Three-dimension electrode reactor and use for treating organic waste water

A three-dimensional electrode and reactor technology, applied in the direction of electrochemical water/sewage treatment, water/sewage treatment, oxidized water/sewage treatment, etc., can solve problems such as rare research in the field of organic wastewater, and achieve improved biodegradability, To ensure the effect of emission standards

Inactive Publication Date: 2002-07-17
SUN YAT SEN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0003] The three-dimensional electrode reactor has a large face-to-face ratio, a good mass transfer effect and a high current efficiency. It is an electrochemical reactor with high practical and theoretical value. It has been used in many ap

Method used

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  • Three-dimension electrode reactor and use for treating organic waste water
  • Three-dimension electrode reactor and use for treating organic waste water
  • Three-dimension electrode reactor and use for treating organic waste water

Examples

Experimental program
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Effect test

Example

[0025] example 1

[0026] Take 91.0% iron filings (with a particle size of 2-4mm) as the matrix, 2% manganese dioxide, 0.01% platinum, 0.02% palladium, 0.5% copper oxide, 1.5% nickel oxide, 0.27% cobalt oxide and 0.7% oxide Zinc is the initiator, and the 4-6mm particle electrode made of 4% sodium carboxymethyl cellulose as the binder is the working electrode; the three-dimensional electrode is composed of graphite and polyester non-woven membrane as the feed electrode. reactor. At 0.3m 3 The removal rate of 100mg / l phenol solution is 92% when treated with an air flow rate of 20 volts / h for 60 minutes. The removal rate is 95% for 500mg / l chloral solution treated for 30 minutes.

Example

[0027] Example 2

[0028] With 90% carbon as the matrix, 2.0% manganese dioxide, 1.0% copper oxide, 1.25% nickel oxide, 0.22% cobalt oxide, 1.5% zinc oxide, 0.01% platinum and 0.02% palladium as initiators, with 4% A particle electrode with a particle size of 4-6mm made of sodium carboxymethyl cellulose as a binder is used as a working electrode; a three-dimensional electrode reactor with graphite and polyester non-woven membrane composite as a feed electrode. At 0.16m 3 Under the air flow rate of 20 volts, the 100 mg / l NaCN solution is treated for 30 minutes, and the CN - The removal rate reached 97%. The removal rate of the chloral solution reached 95% for 30 minutes.

Example

[0029] Example 3

[0030]With 90% iron filings as the matrix, 3.0% manganese dioxide, 0.77% copper oxide, 2.1% nickel oxide, 0.3% cobalt oxide, 0.8% zinc oxide, 0.01% platinum and 0.02% palladium as initiators, with 3 % Carboxymethyl cellulose sodium is a binder made of 4-6mm particle electrode as the working electrode; a three-dimensional electrode reactor with graphite and polyester non-woven membrane composite as the feed electrode. At 0.6m 3 / h air flow, 28 volts of the COD of a printing and dyeing factory in Taiwan Cr Treatment of printing and dyeing wastewater with a concentration of 10608mg / l for 15 minutes, COD Cr The concentration drops to 3672mg / l, its COD Cr The removal rate was 65.3%, and the decolorization rate was 95%.

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Abstract

The present invention relates to a three-D electrode reactor and its application for treating organic waste water. Said reactor is formed from bed body, feeder negative electrode, feeder positive electrode, particle electrode, water-distributing plate, aeration plate and D.C. power supply. It is a three-D electrode reactor using electric energy as excitation energy, air as raw material and particles electrode containing initiating agent as working electrode. Said reactor can produce strong oxidizing agents of H2O2 and OH, and can effectively make oxidation-decomposition, and can compltely mineralize organic pollutant into the inorganic materials of CO2 and water. It can be used for pretreating organic waste water, and can be used for making after treatment of waste water passed through biological chemical treatment so as to ensure standard discharge of waste water.

Description

technical field [0001] The invention relates to a three-dimensional electrode electrochemical reaction device capable of generating hydroxyl radicals and its application in organic waste water treatment. technical background [0002] The treatment of organic pollutants, especially high-concentration organic pollutants, is a difficult and hot point in the treatment of industrial wastewater in the world. The deep oxidation technology (AOTs) proposed by Glaze et al. provides an important way to control organic pollutants (W.H.Glaze, F.Beltranand T.Tuhkanen, Water Pollution Res J.Canada, 1992, 27: 23), has become a A new water treatment technology that is rapidly developing. Its main feature is to make full use of free radicals, especially the strong oxidation of OH of hydroxyl radicals, which will completely oxidize and degrade organic pollutants. Related devices are very meaningful. [0003] The three-dimensional electrode reactor has a la...

Claims

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Application Information

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IPC IPC(8): C02F1/46C02F1/461C02F1/72
Inventor 朱锡海陈卫国熊亚关耀楚罗传荣彭玉凡
Owner SUN YAT SEN UNIV
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