High-thermal-conductivity wear-resistant UPR/polyamide composite film and preparation method thereof
A composite film and polyamide technology, applied in the field of plastic films, can solve the problems of weather resistance and poor sound insulation, and achieve the effects of increasing thermal conductivity and wear resistance, good thermal conductivity and long product validity period.
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specific Embodiment 1
[0021] The present embodiment is a high thermal conductivity and wear-resistant UPR / polyamide composite film and a preparation method thereof, and the method is completed according to the following steps:
[0022] Preparation of Modified Nano-ZrO2 / Al2O3
[0023] Weigh 5g Al2O3 and 2g zirconium oxychloride, dissolve in 100mL absolute ethanol, heat and stir at 40°C for 10min~20min, transfer to a high temperature and high pressure reaction kettle, adjust the pH to 10.0 with 10% ammonia water to obtain a precursor solution , Nano-ZrO2 / Al2O3 was prepared by hydrothermal method under high temperature and high pressure conditions, centrifuged and washed with absolute ethanol for 3 times, and vacuum dried at 80°C for 6h, for use; then 5g Nano-ZrO2 / Al2O3 powder and 2g methacryloyl Oxypropyltrimethoxysilane (MPS), ultrasonically dispersed in 100mL tetrahydrofuran (THF), after 20min~30min, stand at 60℃ for 6h~12h, add methanol to precipitate the modified Nano-ZrO2 / Al2O3, then Wash the p...
specific Embodiment 2
[0028] Specific example 2: The difference between this example and specific example 1 is that the modified Nano-ZrO2 / Al2O3 described in step 3 is mixed with unsaturated polyester 196 at a mass fraction of 20%. Other steps are the same as in specific embodiment 1. The thermal conductivity of the prepared composite film is 0.73W / mK.
specific Embodiment 3
[0029] Specific example 3: The difference between this example and specific example 1 is that the modified Nano-ZrO2 / Al2O3 described in step 3 is mixed with unsaturated polyester 196 at a mass fraction of 30%. Other steps are the same as in specific embodiment 1. The thermal conductivity of the prepared composite film is 1.21W / mK.
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