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Oxide and salt melt electrolyzing process of producing cell-level mixed RF metals

A technology of oxide molten salt and mixed rare earth, which is applied in the technical field of producing battery-grade mixed rare earth metal by electrolysis of oxide molten salt, which can solve the difficulty in meeting the requirements of battery production, increased operating costs of electrolytic production, and high content of non-rare earth impurities. problems, achieve the effects of reducing investment and operating costs, stable product quality, and low content of non-rare earth impurities

Inactive Publication Date: 2004-01-21
中国地质科学院成都矿产综合利用研究所
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] 2. This process must install a huge chlorine gas recovery and disposal system, which requires a lot of investment and covers a large area, which will undoubtedly increase the operating costs of electrolysis production
[0005] 3. The content of non-rare earth impurities in metal products is high. The mixed rare earth metals produced by this process are mainly used as additives in the steel industry, and it is difficult to meet the requirements of modern technology applied to battery production.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment Construction

[0023] A process for producing battery grade mixed rare earth metals by molten salt electrolysis of oxides, in which rare earth chlorides are dissolved, filtered, leached, filtrate extracted, impurities removed, ammonium carbonate carbonized, and burned to obtain mixed rare earth oxides. And add the prepared molten salt, and then carry out electrolysis together to obtain battery-grade rare earth metals.

[0024] Quality requirements for raw materials and furnace products

[0025] indicators

REO

CeO 2 / REO

Fe 2 o 3

Water insoluble matter

Content%

≥45

~45

≤0.05

≤0.1

project

TREO

CeO 2

La 2 o 2

PR 6 o 11

Nd 2 o 2

Content %

≥98.5

48

35

4

12

project

al 2 o 3

CaO

MgO

ZnO

Fe 2 o 3

MnO 2

Content %

≤0.1

≤0.3

≤0.03

≤0.01

≤0.05

≤0.01

...

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PUM

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Abstract

The present invention is oxide and salt melt electrolyzing process of producing cell-level mixed RE metals. Mixed RE oxide formed with RE chloride and through carbon deposition and ignition is mixed with molten salt, and the mixture is electrolyzed to obtain cell-level mixed RE metals. The present invention is green environment-protecting RE metal producing technology, has no adverse effect of producing great amount of chloride to affect environment.

Description

Technical field: [0001] The invention relates to a process for producing mixed rare earth metals, in particular to a process for producing battery grade mixed rare earth metals by electrolysis of oxide molten salt. Background technique: [0002] my country's existing production line for large-scale production of mixed rare earth metals is formed, and its dominant process is the chloride system molten salt electrolysis method. Although this process has the characteristics of low cost, it has the following obvious disadvantages: [0003] 1. Exhaust gas emissions have a greater impact on the environment. Data show that the annual production of rare earth metals in my country is about 5,000 tons, and the chlorine gas emitted by the "chloride electrolysis process" exceeds 1,900 tons, and its impact on the ecological environment cannot be ignored. [0004] 2. This process must install a huge chlorine gas recovery and disposal system, which requires a lot of investment and covers ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C25C3/34C25C3/36
Inventor 胡泽松廖祥文王全根
Owner 中国地质科学院成都矿产综合利用研究所
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