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Method of decontaminating sulfur dioxide in smoke using honeycomb ceramic

A technology of honeycomb ceramics and sulfur dioxide, which is applied in the field of sulfur dioxide desulfurization technology, can solve the problems of large equipment, complex technology, and large floor area, and achieve the effects of reducing sulfur dioxide content, good desulfurization effect, and simple construction

Inactive Publication Date: 2003-09-17
UNIV OF SCI & TECH BEIJING
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Problems solved by technology

These methods are effective in treating high concentrations of sulfur dioxide, so they have been widely used at home and abroad, but the effect is not ideal for treating waste gas from sintering plants with large flue gas volume and low concentration of sulfur dioxide
Moreover, the used equipment of these methods is huge, the investment is high, the floor area is large, and the technology is complicated.
The second is to adopt a clean production process, that is, to desulfurize fuel and other materials before combustion to reduce the sulfur content entering the combustion process. This will inevitably impose various restrictions on fuel, etc., which not only increases production costs, but also reduces the adaptability of raw materials. ability, and it is difficult to achieve the ideal purification effect
However, if this method is used in the sintering plant, even if the problem of secondary release of SO2 is overcome, sulfur will inevitably remain in the sintering ore. As a result, the desulfurization burden of the subsequent steel production process will be increased, and the production of high-purity steel will be affected. is difficult and therefore not advisable

Method used

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  • Method of decontaminating sulfur dioxide in smoke using honeycomb ceramic
  • Method of decontaminating sulfur dioxide in smoke using honeycomb ceramic
  • Method of decontaminating sulfur dioxide in smoke using honeycomb ceramic

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Embodiment Construction

[0020] According to SO in flue gas from a sintering plant of a steel company in Beijing 2 Actual concentration, with air or oxygen and SO 2 Gas prepared as test gas, SO 2 The volume concentration is 4.92×10 -4 , control the ventilation time of the test gas, pass it into the experimental system quantitatively, and then use pure oxygen to drive away the residual sulfur-containing gas in the system), absorb it with the sulfur-fixed absorption liquid in the reactor, and then titrate it with NaOH standard solution , to determine the SO of the test gas 2 true concentration. Grind the honeycomb ceramic bricks with different pore densities into cylinders matching the inner diameter of the furnace tube, immerse them in the lime emulsion to fully absorb the lime emulsion, and then place the honeycomb ceramic bricks soaked in the lime emulsion in the constant temperature zone of the tube furnace . At different temperatures, repeat the above process of feeding test gas and absorbing ...

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Abstract

A process for removing SO2 from the fume in sinterting plane is characterized by use of the porous honeycomb ceramics as absorbing carrier whose pore surface adsorbing the lime milk as desulfurizing agent and the lime milk are dropped in for continuously supplement fresh lime milk. Its advantages are high desulfurizing rate up to more than 80%, and low cost.

Description

Technical field: [0001] The invention belongs to the field of metallurgy and environmental protection, and in particular relates to a sulfur dioxide desulfurization technology suitable for waste gas of sintering plants. Background technique: [0002] The sintering plant in the iron and steel enterprise is a source of air pollution, and the sulfur dioxide it emits is extremely harmful to the earth's ecosystem. According to relevant literature reports, a joint enterprise with an annual output of 3 million tons of steel in foreign countries will emit 2.2 kg of sulfur dioxide for every ton of crude steel produced, of which 1.5 kg of sulfur dioxide will be emitted from the production of one ton of screened sinter. Therefore, how to eliminate and reduce the emission of sulfur dioxide in the waste gas of the sintering plant is a major issue that domestic and foreign iron and steel enterprises and environmental protection departments have been concerned about for a long time and are...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D53/50B01D53/80
Inventor 李福燊连芳李联生李丽芬
Owner UNIV OF SCI & TECH BEIJING
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