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Method for preparing rapid-dry corn starch adhesive

A technology of corn starch and adhesives, applied in the direction of starch adhesives, adhesive types, etc., can solve the problems of not being suitable for small-scale production, pollution of packaging contents, large amount of oxidant, etc., and achieve excellent bonding strength, Reduced dosage, high hardness effect

Inactive Publication Date: 2004-09-15
XI AN JIAOTONG UNIV
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  • Abstract
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  • Application Information

AI Technical Summary

Problems solved by technology

[0003] In the preparation process of oxidized starch, the preparation process of pure oxidized starch has been used for a long time, and no new process has been specially developed for the production of oxidized starch for starch adhesives, which has led to two problems: the first is the production of oxidized starch For starch, the amount of oxidant is large, the reaction time is very long (manpower and power consumption are large); the viscosity is not very large after gelatinization, in order to ensure the bonding strength, the solid content of the adhesive has to be increased; these factors lead to the final production of Starch adhesives are expensive and difficult to be accepted by the market
The second problem is that the existing starch adhesives have a slow drying speed, which is not suitable for the small-scale production and fast-release products of carton manufacturers in my country.
[0004] At present, the most commonly used sodium silicate adhesive in my country's carton industry has the advantages of fast drying speed and low cost of use (compared to the existing starch adhesive products), but it is easy to get damp, and its stiffness is not as good as starch adhesive. Because of the high alkalinity of this kind of adhesive, it is easy to cause pollution to the contents of the package. It belongs to the product that is phased out by the national policy. The developed countries in foreign countries have basically eliminated the sodium hydroxide as early as 20 or 30 years ago. Adhesives, the Chinese government has already stipulated that the packaging cartons for export commodities must not use sodium silicate adhesives

Method used

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Examples

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preparation example Construction

[0016] According to the technical scheme of the present invention, the preparation method of producing low-cost quick-drying type cornstarch adhesive comprises the following main contents:

[0017] 1> Add tap water to the reaction kettle according to 1.5 times the mass fraction of dry starch and stir to make starch milk, the concentration of starch milk: 40%;

[0018] 2> Catalyst and its dosage: choose Fe 2+ salt, the main choice is FeSO 4 , FeCl 2 etc., the dosage is 0.25% to 0.35% of the dry starch mass fraction;

[0019] 3> Oxidant and its dosage: choose H 2 o 2 , the dosage is about 5% (4.5-6%) of the dry starch mass fraction;

[0020] 4> Oxidation temperature: 55℃~60℃;

[0021] 5> Oxidation time: After the temperature rises to 58°C, add an oxidant and react for 10 minutes, then add a catalyst and react for another 25 to 30 minutes;

[0022] 6>Drying temperature: no more than 60°C;

[0023] 7> Moisture content of oxidized starch after drying: 15% by mass for long-t...

Embodiment

[0031] The present embodiment adopts the method of the present invention to prepare adhesive, taking 500kg corn starch as an example, the production process is as follows figure 2 shown.

[0032] Add 725kg of tap water to the reactor, start stirring, then add 500kg of cornstarch, heat up to 58°C, add 25kg of 27.5% concentration of commercially available hydrogen peroxide H 2 o 2 , keep the reaction for 10min, add 1.5kg FeSO 4 , and continue to react for 25 minutes (at this time, due to the intense heat release of the oxidation reaction in the reactor, attention should be paid to passing cold water to cool down, otherwise the temperature is too high, which may cause starch gelatinization), stop stirring, and discharge.

[0033] Put the starch milk in a centrifuge to shake off most of the water, dry it, and control the temperature of the hot air not higher than 60°C to obtain dry oxidized starch powder.

[0034] Take 50kg of oxidized starch, add 100kg of tap water into it, s...

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Abstract

The invention discloses a manufacturing method for dry core starch adhesives, the method uses new catalyst Fe2+, reduces the use quantity of oxidant to 5%A, reduces the reaction time to 30 minutes, and produces a kind of cheap and high adhesives starch adhesives. The method adds in modified bentonite or natrium group bentonite whose weight is 30% of dried starch as the fillers before adding in NaOH, it enhances the drying speed greatly. The adhesives can be dried quickly, it doesn't counter tide, high rigidity. The cost is reduced greatly, the dry speed is enhabced greatly.

Description

technical field [0001] The invention belongs to the modification technology of natural polymers, and relates to a water-based adhesive or an adhesive used for bonding paper products such as cartons and cartons, in particular to a preparation method of a corn starch adhesive. Background technique [0002] The existing corn starch adhesives are basically made from oxidized starch as raw material through NaOH solution gelatinization. Most of its production process is as figure 1 As shown, that is to add water to cornstarch to make starch milk, stir and add oxidant (about 10%), react at a certain temperature for a long time (6h~8h), then filter, dry, add NaOH solution to gelatinize, and make into Starch binder, the solid content is generally 20% to 25%. [0003] In the preparation process of oxidized starch, the preparation process of pure oxidized starch has been used for a long time, and no new process has been specially developed for the production of oxidized starch for st...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J103/02
Inventor 郭炎马素德郭晶李仲谨
Owner XI AN JIAOTONG UNIV
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