Cement based piezoelectric intelligent composite material and its preparing method
A technology of composite materials and piezoelectric materials, applied in the direction of piezoelectric/electrostrictive/magnetostrictive devices, circuits, electrical components, etc., can solve problems such as poor compatibility, achieve low cost, simple preparation process, and extensive engineering The effect of applied meaning
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Problems solved by technology
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Embodiment 1
[0038] With sulfoaluminate cement as the matrix and lead niobium magnesium zirconate titanate (PMN-PZT) ceramic particles as the functional body, its main properties are shown in Table 1 and Table 2.
[0039] flat machine
electrical coupling
Coefficient
K p
Horizontal machine
electrical coupling
Coefficient
K 31
longitudinal piezo
constant
d 33 / pC·N -1
loss
tanδ
relatively medium
electricity often
ε
Machinery
prime factor
Q m
curievin
Spend
T c / °C
0.66
0.41
550
1.5
3800
55
200
[0040] relative dielectric
Constant εr
Dielectric loss tanδ
/ g / cm 3
Average particle size / μm
8.55
0.067
2.078
17.70
[0041] Since the specific gravity of PMN-PZT and cement is quite different, in order to fully mix P...
Embodiment 2
[0044] Using sulfoaluminate cement as the matrix and lead niobium lithium zirconate titanate [P(ZTNL)] ceramic particles as the functional body, its main properties are shown in Table 2 and Table 4.
[0045] flat machine
electrical coupling
Coefficient
K p
Horizontal machine
electrical coupling
Coefficient
K 31
longitudinal piezo
constant
d 33 / pC·N -1
loss
tanδ
relatively medium
electricity often
ε
Machinery
prime factor
Q m
Curie temperature
T c / ℃
0.65
0.39
400
2
2000
60~70
360
[0046] Since the specific gravity of P(ZTNL) and cement is quite different, in order to fully mix P(ZTNL) and cement, firstly mix P(ZTNL) and cement by ball milling, the mixing time is 30min, the grinding medium is absolute ethanol, and after drying, Sieve and set aside. Add a certain amount of water ...
Embodiment 3
[0049] Ordinary Portland cement is used as the matrix, and lead niobium magnesium zirconate titanate (PMN-PZT) ceramic particles are used as the functional body, and its main properties are shown in Table 6 and Table 1.
[0050] Relative permittivity
Number εr
tanδ
/ g / cm 3
The average particle size
/ μm
8.79
0.087
2.017
16.76
[0051] Since the specific gravity of PMN-PZT and cement is quite different, in order to fully mix PMN-PZT and cement, first mix PMN-PZT and cement by ball milling, the mixing time is 30min, the grinding medium is absolute ethanol, and sieve after drying for later use. Add a certain amount of water according to a certain water-cement ratio, and after fully stirring, use the compression molding method to press into a φ15mm×1mm disc with a molding pressure of 60MPa. After curing in a standard curing box (20°C, 100%RH) for 28 days , polish both sides, ...
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