coloring agent and polyamide is poor in an existing polyamide color master batch preparation process are solved. The dispersing agent can generate relatively strong adsorption and steric hindrance effects, so that the carbon black coloring agent is uniformly dispersed in polyamide, and the compatilizer plays a role of a bridge, so that the compatibility of the polyamide color master batch is improved, and the purpose of improving the stability and the coloring effect of the color master batch in polyamide is achieved. And the added antioxidant also enables polyamide to have better thermal stability.

Description

technical field [0001] The invention relates to the field of polyamide color masterbatch, in particular to a polyamide color masterbatch colored with high temperature resistant carbon black and a preparation method thereof. Background technique [0002] Polyamide material has very superior mechanical properties, can withstand repeated shock and vibration, the operating temperature range is -40 ℃ ~ 100 ℃, oil, hydrocarbons, lipids and other organic solvents, not acid, easy to oxidize, easy to color and non-toxic, the current industry The most widely used PA6, PA66, PAI010, of which PA6, PA66 are widely used because of their price advantage and good performance and processability. The modification research of polyamide fiber is still in the stage of development and trial, but in advocating green environmental protection. Today, the functional modification of polyamide has broad development prospects. [0003] Masterbatch is a kind of special colorant for polymer materials. It...

Claims

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Application Information

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IPC IPC(8): C08L77/00C08L75/08C08L75/06C08K3/04C08J3/22C08G18/76C08G18/66C08G18/48C08G18/32C08G18/34C08G18/68
CPCC08J3/226C08G18/7614C08G18/348C08G18/3206C08G18/4804C08G18/6692C08G18/68C08J2477/00C08J2475/08C08J2475/06C08K3/04
Inventor 林文丹曹畅崔永哲李刚方珂琦
Owner 广东九彩新材料有限公司
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