Composition of high work temp. and high thermostability rareearth magnetic material
A technology with high thermal stability and working temperature, applied in the direction of magnetic materials, magnetic objects, electrical components, etc., can solve the problems of high working temperature of magnetic stability, poor thermal stability, limited wide application, etc., to achieve magnetothermal stability Good properties, high coercivity, good room temperature stability
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Embodiment 1
[0017] 1) Preparation of raw materials: select Sm powder, Nd powder, Fe powder and Zr powder with a purity higher than 99.9%, wherein the atomic percentages of Sm, Nd, Fe, and Zr are Sm:Nd:Fe:Zr=7:0.02:91: 1.98, mix the metal powder evenly;
[0018] 2) High-energy ball milling: put the mixed raw materials into a high-energy ball mill, and ball mill for 48 hours under the protection of Ar gas with a purity of 99.999%;
[0019] 3) Crystallization heat treatment: take out the ball-milled powder and put it into a vacuum heat treatment furnace, and vacuumize the furnace so that the vacuum degree is 1×10 -3 Around Pa, the crystallization temperature is controlled at 625°C, and the heat treatment time is 10 minutes. In order to prevent excessive growth of grains, a rapid heating method is adopted during heat treatment, and the heating rate is 10°C / s;
[0020] 4) Nitriding treatment: After the crystallization treatment, put the alloy powder into a vacuum furnace and vacuumize to 1×10 ...
Embodiment 2
[0024] 1) Alloy smelting: select Sm, Nd, Fe and Ta powders with a purity higher than 99.9%, wherein the atomic percentages of Sm, Nd, Fe, and Ta are Sm:Nd:Fe:Ta=6.96:0.04:91:2, Mix the powders into a vacuum induction furnace and pump the vacuum so that the vacuum in the furnace is controlled at 1×10 -4 Pa, then filled with 1×10 3 The purity of Pa is 99.999% Ar gas, which is smelted under the protection of Ar gas. In order to ensure that the composition of the ingot basically meets the design composition, attention must be paid to the loss of rare earth elements during the smelting process;
[0025] 2) Homogenization annealing: Take out the master alloy ingot and put it into the heat treatment furnace, and vacuumize to 1×10 -4 At about Pa, heat rapidly to 1020°C and keep it warm for 24 hours;
[0026] 3) Rapid quenching: remove the oxides and impurities on the surface of the annealed alloy ingot, put it into a vacuum stripping machine, re-melt it under the protection of an in...
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